公开(公告)号：JP2013049624A

公开(公告)日：2013-03-14

申请号：JP2012231436

申请日：2012-10-19

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  XIE BIN

IPC: C01B39/46

CPC classification number: B01J37/0225 ,  B01D53/02 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9436 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20738 ,  B01D2255/502 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2257/702 ,  B01D2257/80 ,  B01D2258/012 ,  B01J29/18 ,  B01J29/24 ,  B01J29/7007 ,  B01J29/7415 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/88 ,  B01J35/002 ,  B01J35/026 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0246 ,  B01J2229/42 ,  C01B39/46 ,  C10G11/05 ,  C10G11/18 ,  Y02A50/2325 ,  Y02C20/10 ,  Y02P20/153

Abstract: PROBLEM TO BE SOLVED: To provide an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YOand optionally comprising XO.SOLUTION: The process comprises the steps of: (1) preparing a mixture comprising seed crystals, at least one source for YOand at least one source for XO; (2) crystallizing the mixture; and (6) subjecting the zeolitic material having a BEA framework structure to an ion-exchange procedure, wherein Y is a tetravalent element, and X is a trivalent element. The seed crystals comprise zeolitic material having a BEA framework structure. In the step (6), at least one ionic non-framework element contained in the zeolitic material having a BEA framework is ion-exchanged against Fe and/or Cu.

Abstract translation: 要解决的问题：提供一种不含有机模板的合成方法，用于生产具有包含YO SB SB“2”的BEA骨架结构的沸石材料，并且任选地包含X 2 O 3 。 解决方案：该方法包括以下步骤：（1）制备包含晶种的混合物，至少一种用于YO 2 的源和至少一个X SB POS =“POST”> 2 O 3 ; （2）使混合物结晶; 和（6）使具有BEA骨架结构的沸石材料进行离子交换程序，其中Y是四价元素，X是三价元素。 晶种包含具有BEA骨架结构的沸石材料。 在步骤（6）中，包含在具有BEA骨架的沸石材料中的至少一种离子非骨架元素与Fe和/或Cu进行离子交换。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：WO2014199348A3

公开(公告)日：2015-06-25

申请号：PCT/IB2014062202

申请日：2014-06-13

Applicant: BASF SE ,  BASF CHINA CO LTD ,  TOKYO INST TECH

Inventor： FEYEN MATHIAS ,  SPANNHOFF KIRSTEN ,  MÜLLER ULRICH ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  GIES HERMANN ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  TOSHIYUKI YOKOI ,  BILGE YILMAZ

IPC: C07C1/20

CPC classification number: C07C1/20 ,  B01J29/049 ,  B01J29/061 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/78 ,  B01J29/7815 ,  B01J29/89 ,  B01J29/90 ,  B01J37/0201 ,  B01J38/12 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/08 ,  C01B39/085 ,  C07C2529/70 ,  C07C2529/89 ,  Y02P20/584 ,  C07C11/167

Abstract: A process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 provided in (i) with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene; wherein the catalyst comprises a crystalline material supporting one or more catalytically active metals M, as well as to the use of the crystalline material supporting one or more catalytically active metals M.

Abstract translation: 一种制备丁二烯的方法，包括（i）提供包含乙醇的气流G-1; （ii）使（i）中提供的气流G-1与催化剂接触，从而获得包含丁二烯的气流G-2; 其中所述催化剂包含支撑一种或多种催化活性金属M的结晶物质，以及支持一种或多种催化活性金属M的结晶物质的用途。

公开(公告)号：WO2015018807A3

公开(公告)日：2015-04-23

申请号：PCT/EP2014066757

申请日：2014-08-05

Applicant: BASF SE ,  TOKYO INST TECH

Inventor： FEYEN MATHIAS ,  MÜLLER ULRICH ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  GIES HERMANN ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  GUO XIAOGUANG

IPC: B01J29/78 ,  B01J29/72 ,  B01J29/80 ,  B01J29/82 ,  B01J29/83 ,  B01J29/86 ,  B01J29/90 ,  B01J38/10 ,  C07C2/76 ,  C07C11/04

CPC classification number: C07C2/76 ,  B01J29/0358 ,  B01J29/061 ,  B01J29/48 ,  B01J29/72 ,  B01J29/78 ,  B01J29/7815 ,  B01J29/80 ,  B01J29/85 ,  B01J29/90 ,  B01J38/10 ,  B01J2229/186 ,  C07C2529/74 ,  C07C2529/76 ,  C07C2529/78 ,  C07C2529/80 ,  Y02P20/52 ,  Y02P20/582 ,  Y02P20/584 ,  Y02P20/588 ,  C07C11/04

Abstract: The present invention relates to a process comprising the step of converting methane to ethene under non-oxidative conditions in the presence of a catalyst comprising (a) a zeolite with a largest pore opening which is larger than 8; (b) a metal whereas the metal (b) is loaded onto the zeolite (a); and whereas the zeolite (a) is selected from zeolites -with a maximum diameter of a sphere that can be included of 4.5 A or smaller and/or -with a maximum diameter of a sphere which can diffuse along a of 4.4 A or smaller and/or -with a maximum diameter of a sphere which can diffuse along b of 4.4 A or smaller and/or -with a maximum diameter of a sphere which can diffuse along c of 4.4 A or smaller. Zeolite (a) is preferably a RRO catalyst, in particular RUB-41.

Abstract translation: 本发明涉及一种方法，其包括在催化剂存在下，在非氧化条件下将甲烷转化为乙烯的步骤，所述催化剂包含（a）最大孔径大于8的沸石; （b）金属，而金属（b）负载在沸石（a）上; 而沸石（a）选自具有球体的最大直径的沸石，其可以包括4.5A或更小的和/或具有可以沿4.4A或更小的扩散的球体的最大直径， /或 - 具有可以沿b扩散的球体的最大直径为4.4A或更小，和/或具有可以沿着4.4A或更小的c扩散的球体的最大直径。 沸石（a）优选为RRO催化剂，特别是RUB-41。

公开(公告)号：WO2013038372A3

公开(公告)日：2013-05-10

申请号：PCT/IB2012054800

申请日：2012-09-14

Applicant: BASF SE ,  TOKYO INST TECH ,  BASF CHINA CO LTD ,  YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  GIES HERMANN ,  IMAI HIROYUKI ,  TIJSEBAERT BART ,  REN LIMIN ,  YANG CHENGGUAN

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  GIES HERMANN ,  IMAI HIROYUKI ,  TIJSEBAERT BART ,  REN LIMIN ,  YANG CHENGGUAN

IPC: C01B39/54 ,  B01J29/06 ,  B01J29/85

CPC classification number: C01B39/00 ,  B01D53/02 ,  B01D53/9418 ,  B01D2255/2025 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/2094 ,  B01D2255/50 ,  B01J29/005 ,  B01J29/7015 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1066 ,  B01J37/02 ,  B01J37/0221 ,  B01J37/023 ,  B01J2229/62 ,  C01B37/08 ,  C01B39/48 ,  C01B39/54 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2006/12 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G11/18 ,  Y02P20/52 ,  Y02P30/20 ,  C07C11/02

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of (1) providing a mixture comprising one or more sources for Z2O5, one or more sources for X2O3, optionally one or more structure directing agents, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises Y02, X2O3, and optionally Z2O5, and wherein the seed crystals have a diameter of 450 nm or greater; (2) crystallizing the mixture provided in (1) to afford zeolite crystals comprising a core of seed crystal provided in step (1 ) and a shell crystallized on the seed crystal; wherein Z is a pentavalent element, Y is a tetravalent element, and X is a trivalent element, and wherein preferably one or more sources for YO2 are further provided in step (1 ).

Abstract translation: 本发明涉及一种制备具有CHA骨架结构的沸石材料的方法，所述沸石材料包含具有核 - 壳结构的沸石晶体，其中所述方法包括以下步骤：（1）提供包含一种或多种 Z2O5的来源，X2O3的一种或多种来源，任选的一种或多种结构导向剂，以及具有CHA骨架结构的晶种，其中晶种的CHA骨架结构包含Y02，X2O3和任选的Z2O5，并且其中种子 晶体的直径为450nm以上; （2）使（1）中提供的混合物结晶，得到包含步骤（1）中提供的晶种核心的沸石晶体和在晶种上结晶的壳; 其中Z是五价元素，Y是四价元素，X是三价元素，并且其中优选在步骤（1）中进一步提供一种或多种YO2源。

公开(公告)号：WO2010100205A3

公开(公告)日：2010-11-18

申请号：PCT/EP2010052716

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INST TECH ,  YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  GIES HERMANN ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  GIES HERMANN ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

IPC: C01B33/38 ,  C01B37/00 ,  C01B37/02

CPC classification number: C01B33/20 ,  B01J20/10 ,  B01J20/30 ,  B01J21/16 ,  B01J29/049 ,  C01B33/38 ,  C01B37/00 ,  C01B37/02 ,  C01B39/02 ,  C01B39/04

Abstract: The present invention relates to a process for the preparation of a layered silicate containing at least silicon and oxygen, comprising (1) providing a mixture containing silica and/or at least one silica precursor, water, at least one tetraalkylammonium compound selected from the group consisting of diethyldimethylammonium compound, a triethylmethylammonium compound, and a mixture of a diethyldimethylammonium and a triethylmethylammonium compound, and at least one base, and optionally at least one suitable seeding material; and (2) heating of the mixture obtained according to (1) under autogenous pressure (hydrothermal conditions) to a temperature in the range of from to 120 to 160 °C for a period in the range of from 5 to 10 days to give a suspension containing the layered silicate.

Abstract translation: 本发明涉及一种制备至少含有硅和氧的层状硅酸盐的方法，其包括（1）提供含有二氧化硅和/或至少一种二氧化硅前体的混合物，水，至少一种选自以下的四烷基铵化合物： 由二乙基二甲基铵化合物，三乙基甲基铵化合物和二乙基二甲基铵和三乙基甲基铵化合物的混合物组成，以及至少一种碱和任选的至少一种合适的接种材料; 和（2）根据（1）得到的混合物在自生压力（水热条件）下加热至120至160℃的温度范围为5至10天，得到 含有层状硅酸盐的悬浮液。

公开(公告)号：WO2014199349A3

公开(公告)日：2015-07-02

申请号：PCT/IB2014062203

申请日：2014-06-13

Applicant: BASF SE ,  BASF CHINA CO LTD ,  TOKYO INST TECH

Inventor： FEYEN MATHIAS ,  SPANNHOFF KIRSTEN ,  MÜLLER ULRICH ,  BAO XINHE ,  ZHANG WEIPING ,  DE VOS DIRK ,  GIES HERMANN ,  TATSUMI TAKASHI ,  XIAO FENG-SHOU ,  TOSHIYUKI YOKOI ,  BILGE YILMAZ

IPC: B01J21/06 ,  C07C11/167

CPC classification number: C07C1/20 ,  B01J23/80 ,  B01J23/94 ,  B01J38/02 ,  C07C2521/06 ,  C07C2521/14 ,  C07C2523/06 ,  C07C2523/72 ,  Y02P20/584 ,  C07C11/167

Abstract: Providing a catalyst and a process for the preparation of butadiene, and the catalyst comprising Hf and two or more further catalytically active metals M1 and M2, wherein the two or more further catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2.

Abstract translation: 提供催化剂和制备丁二烯的方法，以及包含Hf和两种或更多种其它催化活性金属M1和M2的催化剂，其中两种或更多种其它催化活性金属M1和M2选自Zr， Zn，Cu及其两种或更多种的组合，其中M1不同于M2。

公开(公告)号：WO2010100203A3

公开(公告)日：2010-11-18

申请号：PCT/EP2010052713

申请日：2010-03-03

Applicant: BASF SE ,  TOKYO INST TECH ,  YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  XIAO FENG-SHOU ,  GIES HERMANN ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  TATSUMI TAKASHI

Inventor： YILMAZ BILGE ,  MUELLER ULRICH ,  PFAFF MEIKE ,  XIAO FENG-SHOU ,  GIES HERMANN ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  TATSUMI TAKASHI

IPC: B01J29/06 ,  C01B33/38 ,  C01B39/04

CPC classification number: C01B33/20 ,  B01J21/16 ,  B01J29/061 ,  B01J29/70 ,  B01J35/002 ,  C01B33/38 ,  C01B37/00 ,  C01B39/02 ,  C01B39/04 ,  C07C1/20 ,  C07C209/16 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C211/04

Abstract: A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.

Abstract translation: 一种制备同形取代的层状硅酸盐的方法，该方法包括（1）提供含二氧化硅或其前体，至少一种允许层状硅酸盐结晶的结构导向剂（SDA）和水的混合物; （2）在水热条件下加热根据（1）得到的混合物; （3）向至少一个源添加至少一个适于同晶取代的元素; （4）在水热条件下加热根据（3）得到的混合物。

公开(公告)号：ZA201107110B

公开(公告)日：2012-12-27

申请号：ZA201107110

申请日：2011-09-29

Applicant: BASF SE ,  TOKYO INST TECH

Inventor： YILMAZ BILGE ,  MULLER ULRICH ,  PFAFF MEIKE ,  XIAO FENG-SHOU ,  GIES HERMANN ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING ,  TATSUMI TAKASHI

IPC: C01B20060101 ,  B01J20060101

Abstract: A process for the preparation of an isomorphously substituted layered silicate comprising (1) providing a mixture containing silica or a precursor thereof, at least one structure directing agent (SDA) allowing for the crystallization of the layered silicate, and water; (2) heating the mixture obtained according to (1) under hydrothermal conditions; (3) adding at least one source at least one element suitable for isomorphous substitution; (4) heating the mixture obtained according to (3) under hydrothermal conditions.

公开(公告)号：ES2907869T3

公开(公告)日：2022-04-26

申请号：ES17771684

申请日：2017-09-05

Applicant: BASF SE

Inventor： PARVULESCU ANDREI-NICOLAE ,  MÜLLER ULRICH ,  MAURER STEFAN ,  DAI YU ,  XIAO FENG-SHOU ,  MENG XIANGJU ,  WANG YEQING

IPC: C01B37/00 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  C01B39/12 ,  C01B39/48

Abstract: Un proceso para la producción de un material zeolítico que tiene una estructura de entramado MWW que comprende YO2 y B2O3, en donde Y es Si, dicho proceso comprende: (i) preparar una mezcla que comprende una o más fuentes de YO2, una o más fuentes de B2O3, una o más organoplantillas, y cristal germen, (ii) cristalizar la mezcla obtenida en (i) para obtener un precursor laminar de la estructura de entramado MWW, (iii) calcinar el precursor laminar obtenido en (ii) para obtener el material zeolítico que tiene una estructura de entramado MWW, en donde una o más organoplantillas tienen la fórmula (I) R1R2R3N (I) en donde R1 es ciclohexilo, y en donde R2 y R3 son, independientemente, H, y en donde la mezcla preparada en (i) y cristalizada en (ii) contiene 35 % en peso o menos de H2O basado en el 100 % en peso de YO2 contenido en la mezcla preparada en (i) y cristalizada en (ii), en donde el precursor laminar obtenido en (ii) es B-MCM-22(P). en donde el material zeolítico que tiene una estructura de entramado MWW obtenido en iii) es B-MCM-22, en donde la mezcla preparada en (i) y cristalizada en (ii) contiene 5 % en peso o menos de fluoruro calculado como elemento y basado en el 100 % en peso de YO2.

公开(公告)号：ZA201107111B

公开(公告)日：2012-12-27

申请号：ZA201107111

申请日：2011-09-29

Applicant: BASF SE ,  TOKYO INST TECH

Inventor： YILMAZ BILGE ,  MULLER ULRICH ,  PFAFF MEIKE ,  GIES HERMANN ,  XIAO FENG-SHOU ,  TATSUMI TAKASHI ,  DE VOS DIRK ,  BAO XINHE ,  ZHANG WEIPING

IPC: C01B20060101

Abstract: The present invention relates to a process for the preparation of a layered silicate containing at least silicon and oxygen, comprising (1) providing a mixture containing silica and/or at least one silica precursor, water, at least one tetraalkylammonium compound selected from the group consisting of diethyldimethylammonium compound, a triethylmethylammonium compound, and a mixture of a diethyldimethylammonium and a triethylmethylammonium compound, and at least one base, and optionally at least one suitable seeding material; and (2) heating of the mixture obtained according to (1) under autogenous pressure (hydrothermal conditions) to a temperature in the range of from to 120 to 160° C. for a period in the range of from 5 to 10 days to give a suspension containing the layered silicate.