公开(公告)号：JP2013049624A

公开(公告)日：2013-03-14

申请号：JP2012231436

申请日：2012-10-19

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  XIE BIN

IPC: C01B39/46

CPC classification number: B01J37/0225 ,  B01D53/02 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9436 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20738 ,  B01D2255/502 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2258/012 ,  B01J29/18 ,  B01J29/24 ,  B01J29/7007 ,  B01J29/7415 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/88 ,  B01J35/002 ,  B01J35/026 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0246 ,  B01J2229/42 ,  C01B39/46 ,  C10G11/05 ,  C10G11/18 ,  Y02A50/2325 ,  Y02C20/10 ,  Y02P20/153

Abstract: PROBLEM TO BE SOLVED: To provide an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YOand optionally comprising XO.SOLUTION: The process comprises the steps of: (1) preparing a mixture comprising seed crystals, at least one source for YOand at least one source for XO; (2) crystallizing the mixture; and (6) subjecting the zeolitic material having a BEA framework structure to an ion-exchange procedure, wherein Y is a tetravalent element, and X is a trivalent element. The seed crystals comprise zeolitic material having a BEA framework structure. In the step (6), at least one ionic non-framework element contained in the zeolitic material having a BEA framework is ion-exchanged against Fe and/or Cu.

Abstract translation: 要解决的问题：提供一种不含有机模板的合成方法，用于生产具有包含YO SB SB“2”的BEA骨架结构的沸石材料，并且任选地包含X 2 O 3 。 解决方案：该方法包括以下步骤：（1）制备包含晶种的混合物，至少一种用于YO 2 的源和至少一个X SB POS =“POST”> 2 O 3 ; （2）使混合物结晶; 和（6）使具有BEA骨架结构的沸石材料进行离子交换程序，其中Y是四价元素，X是三价元素。 晶种包含具有BEA骨架结构的沸石材料。 在步骤（6）中，包含在具有BEA骨架的沸石材料中的至少一种离子非骨架元素与Fe和/或Cu进行离子交换。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：WO2010100203A3

公开(公告)日：2010-11-18

申请号：PCT/EP2010052713

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INST TECH ,  YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  XIAO FENG-SHOU ,  GIES HERMANN ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  TATSUMI TAKASHI

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  XIAO FENG-SHOU ,  GIES HERMANN ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  TATSUMI TAKASHI

IPC: B01J29/06 ,  C01B33/38 ,  C01B39/04

CPC classification number: C01B33/20 ,  B01J21/16 ,  B01J29/061 ,  B01J29/70 ,  B01J35/002 ,  C01B33/38 ,  C01B37/00 ,  C01B39/02 ,  C01B39/04 ,  C07C1/20 ,  C07C209/16 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C211/04

Abstract: A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.

Abstract translation: 一种制备同形取代的层状硅酸盐的方法，该方法包括（1）提供含二氧化硅或其前体，至少一种允许层状硅酸盐结晶的结构导向剂（SDA）和水的混合物; （2）在水热条件下加热根据（1）得到的混合物; （3）向至少一个源添加至少一个适于同晶取代的元素; （4）在水热条件下加热根据（3）得到的混合物。

公开(公告)号：WO2011073123A3

公开(公告)日：2011-10-20

申请号：PCT/EP2010069476

申请日：2010-12-13

Applicant: BASF SE ,  GROSSSCHMIDT DIRK ,  YILMAZ BILGE ,  KLINGLER DIRK ,  ZOELS BERND

Inventor： GROSSSCHMIDT DIRK ,  YILMAZ BILGE ,  KLINGLER DIRK ,  ZOELS BERND

IPC: B01J29/76 ,  B01D53/94 ,  B01J29/072 ,  B01J37/02

CPC classification number: B01J37/0238 ,  B01D53/9427 ,  B01D2251/2062 ,  B01D2255/20738 ,  B01D2255/50 ,  B01J29/072 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/763 ,  B01J29/85 ,  B01J35/0073 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1057 ,  B01J37/0234 ,  B01J37/086 ,  B01J2229/186 ,  B01J2229/34 ,  B01J2229/40 ,  Y02C20/10

Abstract: The present invention relates to a ferrous zeolite, wherein the number of iron centers, relative to the zeolite, is greater than the number of cation positions of the zeolite. The present invention further relates to a ferrous zeolite that can be produced by gas phase reaction with iron pentacarbonyl, comprising a greater specific surface area than analogous ferrous zeolites produced by ion exchange and/or more hydrothermally stable than analogous ferrous zeolites produced by ion exchange. The present invention further relates to a ferrous zeolite of BETA structure that can be produced by gas phase reaction with iron pentacarbonyl, wherein the number of iron clusters greater than 10 nm is less than 15 wt%, relative to the total amount of iron. The present invention further relates to a method for producing ferrous zeolithic material, characterized in that doping with iron takes place by means of a gas phase reaction using iron pentacarbonyl. The present invention further relates to a method for catalytically reducing nitrogen oxides by adding ammoniac and using catalysts comprising said ferrous zeolithic material.

Abstract translation: 本发明涉及一种含铁沸石，其中铁原子的基于沸石的数量，比沸石的阳离子位置的数目越大。 此外，本发明涉及通过用五羰基铁，其具有比通过离子交换含铁沸石和/或水热比通过离子交换含铁沸石制造的类似的稳定产生模拟较大的比表面积的气相反应产生的含铁Zeoltihen。 此外，本发明betriff结构BETA的含铁沸石，通过用五羰基铁气相反应产生的，与铁簇是大于10纳米，小于15重量％的数量，基于铁的总量是。 此外，本发明涉及一种用于含有铁的沸石材料，其特征在于，所述掺杂经由使用五羰基铁气相反应用铁进行的制备方法。 此外，本发明涉及一种用于在添加氨的催化还原氮氧化物和使用包含所述含铁的沸石材料的催化剂的处理。

公开(公告)号：WO2013038372A3

公开(公告)日：2013-05-10

申请号：PCT/IB2012054800

申请日：2012-09-14

Applicant: BASF SE ,  TOKYO INST TECH ,  BASF CHINA CO LTD ,  YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  GIES HERMANN ,  IMAI HIROYUKI ,  TIJSEBAERT BART ,  REN LIMIN ,  YANG CHENGGUAN

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  GIES HERMANN ,  IMAI HIROYUKI ,  TIJSEBAERT BART ,  REN LIMIN ,  YANG CHENGGUAN

IPC: C01B39/54 ,  B01J29/06 ,  B01J29/85

CPC classification number: C01B39/00 ,  B01D53/02 ,  B01D53/9418 ,  B01D2255/2025 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/50 ,  B01J29/005 ,  B01J29/7015 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1066 ,  B01J37/02 ,  B01J37/0221 ,  B01J37/023 ,  B01J2229/62 ,  C01B37/08 ,  C01B39/48 ,  C01B39/54 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2006/12 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G11/18 ,  Y02P20/52 ,  Y02P30/20 ,  C07C11/02

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of (1) providing a mixture comprising one or more sources for Z2O5, one or more sources for X2O3, optionally one or more structure directing agents, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises Y02, X2O3, and optionally Z2O5, and wherein the seed crystals have a diameter of 450 nm or greater; (2) crystallizing the mixture provided in (1) to afford zeolite crystals comprising a core of seed crystal provided in step (1 ) and a shell crystallized on the seed crystal; wherein Z is a pentavalent element, Y is a tetravalent element, and X is a trivalent element, and wherein preferably one or more sources for YO2 are further provided in step (1 ).

Abstract translation: 本发明涉及一种制备具有CHA骨架结构的沸石材料的方法，所述沸石材料包含具有核 - 壳结构的沸石晶体，其中所述方法包括以下步骤：（1）提供包含一种或多种 Z2O5的来源，X2O3的一种或多种来源，任选的一种或多种结构导向剂，以及具有CHA骨架结构的晶种，其中晶种的CHA骨架结构包含Y02，X2O3和任选的Z2O5，并且其中种子 晶体的直径为450nm以上; （2）使（1）中提供的混合物结晶，得到包含步骤（1）中提供的晶种核心的沸石晶体和在晶种上结晶的壳; 其中Z是五价元素，Y是四价元素，X是三价元素，并且其中优选在步骤（1）中进一步提供一种或多种YO2源。

公开(公告)号：WO2010100205A3

公开(公告)日：2010-11-18

申请号：PCT/EP2010052716

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INST TECH ,  YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  GIES HERMANN ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  GIES HERMANN ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

IPC: C01B33/38 ,  C01B37/00 ,  C01B37/02

CPC classification number: C01B33/20 ,  B01J20/10 ,  B01J20/30 ,  B01J21/16 ,  B01J29/049 ,  C01B33/38 ,  C01B37/00 ,  C01B37/02 ,  C01B39/02 ,  C01B39/04

Abstract: The present invention relates to a process for the preparation of a layered silicate containing at least silicon and oxygen, comprising (1) providing a mixture containing silica and/or at least one silica precursor, water, at least one tetraalkylammonium compound selected from the group consisting of diethyldimethylammonium compound, a triethylmethylammonium compound, and a mixture of a diethyldimethylammonium and a triethylmethylammonium compound, and at least one base, and optionally at least one suitable seeding material; and (2) heating of the mixture obtained according to (1) under autogenous pressure (hydrothermal conditions) to a temperature in the range of from to 120 to 160 °C for a period in the range of from 5 to 10 days to give a suspension containing the layered silicate.

Abstract translation: 本发明涉及一种制备至少含有硅和氧的层状硅酸盐的方法，其包括（1）提供含有二氧化硅和/或至少一种二氧化硅前体的混合物，水，至少一种选自以下的四烷基铵化合物： 由二乙基二甲基铵化合物，三乙基甲基铵化合物和二乙基二甲基铵和三乙基甲基铵化合物的混合物组成，以及至少一种碱和任选的至少一种合适的接种材料; 和（2）根据（1）得到的混合物在自生压力（水热条件）下加热至120至160℃的温度范围为5至10天，得到 含有层状硅酸盐的悬浮液。

公开(公告)号：WO2015032851A3

公开(公告)日：2015-06-04

申请号：PCT/EP2014068822

申请日：2014-09-04

Applicant: BASF SE ,  TOKYO INST TECH

Inventor： FEYEN MATHIAS ,  RUETZ ROGER ,  MÜLLER ULRICH ,  GAAB MANUELA ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  WEISS RALF ,  GIES HERMANN ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  TOSHIYUKI YOKOI ,  YILMAZ BILGE ,  DE BAERDEMAEKER TREES

IPC: C01B37/02 ,  B01J29/035 ,  B01J29/04 ,  C01B33/38 ,  C01B39/02 ,  C01B39/46 ,  C01B39/48 ,  C04B35/16 ,  C07C1/20 ,  C07C11/02 ,  C10G3/00

CPC classification number: B01J29/035 ,  B01J29/049 ,  B01J29/06 ,  B01J35/002 ,  B01J35/1019 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B33/38 ,  C04B35/16 ,  C04B2235/5409 ,  C07C1/20 ,  C07C2521/08 ,  C07C2529/00 ,  C07C11/02

Abstract: The present invention relates to a process for the preparation of a pillared silicate compound comprising a layered silicate structure and bridging silicon atoms located between adjacent silicate layers of the silicate structure, wherein said bridging silicon atoms form at least one covalent bond to each of the adjacent silicate layers, said process comprising (1) providing one or more layered silicates; (2) adding said one or more layered silicates to a solvent system, wherein the resulting mixture has a pH of 5 or less; and (3) subjecting the mixture obtained in step (2) to solvothermal conditions; wherein no silicon-containing compound according to formula (I) R4-mSi[-(SiR2)n-R]m (I) is used at any point of the process up to and including step (3), wherein m is 1, 2, 3, or 4, and n is an integer greater than or equal to 0, wherein when n is equal to 0, one or more residues R are leaving groups, and wherein none of the residues R contains Si, as well as to a pillared silicate compound per se, preferably as obtained and/or obtainable according to the inventive process as well as to the use of the inventive compounds. A further process is disclosed wherein a sulfur oxoacid is present in step (2), and wherein a silicon-containing compound may or may not be used.

Abstract translation: 本发明涉及一种制备柱状硅酸盐化合物的方法，其包括层状硅酸盐结构和位于硅酸盐结构的相邻硅酸盐层之间的桥连硅原子，其中所述桥连硅原子与相邻的每个相邻的硅酸盐层形成至少一个共价键 所述方法包括（1）提供一层或多层层状硅酸盐; （2）将所述一种或多种层状硅酸盐加入到溶剂体系中，其中所得混合物的pH为5以下; 和（3）将步骤（2）中获得的混合物经受溶剂热条件; 其中在直到并包括步骤（3）的任何一个步骤中，不使用根据式（I）的含硅化合物R 4-m Si [ - （SiR 2）n R] m（I），其中m为1,2， 3或4，并且n是大于或等于0的整数，其中当n等于0时，一个或多个残基R是离去基团，并且其中残基R中没有一个含有Si，以及被支化的 硅酸盐化合物本身，优选根据本发明方法获得和/或可获得，以及本发明化合物的用途。 公开了另一种方法，其中在步骤（2）中存在硫含氧酸，并且其中可以使用或不使用含硅化合物。

公开(公告)号：WO2014174416A3

公开(公告)日：2015-03-12

申请号：PCT/IB2014060805

申请日：2014-04-17

Applicant: BASF SE ,  TOKYO INST TECH ,  BASF CHINA CO LTD

Inventor： FEYEN MATHIAS ,  MÜLLER ULRICH ,  MAURER STEFAN ,  BOHN MARTIN ALEXANDER ,  YILMAZ BILGE ,  TATSUMI TAKASHI ,  ZHANG WEIPING ,  DE VOS DIRK ,  GIES HERMANN ,  BAO XINHE ,  XIAO FENG-SHOU ,  TOSHIYUKI YOKOI

IPC: C07D307/46 ,  C01B39/02 ,  C01B39/06 ,  C07D307/48

CPC classification number: B01J29/90 ,  B01J29/7057 ,  B01J35/002 ,  B01J37/06 ,  B01J38/02 ,  B01J2229/16 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/06 ,  C01B39/46 ,  Y02P20/584

Abstract: A method of dehydration of at least one compound (A) comprising, in the chain form, -at least one hydroxyl group and -at least one carbonyl functionality selected from the group consisting of aldehyde (CHO), ke- tone (CO) and carboxylic acid (COOH) and mixtures thereof,in the presence of at least one zeolite which is (a) obtainable from an organotemplate-free synthetic process and (b) isomorphously substituted comprising silicon, aluminum and at least one further metal wherein the at least one further metal is selected from the group consisting of the elements of Group 3 to 14 in Period 4 to 6and mixtures thereof.

Abstract translation: 至少一种化合物（A）的脱水方法，其以链形式包含至少一个羟基和至少一种选自醛（CHO），酮基（CO）和 羧酸（COOH）及其混合物，在至少一种沸石存在下，其是（a）可从无有机无模板的合成方法获得，和（b）同晶取代，包括硅，铝和至少一种其它金属，其中至少 另外一种金属选自第4至6期的第3至14族的元素及其混合物。

公开(公告)号：WO2014060982A3

公开(公告)日：2014-06-12

申请号：PCT/IB2013059417

申请日：2013-10-17

Applicant: BASF SE ,  BASF CHINA CO LTD ,  TOKYO INST TECH

Inventor： YILMAZ BILGE ,  MÜLLER ULRICH ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  GIES HERMANN ,  IMAI HIROYUKI

IPC: C01B37/00 ,  C01B37/02

CPC classification number: C07C1/044 ,  B01J29/76 ,  B01J29/89 ,  B01J35/1019 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J2229/186 ,  C10G25/003 ,  C10G25/03

Abstract: A process for the production of a pillared silicate comprises: (i) providing a layered silicate; (ii) interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii) treating the interlayer expanded silicate with one or more hydrolysable silicon containing compounds; (iv) treating the interlayer expanded compound with an aqueous solution to obtain a pillared silicate; (v) removing at least a portion of the one or more swelling agents from the pillared silicate; (vi) impregnating the pillared silicate with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof, as well as to a pillared silicate optionally obtainable from said process and its use, in particular in a process for the production of one or more olefins.

Abstract translation: 用于生产柱状硅酸盐的方法包括：（i）提供层状硅酸盐; （ii）层间膨胀步骤（i）中提供的层状硅酸盐，包括用一种或多种溶胀剂处理层状硅酸盐的步骤; （iii）用一种或多种可水解含硅化合物处理层间发泡硅酸盐; （iv）用水溶液处理层间发泡化合物，得到柱状硅酸盐; （v）从柱状硅酸盐中去除至少一部分一种或多种溶胀剂; （vi）用一种或多种选自Fe，Ru，Ir及其两种或多种的组合的一种或多种元素浸渍柱状硅酸盐，以及任选地可从所述方法获得的柱状硅酸盐及其用途，特别是 在一种制备一种或多种烯烃的方法中。

公开(公告)号：WO2010100191A3

公开(公告)日：2011-05-12

申请号：PCT/EP2010052695

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INST TECH ,  YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  GIES HERMANN ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  GIES HERMANN ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

IPC: C01B37/00 ,  C01B33/38 ,  C01B33/40 ,  C01B33/42 ,  C01B37/02 ,  C01B39/46 ,  C01B39/48

CPC classification number: C01B37/005 ,  C01B32/05 ,  C01B37/02 ,  C01B39/026 ,  C01B39/46 ,  C01B39/48 ,  C04B35/16 ,  C04B2235/3201 ,  C04B2235/3222 ,  C04B2235/3427 ,  C04B2235/5409

Abstract: The present invention relates to a process for the preparation of a silicate compound, comprising (1) providing at least one layered silicate; and (2) mixing said layered silicate with water and at least one silicon containing compound according to formula R4-mSi[-(SiR2)n-R]m wherein at least one residue R is a leaving group and none of the residues R contains Si; m is 0, 1, 2, 3, or 4; and n is an integer greater than or equal to 0.

Abstract translation: 本发明涉及一种制备硅酸盐化合物的方法，包括（1）提供至少一种层状硅酸盐; 和（2）将所述层状硅酸盐与水和至少一种根据式R 4-m Si [ - （SiR 2）n -R] m的含硅化合物混合，其中至少一个残基R是离去基团，并且残基R都不含有Si; m为0,1,2,3或4; 并且n是大于或等于0的整数。

公开(公告)号：WO2010100193A3

公开(公告)日：2010-11-18

申请号：PCT/EP2010052699

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INST TECH ,  YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  GIES HERMANN ,  BAO XINHE ,  DE VOS DIRK ,  TATSUMI TAKASHI ,  ZHANG WEIPING

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  GIES HERMANN ,  BAO XINHE ,  DE VOS DIRK ,  TATSUMI TAKASHI ,  ZHANG WEIPING

IPC: C01B33/38 ,  C01B37/00 ,  C01B37/02

CPC classification number: C01B37/005 ,  C01B37/02 ,  C04B35/16 ,  C04B2235/3217 ,  C04B2235/3232 ,  C04B2235/3239 ,  C04B2235/3244 ,  C04B2235/3251 ,  C04B2235/3272 ,  C04B2235/3286 ,  C04B2235/3287 ,  C04B2235/3293 ,  C04B2235/3409 ,  C04B2235/3427 ,  C04B2235/441 ,  C04B2235/5409 ,  C04B2235/602 ,  C04B2235/6021

Abstract: The present invention relates to a process for the preparation of an isomorphously substituted RUB-36 silicate comprising (1) providing a mixture containing silica, preferably amorphous silica, and/or at least one silica precursor, water, at least one suitable structure directing agent, (2) heating the mixture obtained according to (1) under hydrothermal conditions to give a suspension containing an RUB-36 silicate, (3) separating the RUB-36 silicate, wherein (a) either the mixture according to (1) contains at least one element suitable for isomorphous substitution and/or (b) the separated RUB-36 silicate according to (3) is subjected to isomorphous substitution.

Abstract translation: 本发明涉及制备同晶取代的RUB-36硅酸盐的方法，其包括（1）提供含有二氧化硅，优选无定形二氧化硅和/或至少一种二氧化硅前体，水，至少一种合适的结构导向剂 ，（2）在水热条件下加热根据（1）获得的混合物，得到含有RUB-36硅酸盐的悬浮液，（3）分离RUB-36硅酸盐，其中（a）根据（1）的混合物含有 适于同晶取代的至少一种元素和/或（b）根据（3）的分离的RUB-36硅酸盐进行同晶取代。