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    METHOD OF FORMING A DIANHYDROSUGAR ALCOHOL
    3.
    发明申请
    METHOD OF FORMING A DIANHYDROSUGAR ALCOHOL 审中-公开
    形成二醛醇的方法

    公开(公告)号：WO2007089527B1

    公开(公告)日：2008-03-06

    申请号：PCT/US2007001996

    申请日：2007-01-25

    Applicant: BATTELLE MEMORIAL INSTITUTE ,  HOLLADAY JOHNATHAN ,  WERPY TODD A ,  HU JIANLI ,  WANG YONG ,  ZHANG XINJIE

    Inventor： HOLLADAY JOHNATHAN ,  WERPY TODD A ,  HU JIANLI ,  WANG YONG ,  ZHANG XINJIE

    IPC: C07D493/04

    CPC classification number: C07D307/20 ,  C07D493/04 ,  Y02P20/127

    Abstract: The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.

    Abstract translation: 本发明包括生产二脱水糖的方法。 多元醇在第一催化剂存在下反应形成单环糖。 将单环糖转移到第二反应器中，在第二反应器中在第二催化剂的存在下将其转化成二水糖醇。 本发明包括形成异山梨醇的方法。 初始反应在固体酸催化剂存在下的第一温度下进行。 最初的反应包括使山梨糖醇反应生成1,4-脱水山梨糖醇，3,6-脱水山梨糖醇，2,5-甘露糖醇和2,5-戊二酸。 利用第二温度，1,4-脱水山梨糖醇和3,6-脱水山梨糖醇转化为异山梨醇。 本发明包括从含有异山梨醇和至少一种附加组分的混合物中纯化异山梨醇的方法。 第一次蒸馏从混合物中除去第一部分异山梨醇。 然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分异山梨醇。

    METHODS OF MAKING PYRROLIDONES
    6.
    发明申请
    METHODS OF MAKING PYRROLIDONES 审中-公开
    制备吡咯烷酮的方法

    公开(公告)号：WO02102772B1

    公开(公告)日：2003-11-20

    申请号：PCT/US0219372

    申请日：2002-06-17

    Applicant: BATTELLE MEMORIAL INSTITUTE

    Inventor： WERPY TODD ,  FRYE JOHN G JR ,  WANG YONG ,  ZACHER ALAN H

    IPC: C07D207/26 ,  C07D207/267

    CPC classification number: C07D207/267 ,  C07D201/02 ,  C07D201/08

    Abstract: The present invention provides methods for making N-methylpyrrolidine and analogous compounds via hydrogenation. Novel catalysts for this process, and novel conditions/yields are also described. Other process improvements may include extraction and hydrolysis steps. Some preferred reactions take place in the aqueous phase. Starting materials for making N-methylpyrrolidine may include succinic acid, N-methylsuccinimide, and their analogs.

    Abstract translation: 本发明提供了通过氢化制备N-甲基吡咯烷和类似化合物的方法。 还描述了用于该方法的新型催化剂和新的条件/收率。 其他工艺改进可以包括提取和水解步骤。 一些优选的反应发生在水相中。 用于制备N-甲基吡咯烷的原料可包括琥珀酸，N-甲基琥珀酰亚胺及其类似物。

    METHODS FOR DEHYDRATION OF SUGARS
    9.
    发明申请
    METHODS FOR DEHYDRATION OF SUGARS 审中-公开
    蔗糖脱水方法

    公开(公告)号：WO2007089510A3

    公开(公告)日：2008-01-17

    申请号：PCT/US2007001945

    申请日：2007-01-24

    Applicant: BATTELLE MEMORIAL INSTITUTE ,  HOLLADAY JOHNATHAN E ,  HU JIANLI ,  ZHANG XINJIE ,  WANG YONG

    Inventor： HOLLADAY JOHNATHAN E ,  HU JIANLI ,  ZHANG XINJIE ,  WANG YONG

    IPC: C07D493/04 ,  C07H1/00 ,  C07H3/10 ,  C08G63/672

    CPC classification number: C07D493/04

    Abstract: The invention includes a method of dehydration of a sugar using a dehydration catalyst and a co-catalyst within a reactor. A sugar is introduced and H 2 is flowed through the reactor at a pressure of less than or equal to about 300 psig to convert at least some of the sugar into an anhydrosugar product. The invention includes a process for producing isosorbide. A starting material comprising sorbitol is flowed into a reactor. H 2 is counter flowed through the reactor. The starting material is exposed to a catalyst in the presence of a co- catalyst which comprises at least one metal. The exposing is conducted at a hydrogen pressure of less than or equal to 300 psig within the reactor and the hydrogen removes at least some of any water present during the exposing and inhibits formation of colored byproducts.

    Abstract translation: 本发明包括使用反应器内的脱水催化剂和助催化剂使糖脱水的方法。 引入糖，并且H 2 O 2以小于或等于约300psig的压力流过反应器，以将至少一些糖转化为脱水糖产物。 本发明包括制备异山梨醇的方法。 将含有山梨醇的原料流入反应器。 H 2反向流过反应器。 在包含至少一种金属的助催化剂的存在下，将原料暴露于催化剂。 暴露在反应器内在小于或等于300psig的氢气压力下进行，并且氢去除暴露期间存在的任何水中的至少一些，并且抑制着色副产物的形成。

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