Abstract:
BONDED FIBER FLEECES ARE PROVIDED AND A METHOD FOR THEIIIR PRODUCTION WHICH COMPRISES PREPARING A REACTIVE POLYADDITION REACTION MIXTURE FROM AN ORGANIC POLYISOCYANATE, AND AN ORGANIC COMPOUND CONSISTING AT LEAST TWO HYDROXYL OR AMINO HYDROGEN ATOMS CAPABLE OF REACTING WITH NCO GROUPS AS STARTING COMPONENTS IN AN INERT LIQUID ORGANIC SOLVENT FOR THE STARTING COMPONENTS WHICH BOILS AT A TEMPERATURE OF BELOW ABOUT 250*C. BUT WHICH IS A NON-SOLVENT FOR THE POLYADDITION PRODUCT, WHICH SOLVENT HAS NO SIGNIFICANT SWELLING EFFECT ON A HOMOGENEOUS, NON-POROUS FILM OF THE POLYADDITION PRODUCT AND IS PRESENT IN A QUANTITY WHICH DOES NOT EXCEED THAT WHICH THE POLYADDITION PRODUCT IS CAPABLE OF ENCLOSING AS AN INTERNAL PHASE, APPLYING THE REACTIVE MIXTURE TO AN UNBONDED FLEECE IN A QUANTITY SUFFICIENT TO YIELD FROM 10 TO 500% BY WEIGHT BASED ON THE WEIGHT OF THE FLEECE OF THE POLYADDITION PRODUCT AND TERMINATING THE POLYADDITION REACTION AT A TEMPERATURE OF FROM ABOUT 20* TO ABOUT 200*C. WHILE EVAPORATING THE SOLVENT.
Abstract:
A PROCESS IS PROVIDED FOR THE PRODUCTION OF POLYURETHANE ELASTOMERS BY REACTING HIGHER MOLECULAR WEIGHT HYDROXY COMPOUNDS WHICH HAVE A MOLECULAR WEIGHT OF 800 TO 2500, DIISOCYANATES AND LOW MOLECULAR WEIGHT COMPOUNDS WHICH HAVE A MOLECULAR WEIGHT OF UP TO 400 AND WHICH CONTAIN AT LEAST TWO HYDROGEN ATOMS REACTIVE WITH ISOCYANATES, CHARACTERIZED IN THAT THE HIGHER MOLECULAR WEIGHT HYDROXY COMPOUNDS ARE CONDENSATION PRODUCTS OF 1,6-HEXANE DIOL, ADIPIC ACID AND DIARYL CARBONATE.
Abstract:
MICROPOROUS SHEETS ARE PREPARED BY REACTING AN NCO TERMINATED PREPOLYMER WITH A DISECONDARY DIAMINE IN AN INERT SUBSTANCE THAT DISSOLVES THE REACTANTS BUT CAUSES ONLY SWELLING OF THE PRODUCT THEREOF AND DRYING THE DISPERSIONS THUS FORMED TO FORM MICROPOROUS FOILS.
Abstract:
NOVEL AROMATIC DIAMINES CONTAINING ETHER GROUPS AND HAVING CHLORINE ATOMS IN THE O-POSITION TO THE AMINO GROUPS ARE USEFUL TO PREPARE POLYURETHANE ELASTOMERS THEREFROM WITH AN ORGANIC DIISOCYANATE AND AN ORGANIC COMPOUND CONTAINING AT LEAST TWO HYDROXYL GROUPS AND HAVING A MOLECULAR WEIGHT OF FROM ABOUT 800 TO ABOUT 5000.
Abstract:
Noncellular polyurethane plastics are prepared from organic compounds having hydroxyl groups and a molecular weight from about 800 to about 3,000, organic diisocyanates and 2,3dibromobut-2-ene-1,4-diol. The polyurethane elastomers due to their improved chemical and thermal stability are eminently suitable in the production of molded articles.
Abstract:
A solution of a polyurethane in a polyol is made from (a) the reaction product of a polyisocyanate and a diprimary diol, and (b) a polyether in which the reaction product constitutes from 3 to 60 wt. % of the solution. Suitable diprimary diols have a molecular weight of from 90 to 800 and a structure at both hydroxyl groups corresponding to the general formula: in which R1 represents chlorine, an alkyl, cycloalkyl, aralkyl or aryl radical having from 1 to 10 carbon atoms, which carbon atoms may be substituted or interrupted by chlorine, ester groups, ether groups, amide groups, urethane groups or nitrile groups, and R2 represents hydrogen or a radical within the definition of R1. Polyethers which may be employed have at least two hydroxyl groups (at least 80% of which are secondary hydroxyl groups) and an average molecular weight of from 500 to 12,000. The disclosed solutions are particularly useful in the production of flexible polyurethane plastics which are suitable for flamecoating and high frequency bonding.
Abstract:
A solution of a polyurethane in a polyol is made from (a) the reaction product of a polyisocyanate and a diprimary diol, and (b) a polyether in which the reaction product constitutes from 3 to 60 wt. % of the solution. Suitable diprimary diols have a molecular weight of from 90 to 800 and a structure at both hydroxyl groups corresponding to the general formula: in which R1 represents chlorine, an alkyl, cycloalkyl, aralkyl or aryl radical having from 1 to 10 carbon atoms, which carbon atoms may be substituted or interrupted by chlorine, ester groups, ether groups, amide groups, urethane groups or nitrile groups, and R2 represents hydrogen or a radical within the definition of R1. Polyethers which may be employed have at least two hydroxyl groups (at least 80% of which are secondary hydroxyl groups) and an average molecular weight of from 500 to 12,000. The disclosed solutions are particularly useful in the production of flexible polyurethane plastics which are suitable for flamecoating and high frequency bonding.