公开(公告)号：EP1623761B1

公开(公告)日：2013-04-03

申请号：EP05020644.0

申请日：2003-02-13

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Tonkovich, Anna Lee Y. ,  Neagle, Paul W. ,  Roberts, Gary ,  Qiu, Dongming ,  Fitzgerald, Sean P. ,  Schmidt, Matthew

IPC: B01F5/06

CPC classification number: F28F3/048 ,  B01F5/0604 ,  B01F5/061 ,  B01F5/0614 ,  B01F13/0059 ,  B01F2005/0621 ,  B01F2005/0632 ,  B01J19/0093 ,  B01J23/44 ,  B01J23/58 ,  B01J23/6522 ,  B01J35/06 ,  B01J37/0205 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0226 ,  B01J37/0238 ,  B01J37/0244 ,  B01J37/0248 ,  B01J2219/00783 ,  B01J2219/00804 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00889 ,  B01L2300/0887 ,  B01L2300/18 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1035 ,  C01B2203/1047 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  F28D9/005 ,  F28D9/0075 ,  F28D2021/0064 ,  F28D2021/0071 ,  F28F3/086 ,  F28F9/0278 ,  F28F13/187 ,  F28F2250/102 ,  F28F2260/02 ,  Y02P20/52 ,  Y10T29/49345 ,  Y10T29/4935 ,  Y10T29/49396 ,  Y10T428/24322

公开(公告)号：EP1568412A1

公开(公告)日：2005-08-31

申请号：EP05007860.9

申请日：2000-08-17

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Tonkovich, Anna Lee Y. ,  Wang, Yong ,  Fitzgerald, Sean P. ,  Marco, Jennifer L. ,  Roberts, Gary L. ,  Vanderwiel, David P. ,  Wegeng, Robert S.

IPC: B01J19/00 ,  C01B3/38 ,  C01B3/50 ,  C01B13/02 ,  B01J12/00

CPC classification number: C01B3/384 ,  B01J12/007 ,  B01J19/0093 ,  B01J23/58 ,  B01J23/60 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/031 ,  B01J2219/00159 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/00873 ,  B01J2219/00907 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2465 ,  B01J2219/2474 ,  B01J2219/2475 ,  B01J2219/2479 ,  B01J2219/2482 ,  B01J2219/2497 ,  C01B3/38 ,  C01B3/501 ,  C01B13/0251 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/041 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/065 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0833 ,  C01B2203/0838 ,  C01B2203/1005 ,  C01B2203/1011 ,  C01B2203/1029 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/1276 ,  C01B2203/1288 ,  C01B2203/148 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/1652 ,  C01B2203/1676 ,  C01B2210/0046 ,  H01M8/0612 ,  Y02P20/128 ,  Y02P20/52

Abstract: The present invention relates to methods for gas phase reactant catalytic reactions. In particular the present invention relates to a method of hydrocarbon steam reforming, comprising:

passing a reactant stream comprising steam and hydrocarbon into at least one reaction chamber;
   wherein the reaction chamber has an internal volume having dimensions of chamber height, chamber width and chamber length;
   wherein the chamber has a length of greater than 1 cm;
   wherein the chamber height or chamber width is 2 mm or less;
   wherein the reaction chamber is in thermal contact through a reaction chamber wall with an exothermic reaction chamber;
   transferring heat from the exothermic reaction chamber to the reaction chamber through the reaction chamber wall at a rate such that heat flux between the reaction chamber and the exothermic reaction chamber is at least 0.6 W per cubic centimeter of the reaction chamber wall;
   wherein the method is controlled under conditions such that the hydrocarbon has a contact time of less than 300 ms;
   wherein the reactant stream is converted to a product stream; and
   wherein at least 70% of the equilibrium conversion of the hydrocarbon entering the reaction chamber is converted to hydrogen, carbon monoxide or carbon dioxide.

Abstract translation: 本发明涉及气相反应物催化反应的方法。 特别地，本发明涉及一种烃蒸汽重整方法，包括：将包含蒸汽和烃的反应物流通入至少一个反应室中; 其中所述反应室具有具有室高度，室宽度和室长度的尺寸的内部容积; 其中所述腔室具有大于1cm的长度; 其中室高度或室宽度为2mm或更小; 其中所述反应室通过反应室壁与放热反应室热接触; 通过反应室壁将热量从放热反应室传递到反应室，反应室和放热反应室之间的热通量至少为每立方厘米反应室壁0.6W; 其中所述方法在使得所述烃具有小于300ms的接触时间的条件下进行控制; 其中所述反应物流被转化成产物流; 并且其中进入反应室的烃的至少70％的平衡转化率转化为氢气，一氧化碳或二氧化碳。

公开(公告)号：EP1568412B1

公开(公告)日：2012-05-09

申请号：EP05007860.9

申请日：2000-08-17

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Tonkovich, Anna Lee Y. ,  Wang, Yong ,  Fitzgerald, Sean P. ,  Marco, Jennifer L. ,  Roberts, Gary L. ,  Vanderwiel, David P. ,  Wegeng, Robert S.

IPC: B01J19/00 ,  C01B3/38 ,  C01B3/50 ,  C01B13/02 ,  B01J12/00

CPC classification number: C01B3/384 ,  B01J12/007 ,  B01J19/0093 ,  B01J23/58 ,  B01J23/60 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/031 ,  B01J2219/00159 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/00873 ,  B01J2219/00907 ,  B01J2219/00984 ,  B01J2219/2453 ,  B01J2219/2465 ,  B01J2219/2474 ,  B01J2219/2475 ,  B01J2219/2479 ,  B01J2219/2482 ,  B01J2219/2497 ,  C01B3/38 ,  C01B3/501 ,  C01B13/0251 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/041 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/065 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0833 ,  C01B2203/0838 ,  C01B2203/1005 ,  C01B2203/1011 ,  C01B2203/1029 ,  C01B2203/1035 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/1276 ,  C01B2203/1288 ,  C01B2203/148 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/1652 ,  C01B2203/1676 ,  C01B2210/0046 ,  H01M8/0612 ,  Y02P20/128 ,  Y02P20/52

公开(公告)号：EP1623761A1

公开(公告)日：2006-02-08

申请号：EP05020644.0

申请日：2003-02-13

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： Tonkovich, Anna Lee Y. ,  Neagle, Paul W. ,  Roberts, Gary ,  Qiu, Dongming ,  Fitzgerald, Sean P. ,  Schmidt, Matthew

IPC: B01L3/00 ,  B81B1/00

CPC classification number: F28F3/048 ,  B01F5/0604 ,  B01F5/061 ,  B01F5/0614 ,  B01F13/0059 ,  B01F2005/0621 ,  B01F2005/0632 ,  B01J19/0093 ,  B01J23/44 ,  B01J23/58 ,  B01J23/6522 ,  B01J35/06 ,  B01J37/0205 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0226 ,  B01J37/0238 ,  B01J37/0244 ,  B01J37/0248 ,  B01J2219/00783 ,  B01J2219/00804 ,  B01J2219/00822 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00889 ,  B01L2300/0887 ,  B01L2300/18 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1035 ,  C01B2203/1047 ,  C01B2203/1064 ,  C01B2203/1082 ,  C01B2203/1241 ,  F28D9/005 ,  F28D9/0075 ,  F28D2021/0064 ,  F28D2021/0071 ,  F28F3/086 ,  F28F9/0278 ,  F28F13/187 ,  F28F2250/102 ,  F28F2260/02 ,  Y02P20/52 ,  Y10T29/49345 ,  Y10T29/4935 ,  Y10T29/49396 ,  Y10T428/24322

Abstract: New designs, methods and processes are described that in which laminated devices and configured in a style named the "ortho" style. To form a device in the ortho style, plates or sheets are machined to have apertures and then stacked together such that the apertures connect and fluid can flow through the device in a direction that is substantially parallel to the direction of sheet thickness. Various laminated devices and processes using them are also described. For example, devices in which non-rectangular microchannels conform around reaction chambers or other bodies that need to be heated or cooled, are described. Features that separate or trip boundary layer and enhance heat transfer are also described.

Abstract translation: 描述了新的设计，方法和过程，其中层压装置并且被配置为称为“邻”风格的风格。 为了形成邻近的装置，将板或片加工成具有孔，然后堆叠在一起，使得孔连接，并且流体可以在基本上平行于板厚度的方向上流过装置。 还描述了使用它们的各种层压装置和方法。 例如，描述了其中非矩形微通道与反应室或需要被加热或冷却的其它物体一致的装置。 还描述了分离或离开边界层并增强热传递的特征。