Abstract:
PROBLEM TO BE SOLVED: To obtain a purified organic isocyanate or the like useful for producing a prepolymer or the like by adding a specific anion exchange organic substance to an organic isocyanate or a mixture of isocyanates and then by the heatup under a specific pressure for a specific period of time to remove chlorine compounds. SOLUTION: This method is to bring a gel-type porous anion exchange organic substance (e.g. Lewatit3MP62) not containing metal ions, water and a solvent and having a tertiary and/or quaternary amino group into contact with a chlorine-containing isocyanate (e.g. 4-isocyanatomethyl-1,8- octanediisocyanate) at a temp. of preferably 150-180 deg.C for preferably 3-15 h. to obtain a chlorine content-lessened isocyanate. The anion exchange organic substance is applied in an amount of at least 0.1 wt.%, preferably 1.0-10.0 wt.% based on the weight of an isocyanate. The content of hydrolyzable chlorine separated from the anion exchange substance is
Abstract:
PROBLEM TO BE SOLVED: To provide a monodisperse anion exchanger accompanied by the mechanical and penetration stability of beads, the low pressure drop of a bead bed and the lower consumption of cleaning water in use. SOLUTION: A method for manufacturing the monodisperse, weakly basic, or in some cases, strongly basic anion exchanger of a poly(meth)acrylamide type, the ion exchangers themselves and the provision thereof are privided. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To obtain a heterodisperse chelating resin suitable for removal of absorption of a metal compound and having high stability at high capacity, to ensure that the resin can be used for many years with the associated repeated regeneration, and without any use of toxicologically questionable starting materials. SOLUTION: This method for preparing the heterodisperse chelating resin comprises (a) reacting monomer droplets prepared from at least one monovinylaromatic compound and at least one polyvinylaromatic compound, a foaming agent and an initiator or an initiator combination, wherein the initiator is a peroxycarbonate, a perester, or a peroxyester, to give a heterodisperse crosslinked bead polymer, (b) amidomethylating the heterodisperse crosslinked bead polymer with a phthalimide derivative, (c) reacting the amidomethylated bead polymer to afford an amino-methylated bead polymer, and (d) functionalizing the aminomethylated bead polymer to give a bead polymer containing chelating groups.
Abstract:
PROBLEM TO BE SOLVED: To remove arsenic (V) compounds, more particularly hexafluoro arseneate compounds from the distillation bottom residues from preparation of hydrogen fluoride under cost-effective conditions and converting these compounds to the form that the compounds can be disposed to the ground in reclamation lands. SOLUTION: The novel method for removing the arsenic compounds by an anion exchanger functionalized by amino/ammonium from the distillation bottom residues obtained in refining of the hydrogen fluoride by distillation is provided.
Abstract:
PROBLEM TO BE SOLVED: To provide an ion exchanger which is particularly suitable for arsenic ions and/or antimony ions, selectively removes the arsenic ions and/or the antimony ions from a reaction solution during a synthesizing process step, surely functions for a long period of time at a relatively high temperature and is eventually capable of returning and releasing the water from a process circulating system into the environment. SOLUTION: The monodisperse ion exchanger, more particularly the monodisperse anion exchanger for selective removal of the arsenic/and or antimony in the form of AsF6- ions or SbF6- ions from an aqueous solution or the use of a monodisperse chelate resin.
Abstract:
PROBLEM TO BE SOLVED: To provide a method of sulfonation for a large porous bead polymer and a monodisperse gel type bead polymer whereby the improved osmotic pressure and the mechanical stability, which are required to conform with the current standard, are given to a sulfonated product. SOLUTION: The invention relates to a method for producing an ion exchanger of large porous and strong-acid, or strong-acid and monodisperse gel type, especially the exchanger of large porous and monodisperse, large porous and heterodisperse, or monodisperse gel type by effecting each polymer with a sulfuric acid stepwise through cycles with making the concentration gradient, a cation exchanger produced by the method and use of the same.
Abstract:
PROBLEM TO BE SOLVED: To provide a process for preparing a monodisperse anion exchanger, preferably a monodisperse, large-pores anion exchanger which has a high mechanical and permeation stability of particles, has an increased absorptive power for anions, requires a reduced amount of resources for preparing the anion-exchanger itself and has a highly pure function basic group and can be prepared in a high yield. SOLUTION: In a process for preparing a monodisperse anion exchanger, (a) monomer droplets prepared from at least one monovinyl aromatic compound and at least one polyvinyl aromatic compound are allowed to undergo a reaction to generate a crosslinked monodisperse bead polymer, (b) this monodisperse bead polymer is subjected to amidomethylation using a phthalimide derivative, (c) this amidomethylated bead polymer is allowed to undergo a reaction to generate an aminomethylated bead polymer, and (d) this aminomethylated bead polymer is alkylated.
Abstract:
PROBLEM TO BE SOLVED: To provide a gel-type cation exchange resin having high mechanical and osmotic stability and improved resistance to oxidation. SOLUTION: Crosslinked polystyrene polymer beads containing 3.5-7 wt.% crosslinking agent are used as a base polymer and the base polymer is swollen in a monomer mixture of a vinyl monomer, a crosslinking agent and a free radical initiator. The monomer mixture thereof is polymerized in the base polymer and the copolymer obtained is sulfonated to produce the gel type cation exchange resin.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for causing a gas, especially an acidic gas, to be adsorbed by a monodisperse aminomethylated bead polymer. SOLUTION: This method causes a gas, especially an acidic gas, to be adsorbed by a monodisperse aminomethylated bead polymer which has a porosity of 40-60% and is prepared by aminomethylating a polymer formed basing upon at least one aromatic monovinyl compound and at least one aromatic polyvinyl compound.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for manufacturing an ion-exchanger, preferably a weakly acidic ion-exchanger, having a homogeneous network structure, on the basis of an unsaturated aliphatic nitrile and in the presence of a film-forming protective colloid. SOLUTION: In this manufacturing method, (a) an unsaturated aliphatic nitrile polymerizes with a divinyl or polyvinyl ether acting as a crosslinking agent and then polymerizes with the initiator in a suspension to produce polymer beads not in a seed feeding process but in the presence of a protective colloid, and (b) the beads are functionalized into ion exchangers.