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1.发明申请HYDROFORMYLATION PROCESS FOR PRODUCING 1,6-DISUBSTITUTED HEXANE DERIVATIVES 审中-公开用于生产1,6-二取代的己烷衍生物的加氢甲酰化方法
公开(公告)号：WO2017064064A1
公开(公告)日：2017-04-20
申请号：PCT/EP2016/074347
申请日：2016-10-11
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , ERNST, Martin , MORMUL, Jaroslaw , BREITENFELD, Jan , TRAPP, Oliver
IPC: C07C29/141 , C07C45/49 , C07C51/16 , C07C209/26 , C07C31/18 , C07C47/12 , C07C55/14 , C07C211/12
CPC classification number: C07C209/26 , B01J31/00 , C07C29/132 , C07C51/305 , C07D317/12 , C07D319/06 , C07C211/12 , C07C55/14 , C07C31/20
Abstract: The invention relates to a process for the production of 1,6-difunctionalized hexane derivatives from 1,3-diunsaturated hydrocarbons, preferably butadiene, wherein a hydroformylation with carbon monoxide and hydrogen is performed in the presence of an at least dihydric alkanol and during the hydroformylation the temperature is increased. The reaction yields the acetals of the 1,6-hexanedial derivatives which are isolated and further reacted to obtain the desired 1,6-difunctionalized hexane derivatives, in particular 1,6-hexanediamine, 1,6-hexanediol and adipic acid.
Abstract translation: 本发明涉及由1,3-二不饱和烃，优选丁二烯制备1,6-二官能化己烷衍生物的方法，其中用一氧化碳和氢进行加氢甲酰化是在 至少二元链烷醇，并且在加氢甲酰化过程中温度升高。 该反应产生1,6-己二醛衍生物的缩醛，将其分离并进一步反应以获得所需的1,6-二官能化己烷衍生物，特别是1,6-己二胺，1,6-己二醇和己二酸。 p>
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公开(公告)号：WO2017178282A1
公开(公告)日：2017-10-19
申请号：PCT/EP2017/057953
申请日：2017-04-04
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , HUGUET SUBIELA, Nuria , TRAPP, Oliver , MANZINI, Simone
IPC: C07C51/15
Abstract: The present invention relates to a catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising contacting an alkene and carbon dioxide with a carboxylation catalyst being a transition metal complex, an alkoxide, and an organic solvent, to obtain an α,β-ethylenically unsaturated carboxylic acid salt, the organic solvent being incompletely miscible with water at a pressure of 1 bar at at least one temperature T and selected from amides and ureas, T being a temperature in the range from 10°C to 90°C.
Abstract translation: 本发明涉及制备α，β-烯键式不饱和羧酸盐的催化方法，包括使烯烃和二氧化碳与作为过渡金属络合物的羧化催化剂，醇盐和 得到α，β-烯键式不饱和羧酸盐，所述有机溶剂在至少一个温度T下在1巴的压力下与水不完全混溶并且选自酰胺和脲，T是 范围从10℃到90℃。
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公开(公告)号：WO2017133995A1
公开(公告)日：2017-08-10
申请号：PCT/EP2017/051887
申请日：2017-01-30
Applicant: BASF SE
Inventor： DEHN, Richard , DEHESTANI, Ahmad , MASSONNE, Klemens , WAGLÖHNER, Steffen , TELES, Joaquim Henrique , SCHAUB, Thomas , BRÜGGEMANN, Till Christian , TELLÄCHE HERRANZ, Carlos , TRAPP, Oliver , WYSOCKI, Jedrzej
IPC: C07D201/02
CPC classification number: C07D201/02
Abstract: Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von C 4 -C 15 -Lactamen, bei dem ein C 1 -C 10 -Alkylnitrit mit einem C 4 -C 15 -Cycloalkan umgesetzt wird und während der Umsetzung mit einer Leuchtdiode belichtet wird. Das sich dabei bildende C 4 -C 15 - Cyclohexanonoxim wird dann weiter zu einem C 4 -C 15 -Lactam umgesetzt, der gebildete C- 1 -C 10 -Alkohol wird in die Herstellung des C- 1 -C- 10 -Alkylnitrits recycliert.
Abstract translation: 本发明涉及一种生产C 4 -C 15内酰胺的方法，其中C 1 / sub 亚硝酸C10烷基酯与C≡C15环烷烃反应并在反应过程中暴露于发光二极管。 然后将得到的C 4 -C 15环己酮肟进一步转化为C 4 -C 15环己酮肟， 内酰胺反应，形成的C-1-C10醇用于制备C-1-C-10醇， / sub>烷基亚硝酸盐回收。
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Patent Agency Ranking
公开(公告)号：EP3442939B1
公开(公告)日：2020-08-26
申请号：EP17715469.7
申请日：2017-04-04
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , HUGUET SUBIELA, Nuria , TRAPP, Oliver , MANZINI, Simone
IPC: C07C51/15
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公开(公告)号：EP3411357A1
公开(公告)日：2018-12-12
申请号：EP17702599.6
申请日：2017-01-30
Applicant: BASF SE
Inventor： DEHN, Richard , DEHESTANI, Ahmad , MASSONNE, Klemens , WAGLÖHNER, Steffen , TELES, Joaquim Henrique , SCHAUB, Thomas , BRÜGGEMANN, Till Christian , TELLÄCHE HERRANZ, Carlos , TRAPP, Oliver , WYSOCKI, Jedrzej
IPC: C07D201/02
CPC classification number: C07D201/02
Abstract: The present invention relates to a method for producing C4-C15 lactams, in which a C1-C10 alkyl nitrite is reacted with a C4-C15 cycloalkane and is exposed during the reaction by means of a light-emitting diode. The thus produced C4-C15 cyclohexanone oxime is then further reacted to a C4-C15 lactam, and the formed C1-C10 alcohol is recycled in the production of the C1-C-10 alkyl nitrite.
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公开(公告)号：EP3442939A1
公开(公告)日：2019-02-20
申请号：EP17715469.7
申请日：2017-04-04
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , HUGUET SUBIELA, Nuria , TRAPP, Oliver , MANZINI, Simone
IPC: C07C51/15
Abstract: The present invention relates to a catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising contacting an alkene and carbon dioxide with a carboxylation catalyst being a transition metal complex, an alkoxide, and an organic solvent, to obtain an α,β-ethylenically unsaturated carboxylic acid salt, the organic solvent being incompletely miscible with water at a pressure of 1 bar at at least one temperature T and selected from amides and ureas, T being a temperature in the range from 10° C. to 90° C.
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公开(公告)号：EP3362426A1
公开(公告)日：2018-08-22
申请号：EP16784149.3
申请日：2016-10-11
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , ERNST, Martin , MORMUL, Jaroslaw , BREITENFELD, Jan , TRAPP, Oliver , HOFMANN, Peter
IPC: C07C29/141 , C07C45/49 , C07C51/16 , C07C209/26 , C07C31/18 , C07C47/12 , C07C55/14 , C07C211/12
Abstract: The invention relates to a process for the production of 1,6-difunctionalized hexane derivatives from 1,3-diunsaturated hydrocarbons, preferably butadiene, wherein a hydroformylation with carbon monoxide and hydrogen is performed in the presence of an at least dihydric alkanol and during the hydroformylation the temperature is increased. The reaction yields the acetals of the 1,6-hexanedial derivatives which are isolated and further reacted to obtain the desired 1,6-difunctionalized hexane derivatives, in particular 1,6-hexanediamine, 1,6-hexanediol and adipic acid.
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公开(公告)号：EP3362426B1
公开(公告)日：2020-09-02
申请号：EP16784149.3
申请日：2016-10-11
Applicant: BASF SE
Inventor： SCHAUB, Thomas , PACIELLO, Rocco , ERNST, Martin , MORMUL, Jaroslaw , BREITENFELD, Jan , TRAPP, Oliver , HOFMANN, Peter
IPC: C07C29/141 , C07C45/49 , C07C51/16 , C07C209/26 , C07C31/18 , C07C47/12 , C07C55/14 , C07C211/12
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