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公开(公告)号：WO02066371A3
公开(公告)日：2003-03-06
申请号：PCT/US0204479
申请日：2002-02-15
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： WANG YONG , TONKOVICH ANNA LEE Y , VANDERWIEL DAVID P
IPC: B01J23/46 , B01J12/00 , B01J19/00 , B01J21/00 , B01J21/10 , B01J23/00 , B01J23/40 , B01J23/58 , B01J27/22 , B01J35/04 , B01J35/06 , B01J35/10 , B01J37/02 , C01B3/38 , C01B3/40 , C01B3/50 , C01B13/02 , C01B32/60 , H01M8/06
CPC classification number: B01J12/007 , B01J19/0093 , B01J21/005 , B01J21/10 , B01J23/005 , B01J23/40 , B01J23/464 , B01J23/58 , B01J27/22 , B01J35/06 , B01J37/0207 , B01J37/0225 , B01J37/0244 , B01J37/0248 , B01J2219/00788 , B01J2219/00826 , B01J2219/00835 , B01J2219/00873 , B01J2219/00891 , B01J2219/00961 , B01J2219/2453 , B01J2219/2465 , B01J2219/2474 , B01J2219/2475 , B01J2219/2479 , B01J2219/2482 , B01J2219/2497 , C01B3/38 , C01B3/40 , C01B3/501 , C01B13/0251 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/047 , C01B2203/065 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0833 , C01B2203/1005 , C01B2203/1011 , C01B2203/1029 , C01B2203/1035 , C01B2203/1041 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1217 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/1288 , C01B2203/148 , C01B2203/1604 , C01B2203/1619 , C01B2203/1652 , C01B2203/1676 , C01B2203/169 , C01B2203/80 , H01M8/0612 , Y02P20/52
Abstract: The present invention provides a method of steam reforming a hydrocarbon over a catalyst at short residence times or short contact times. The present invention also provides spinel-containing catalysts. Surprisingly superior results and properties obtained in methods and catalysts of the present invention are also described.
Abstract translation: 本发明提供一种在短的停留时间或短的接触时间下在催化剂上蒸汽重整烃的方法。 本发明还提供了含尖晶石的催化剂。 还描述了在本发明的方法和催化剂中获得的令人惊奇的优异结果和性能。
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公开(公告)号：WO0112323A2
公开(公告)日：2001-02-22
申请号：PCT/US0022422
申请日：2000-08-15
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： WANG YONG , VANDERWIEL DAVID P , TONKOVICH ANNA LEE Y , GAO YUFEI , BAKER EDDIE G
IPC: B01J8/02 , B01J12/00 , B01J19/24 , B01J23/89 , B01J35/00 , B01J35/10 , B01J37/02 , C07B61/00 , C07C1/04 , C07C9/02 , C07C9/04 , C07C9/15 , C10G2/00
CPC classification number: B01J23/8913 , B01J8/0285 , B01J12/007 , B01J19/248 , B01J23/462 , B01J23/75 , B01J35/0006 , B01J35/002 , B01J35/04 , B01J35/10 , B01J35/1009 , B01J37/0221 , B01J37/0238 , B01J37/0244 , B01J2219/32293 , B01J2219/32296 , B01J2219/32408 , B01J2219/32466 , B01J2219/32475 , C07C1/041 , C07C1/0425 , C07C1/0455 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C10G2/33 , C10G2/332
Abstract: The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.
Abstract translation: 本发明包括费 - 托催化剂，使用费 - 托催化剂的反应，制造费 - 托催化剂的方法，氢化一氧化碳的方法以及使用这些方法制备的燃料。 本发明提供了以低接触时间氢化一氧化碳的能力，良好的转化率和低的甲烷选择性。 在优选的方法中，催化剂使用金属泡沫载体制成。
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公开(公告)号：ES2386506T3
公开(公告)日：2012-08-22
申请号：ES05007860
申请日：2000-08-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： TONKOVICH ANNA LEE Y , WANG YONG , FITZGERALD SEAN P , MARCO JENNIFER L , ROBERTS GARY L , VANDERWIEL DAVID P , WEGENG ROBERT S
IPC: B01D53/22 , B01J19/00 , B01D71/02 , B01J12/00 , B01J19/24 , B01J23/60 , B01J37/02 , B01J37/03 , C01B3/38 , C01B3/48 , C01B3/50 , C01B3/56 , C01B13/02 , H01M8/06
Abstract: Método de reformado con vapor de hidrocarburo, comprendiendo:paso de una corriente de reactivos comprendiendo vapor e hidrocarburo en al menos una cámara de reacción;donde la cámara de reacción tiene un volumen interno con dimensiones de altura de cámara, anchura decámara y longitud de cámara;donde la cámara tiene una longitud mayor de 1 cm;donde la altura de cámara o anchura de cámara es de 2 mm o menos;donde la cámara de reacción tiene una entrada y una salida con una trayectoria de flujo en masa contiguodesde la entrada hasta la salida;donde la cámara de reacción está en contacto térmico a través de una pared de cámara de reacción con unacámara de reacción exotérmica;transferencia de calor desde la cámara de reacción exotérmica hasta la cámara de reacción a través de lapared de cámara de reacción;donde el método es controlado bajo condiciones de manera que el hidrocarburo tiene un tiempo de contactoinferior a 300 ms;donde la corriente de reactivos se convierte en un flujo de producto; ydonde al menos 70% de la conversión de equilibrio del hidrocarburo entrando en la cámara de reacción seconvierte a hidrógeno, monóxido de carbono o dióxido de carbono.
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公开(公告)号：NO330178B1
公开(公告)日：2011-02-28
申请号：NO20084211
申请日：2008-10-08
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： WEGENG ROBERT S , ROBERTS GARY L , WANG YONG , VANDERWIEL DAVID P , TONKOVICH ANNA LEE Y , FITZGERALD SEAN P , MARCO JENNIFER L
IPC: B01D53/22 , B01J12/00 , B01D71/02 , B01J19/00 , B01J19/24 , B01J23/60 , B01J37/02 , B01J37/03 , C01B3/38 , C01B3/48 , C01B3/50 , C01B3/56 , C01B13/02 , H01M8/06
Abstract: The present invention relates to methods for gas phase reactant catalytic reactions. In particular the present invention relates to a method of hydrocarbon steam reforming, comprising: passing a reactant stream comprising steam and hydrocarbon into at least one reaction chamber; wherein the reaction chamber has an internal volume having dimensions of chamber height, chamber width and chamber length; wherein the chamber has a length of greater than 1 cm; wherein the chamber height or chamber width is 2 mm or less; wherein the reaction chamber is in thermal contact through a reaction chamber wall with an exothermic reaction chamber; transferring heat from the exothermic reaction chamber to the reaction chamber through the reaction chamber wall at a rate such that heat flux between the reaction chamber and the exothermic reaction chamber is at least 0.6 W per cubic centimeter of the reaction chamber wall; wherein the method is controlled under conditions such that the hydrocarbon has a contact time of less than 300 ms; wherein the reactant stream is converted to a product stream; and wherein at least 70% of the equilibrium conversion of the hydrocarbon entering the reaction chamber is converted to hydrogen, carbon monoxide or carbon dioxide.
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公开(公告)号：AU2005200564B2
公开(公告)日：2008-01-10
申请号：AU2005200564
申请日：2005-02-09
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： TONKOVICH ANNA LEE Y , VANDERWIEL DAVID P , GAO YUFEI , WANG YONG , BAKER EDDIE G
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Patent Agency Ranking
公开(公告)号：AU779528B2
公开(公告)日：2005-01-27
申请号：AU6643400
申请日：2000-08-15
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： WANG YONG , VANDERWIEL DAVID P , TONKOVICH ANNA LEE Y
Abstract: The present invention includes an improvement to the existing method of steam reforming of hydrocarbon, wherein the improvement comprises: the flowing is at a rate providing a residence time less than about 0.1 sec resulting in obtaining product formation yield or amount that is the same or greater compared to product formation at a longer residence time. Another improvement of the present invention is operation at a steam to carbon ratio that is substantially stoichiometric and maintaining activity of the supported catalyst. The present invention also includes a catalyst structure for steam reforming of a hydrocarbon.
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公开(公告)号：ZA200200864B
公开(公告)日：2003-04-30
申请号：ZA200200864
申请日：2002-01-30
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： TONKOVICH ANNA LEE Y , FITZGERALD SEAN P , ROBERTS GARY L , WEGENG ROBERT S , WANG YONG , MARCO JENNIFER L , VANDERWIEL DAVID P
IPC: B01D53/22 , B01D71/02 , B01J12/00 , B01J19/00 , B01J19/24 , B01J23/60 , B01J37/02 , B01J37/03 , C01B3/38 , C01B3/48 , C01B3/50 , C01B3/56 , C01B13/02 , H01M8/06 , B01J , C01B
Abstract: The present invention relates to methods for gas phase reactant catalytic reactions. In particular the present invention relates to a method of hydrocarbon steam reforming, comprising: passing a reactant stream comprising steam and hydrocarbon into at least one reaction chamber; wherein the reaction chamber has an internal volume having dimensions of chamber height, chamber width and chamber length; wherein the chamber has a length of greater than 1 cm; wherein the chamber height or chamber width is 2 mm or less; wherein the reaction chamber is in thermal contact through a reaction chamber wall with an exothermic reaction chamber; transferring heat from the exothermic reaction chamber to the reaction chamber through the reaction chamber wall at a rate such that heat flux between the reaction chamber and the exothermic reaction chamber is at least 0.6 W per cubic centimeter of the reaction chamber wall; wherein the method is controlled under conditions such that the hydrocarbon has a contact time of less than 300 ms; wherein the reactant stream is converted to a product stream; and wherein at least 70% of the equilibrium conversion of the hydrocarbon entering the reaction chamber is converted to hydrogen, carbon monoxide or carbon dioxide.
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公开(公告)号：BR0013342A
公开(公告)日：2002-06-11
申请号：BR0013342
申请日：2000-08-17
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： TONKOVICH ANNA LEE Y , WANG YONG , FITZGERALD SEAN P , MARCO JENNIFER L , ROBERTS GARY L , VANDERWIEL DAVID P , WEGENG ROBERT S
IPC: B01D53/22 , B01D71/02 , B01J12/00 , B01J19/00 , B01J19/24 , B01J23/60 , B01J37/02 , B01J37/03 , C01B3/38 , C01B3/48 , C01B3/50 , C01B3/56 , C01B13/02 , H01M8/06
Abstract: The present invention provides chemical reactors and reaction chambers and methods for conducting catalytic chemical reactions having gas phase reactants. In preferred embodiments, these reaction chambers and methods include at least one porous catalyst material that has pore sizes large enough to permit molecular diffusion within the porous catalyst material.
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公开(公告)号：NO20020587L
公开(公告)日：2002-04-10
申请号：NO20020587
申请日：2002-02-06
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： TONKOVICH ANNA LEE Y , WANG YONG , FITZGERALD SEAN P , MARCO JENNIFER L , ROBERTS GARY L , VANDERWIEL DAVID P , WEGENG ROBERT S
IPC: B01D71/02 , B01J12/00 , B01D53/22 , B01J19/00 , B01J19/24 , B01J23/60 , B01J37/02 , B01J37/03 , C01B3/38 , C01B3/48 , C01B3/50 , C01B3/56 , C01B13/02 , H01M8/06 , B01J35/10
Abstract: The present invention provides chemical reactors and reaction chambers and methods for conducting catalytic chemical reactions having gas phase reactants. In preferred embodiments, these reaction chambers and methods include at least one porous catalyst material that has pore sizes large enough to permit molecular diffusion within the porous catalyst material.
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公开(公告)号：NO20020419L
公开(公告)日：2002-04-09
申请号：NO20020419
申请日：2002-01-28
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： WANG YONG , VANDERWIEL DAVID P , TONKOVICH ANNA LEE Y
Abstract: The present invention includes an improvement to the existing method of steam reforming of hydrocarbon, wherein the improvement comprises: the flowing is at a rate providing a residence time less than about 0.1 sec resulting in obtaining product formation yield or amount that is the same or greater compared to product formation at a longer residence time. Another improvement of the present invention is operation at a steam to carbon ratio that is substantially stoichiometric and maintaining activity of the supported catalyst. The present invention also includes a catalyst structure for steam reforming of a hydrocarbon.
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