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公开(公告)号:JP2000140653A
公开(公告)日:2000-05-23
申请号:JP31683199
申请日:1999-11-08
Applicant: BAYER AG
Inventor: PODSZUN WOLFGANG , KLIPPER REINHOLD , MARTIN GEORG , HALLE OLAF , STRUEVER WERNER , MITSCHKER ALFRED , SEIDEL RUEDIGER , FEISTEL LOTHAR
IPC: B01J41/00 , B01J41/14 , C08F2/44 , C08F257/00 , C08F291/00
Abstract: PROBLEM TO BE SOLVED: To obtain a monodisperse gelatinous anion exchanger with high stability and high purity by constituting a chloromethylated and aminated seed polymer of a crosslinked polymer having a specified range of swelling index and containing a nonvolatile soluble component by
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公开(公告)号:JP2001098019A
公开(公告)日:2001-04-10
申请号:JP2000255812
申请日:2000-08-25
Applicant: BAYER AG
Inventor: KLIPPER REINHOLD DR , STRUEVER WERNER DR , SCHNEGG ULRICG , SEIDEL RUEDIGER DR , MITSCHKER ALFRED , LUETJENS HOLGER DIPL CHEM DR
IPC: B01J39/04 , B01J41/04 , B01J41/14 , C02F1/42 , C08F2/00 , C08F8/00 , C08F8/30 , C08F212/02 , C08F212/34
Abstract: PROBLEM TO BE SOLVED: To provide a process for preparing a monodisperse anion exchanger, preferably a monodisperse, large-pores anion exchanger which has a high mechanical and permeation stability of particles, has an increased absorptive power for anions, requires a reduced amount of resources for preparing the anion-exchanger itself and has a highly pure function basic group and can be prepared in a high yield. SOLUTION: In a process for preparing a monodisperse anion exchanger, (a) monomer droplets prepared from at least one monovinyl aromatic compound and at least one polyvinyl aromatic compound are allowed to undergo a reaction to generate a crosslinked monodisperse bead polymer, (b) this monodisperse bead polymer is subjected to amidomethylation using a phthalimide derivative, (c) this amidomethylated bead polymer is allowed to undergo a reaction to generate an aminomethylated bead polymer, and (d) this aminomethylated bead polymer is alkylated.
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公开(公告)号:JP2001206901A
公开(公告)日:2001-07-31
申请号:JP2000378831
申请日:2000-12-13
Applicant: BAYER AG
Inventor: PODSZUN WOLFGANG DR , FEISTEL LOTHAR , HALLE OLAF DR , SCHMID CLAUDIA , MITSCHKER ALFRED
IPC: B01J39/20 , B01J41/14 , C08F2/00 , C08F2/18 , C08F212/36 , C08F257/02
Abstract: PROBLEM TO BE SOLVED: To provide a method of producing a monodisperse crosslinked bead polymer useful as an ion exchange resin. SOLUTION: This method of producing the monodisperse crosslinked bead polymer is carried out through seed/feed-polymerization, wherein the seed comprising monomer droplets incompletely polymerized, monodispersed, and microencapsulated is used to obtain the objective polymer low in a soluble polymer content.
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公开(公告)号:JP2004035549A
公开(公告)日:2004-02-05
申请号:JP2003124993
申请日:2003-04-30
Applicant: Bayer Ag , バイエル アクチェンゲゼルシャフト
Inventor: GROTH TORSTEN , MITSCHKER ALFRED , MORITZ RALF-JOHANN , KLEIN THOMAS , MENZEL THOMAS , WIRTH WOLFGANG
IPC: A01M1/20 , A01N37/44 , C05D3/00 , C05D5/00 , C05D9/00 , C05D9/02 , C07C227/08 , C07C229/16 , C07C229/24 , C07C229/76 , C09K3/00
CPC classification number: C07C229/76 , A01N37/44 , C05D9/02 , C07C227/08 , C07C229/24 , C05F11/00
Abstract: PROBLEM TO BE SOLVED: To provide a complexing agent without having any toxico-ecological drawback. SOLUTION: This iminodisuccinic acid ammonium metal salt is expressed by formula 8: IDA(NH 4 ) x (Na) y (K) z (Me) m -(NH 3 ) n . The method for producing iminodisuccinic acid ammonium metal salt expressed by formula 8 comprises a first process of mixing maleic anhydride (MA) with an alkali metal hydroxide and water by (2:0-3:5-30) molar ratio, and then blending ammonia by MA:ammonia=(2:1.5-8) molar ratio to obtain iminodisuccinic acid ammonium salt and a second process of performing a reaction by mixing the obtained salt with a metal oxide, metal hydroxide and/or other metal salts or their mixtures. COPYRIGHT: (C)2004,JPO
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公开(公告)号:JP2001106725A
公开(公告)日:2001-04-17
申请号:JP2000248451
申请日:2000-08-18
Applicant: BAYER AG
Inventor: KLIPPER REINHOLD DR , SCHNEGG ULRICG , SEIDEL RUEDIGER DR , SOEST HANS-KARL , MITSCHKER ALFRED , LUETJENS HOLGER DIPL CHEM DR
IPC: A23C9/146 , A23C21/00 , A23J3/06 , A23J3/08 , A23L2/08 , A23L2/78 , A23L27/30 , B01J41/04 , B01J41/14 , C02F1/42 , C08F8/02 , C08F8/30 , C08F212/02 , C08F212/34 , C08F212/36 , C08F220/20 , C08F236/04 , C08J5/20 , C13B20/14 , A23L1/236 , C13D3/14
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a monodisperse anion exchanger having strongly basic functional groups, and to obtain such anion exchanger by the above method, and to provide a usage of such anion exchanger. SOLUTION: This method for producing a new monodisperse anion exchanger with strongly basic functional groups existing in the core or shell of the resin beads comprises amidomethylation of a phthalimide derivative.
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公开(公告)号:BR0304486A
公开(公告)日:2004-08-31
申请号:BR0304486
申请日:2003-10-14
Applicant: BAYER AG , ADOB PRZED PROD CONSULTINGOWE
Inventor: MITSCHKER ALFRED , MORITZ RALF-JOHANN , NAWROCKI ADAM
IPC: C05D9/02 , C07C229/76
Abstract: New chelated trace nutrients (I) for plants comprise the reaction products of at least one complex former (A) selected from sodium, potassium, sodium/ammonium or potassium/ammonium salts of N-(1,2-dicarboxyethyl)-D,L-aspartic acid and metal ions (B) derived from inorganic or organic zinc, manganese, iron (II) or copper (II) compounds. An Independent claim is included for the preparation of chelated plant trace nutrient fertilizers (I'), by reacting a complex former (A') having an imino group and multiple carboxylic acid groups with a compound (B') selected from the chlorides, nitrates, acetates and sulfates of iron, manganese, copper or zinc (or with a corresponding metal hydroxide, carbonate or oxide in presence of an (in)organic acid).
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公开(公告)号:DE19954393A1
公开(公告)日:2001-03-01
申请号:DE19954393
申请日:1999-11-12
Applicant: BAYER AG
Inventor: KLIPPER REINHOLD , STRUEVER WERNER , SCHNEGG ULRICH , SEIDEL RUEDIGER , MITSCHKER ALFRED , LUETJENS HOLGER
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公开(公告)号:DE19817679A1
公开(公告)日:1999-10-28
申请号:DE19817679
申请日:1998-04-21
Applicant: BAYER AG
Inventor: LUETJENS HOLGER , KLIPPER REINHOLD , MARTIN GEORG , MITSCHKER ALFRED , HOLZBRECHER MICHAEL
Abstract: Production of gelatinous anion exchangers with osmotic and mechanical stability comprises aminating crosslinked, gelatinous styrene-divinylbenzene suspension polymers containing haloalkyl groups in the presence of less than 5 wt.% inorganic salt w.r.t. the total amount of water.
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公开(公告)号:HU212975B
公开(公告)日:1997-01-28
申请号:HU9202703
申请日:1992-08-19
Applicant: BAYER AG
Inventor: HELLER HAROLD , HOFFMANN HEIKO , KLIPPER REINHOLD M , MINZ FRANZ-RUDOLF , MITSCHKER ALFRED
Abstract: Weakly basic anion exchangers of the poly(meth)acrylamide type, which have been prepared by aminolysis of poly(meth)acrylonitrile or poly(meth)acrylate with polyamines of a defined composition, have an improved uptake capacity for sulphate ions and are suitable for selective removal of sulphate ions from aqueous liquids, especially from sodium chloride brines and from waste waters.
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公开(公告)号:NO170135C
公开(公告)日:1992-09-16
申请号:NO873098
申请日:1987-07-23
Applicant: BAYER AG
Inventor: OECKL SIEGFRIED , MITSCHKER ALFRED , LANGE PETER MICHAEL , MARTINOLA FRIEDRICH
IPC: B01J31/10 , B01J23/42 , B01J23/44 , B01J31/08 , B01J37/16 , B01J37/30 , C02F1/58 , C07C2/28 , B01J37/02
Abstract: The invention relates to a new process for the preparation of strongly acid cation exchangers loaded with catalytically active metals by loading the cation exchangers with a solution of a salt of the catalytically active metal and reducing the cation exchangers loaded with metal ions, according to which the loading of the cation exchangers is carried out at temperatures from 50 DEG to 120 DEG C. and formic acid is used as the reducing agent; the invention also relates to the catalyst resins which can be obtained by the process.
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