公开(公告)号：CA2863836C

公开(公告)日：2020-06-30

申请号：CA2863836

申请日：2013-02-15

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS ,  MUHLBACH KLAUS ,  CORBERAN ROC ROSA ,  HASCHICK ROBERT ,  DAISS ANDREAS ,  VOLLAND MARCO-CHRISTIAN

IPC: C08F10/10

Abstract: Preparation of isobutene homopolymers having a weight-average molecular weight of 75 000 to 10 000 000 by polymerization of isobutene, by (a) performing the polymerization at -80°C to -190°C, (b) using, as an inert solvent, optionally halogenated C1 to C5 hydrocarbons, (c) using, as a polymerization catalyst, a Lewis acid complex, (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound comprising one oxygen atom and no abstractable proton, and (e) performing the polymerization in the presence of at least one chain length regulator comprising one tertiary olefinic carbon atom.

公开(公告)号：SG11201403143VA

公开(公告)日：2014-10-30

申请号：SG11201403143V

申请日：2013-01-04

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS

IPC: C08F110/10 ,  C08F2/00

Abstract: Continuous production of polyisobutylene having a content of terminal double bonds of greater than 50% by polymerization of isobutene in the presence of a polymerization catalyst usual therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene, and feeding the combined stream into the reaction zone in such a manner that the steady state concentration of isobutene in the combined stream at the point where the combined stream is fed into the reaction zone has a value of on average at least 40% by weight, and the invention also relates to a polymerization system therefor.

公开(公告)号：SG11201510755VA

公开(公告)日：2016-02-26

申请号：SG11201510755V

申请日：2014-07-07

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS

IPC: C08F10/10 ,  C08F2/00 ,  C08F110/10

Abstract: A polyisobutylene having a total content of vinylidene double bonds of more than 50 mol % and a number-average molecular weight of 500 to 10 000 daltons, where at least 10% of all the vinylidene double bonds in the polyisobutylene are part of one or more side chains composed of at least 2 carbon atoms from the main polyisobutylene chain. Such a polyisobutylene is suitable for production of fuel and lubricant additives.

公开(公告)号：MY174854A

公开(公告)日：2020-05-19

申请号：MYPI2014001901

申请日：2013-01-04

Applicant: BASF SE

Inventor： DR BRYM MARKUS ,  DR WETTLING THOMAS ,  HIRSCH STEFAN ,  WEIS MARKUS

Abstract: Continuous production of polyisobutylene having a content of terminal double bonds of greater than 50% by polymerization of isobutene in the presence of a polymerization catalyst usual therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene, and feeding the combined stream into the reaction zone in such a manner that the steady state concentration of isobutene in the combined stream at the point where the combined stream is fed into the reaction zone has a value of on average at least 40% by weight, and the invention also relates to a polymerization system therefor.

公开(公告)号：MY169056A

公开(公告)日：2019-02-12

申请号：MYPI2014002337

申请日：2013-02-13

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  WEIS MARKUS ,  BRYM MARKUS ,  HIRSCH STEFAN

Abstract: The invention relates to a catalyst complex comprising boron trifluoride and a co-catalyst mixture of 10 to 90 wt% of a monovalent primary C1 to C20 alcohol and 90 to 10 wt% of a monovalent secondary C3 to C20 alcohol, wherein the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. Said catalyst complex is used in the production of highly reactive isobutene homopolymers having a number-average molecular weight of 300 to 50,000, wherein a C4 hydrocarbon mixture containing at least 20 wt% of isobutene and in total at least 10 wt% of other C4 olefins is used as a feed material.

公开(公告)号：SG10201606559UA

公开(公告)日：2016-09-29

申请号：SG10201606559U

申请日：2013-02-13

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS

Abstract: The invention relates to a catalyst complex comprising boron trifluoride and a co-catalyst mixture of 10 to 90 wt% of a monovalent primary C1 to C20 alcohol and 90 to 10 wt% of a monovalent secondary C3 to C20 alcohol, wherein the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. Said catalyst complex is used in the production of highly reactive isobutene homopolymers having a number-average molecular weight of 300 to 50,000, wherein a C4 hydrocarbon mixture containing at least 20 wt% of isobutene and in total at least 10 wt% of other C4 olefins is used as a feed material.

公开(公告)号：SG10201606861XA

公开(公告)日：2016-10-28

申请号：SG10201606861X

申请日：2013-02-15

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS ,  CORBERAN ROC ROSA ,  MÜHLBACH KLAUS ,  HASCHICK ROBERT ,  DAIΒ ANDREAS ,  VOLLAND MARCO-CHRISTIAN

Abstract: The invention relates to the production of isobutylene homopolymers having a weight-average molecular weight of 75,000 to 10,000,000 by means of the polymerization of isobutylene by (a) performing the polymerization at -80°C to -190°C, (b) using optionally halogenated C1 to C5 hydrocarbons as an inert solvent, (c) using a Lewis acid complex as a polymerization catalyst, and (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound, which contains an oxygen atom and no proton that can be emitted, and performing the polymerization in the presence of at least one chain length regulator, which contains a tertiary olefinic carbon atom.

公开(公告)号：SG11201403863YA

公开(公告)日：2014-10-30

申请号：SG11201403863Y

申请日：2013-02-15

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS ,  CORBERAN ROC ROSA ,  MÜHLBACH KLAUS ,  HASCHICK ROBERT ,  DAIΒ ANDREAS ,  VOLLAND MARCO-CHRISTIAN

IPC: C08F10/10

Abstract: The invention relates to the production of isobutylene homopolymers having a weight-average molecular weight of 75,000 to 10,000,000 by means of the polymerization of isobutylene by (a) performing the polymerization at -80°C to -190°C, (b) using optionally halogenated C1 to C5 hydrocarbons as an inert solvent, (c) using a Lewis acid complex as a polymerization catalyst, and (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound, which contains an oxygen atom and no proton that can be emitted, and performing the polymerization in the presence of at least one chain length regulator, which contains a tertiary olefinic carbon atom.

公开(公告)号：MY168940A

公开(公告)日：2019-01-10

申请号：MYPI2014002038

申请日：2013-02-15

Applicant: BASF SE

Inventor： DR WETTLING THOMAS ,  DR BRYM MARKUS ,  WEIS MARKUS ,  HIRSCH STEFAN

IPC: C08F10/10 ,  C08F4/14 ,  C08F4/26

Abstract: The invention relates to the production of isobutylene homopolymers having a weight-average molecular weight of 75,000 to 10,000,000 by means of the polymerization of isobutylene by (a) performing the polymerization at -80?C to - 190?C, (b) using optionally halogenated C1 to C5 hydrocarbons as an inert solvent, (c) using a Lewis acid complex as a polymerization catalyst, and (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound, which contains an oxygen atom and no proton that can be emitted, and performing the polymerization in the presence of at least one chain length regulator, which contains a tertiary olefinic carbon atom.

公开(公告)号：SG10201605034SA

公开(公告)日：2016-08-30

申请号：SG10201605034S

申请日：2013-01-04

Applicant: BASF SE

Inventor： WETTLING THOMAS ,  HIRSCH STEFAN ,  BRYM MARKUS ,  WEIS MARKUS

Abstract: Continuous production of polyisobutylene having a content of terminal double bonds of greater than 50% by polymerization of isobutene in the presence of a polymerization catalyst usual therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene, and feeding the combined stream into the reaction zone in such a manner that the steady state concentration of isobutene in the combined stream at the point where the combined stream is fed into the reaction zone has a value of on average at least 40% by weight, and the invention also relates to a polymerization system therefor.