Abstract:
ALLOPHANATE POLYISOCYANATES CONTAINING AT LEAST ONE AROMATICALLY BOUND-NCO GROUP ARE PREPARED BY REACTING AN N-SUBSTITUTED CARBAMIC ACID ESTER WITH ORGANIC MONO- OR POLYISOCYANATES IN THE PRESENCE OF A COMPOUND HAVING AN ALKYLATING EFFECT. THE ALLOPHANATE POLYISOCYANATES ARE OBTAINED FREE OF SECONDARY PRODUCTS HAVING ISOCYANURATE STRUCTURES, AND ARE ESPECIALLY USEFUL AS ISOCYANATE PRECURSORS IN THE PRODUCTION OF POLYUETHANE PLASTICS BY THE ISOCYANATE-POLYADDITION PROCESS.
Abstract:
TEXTILE COATINGS AND LEATHER DRESSING COMPOSITION ARE PROVIDED WHICH COMPOSITIONS COMPRISE MIXTURES OF POLYURETHANE OR POLYUREA WITH NITROCELLULOSE AND A UREA DERIVATIVE WHICH CONTAINS AT LEAST ONE SATURATED OR UNSATURATED ALIPHATIC RADICAL CONTAINING FROM 8 TO 20 CARBON ATOMS AND AT LEAST ONE UREA GROUP.
Abstract:
FLAME-RESISTANT POLYURETHANE FOAMS ARE DISCLOSED WHICH ARE PREPARED BY REACTING A POLYETHER POLYOL HAVING A MOLECULAR WEIGHT OF FROM ABOUT 750 TO ABOUT 10,000 IN WHICH AT LEAST 10% OF THE POLYISOCYANATE WHICH IS A SOLUHYDROXYL GROUPS, WITH A POLYISOCYANATE WHICH IS A SOLUTION OF FROM ABOUT 10 TO ABOUT 70% BY WEIGHT OF AN ORGANIC POLYISOCYANATE CONTAINING AT LEAST ONE N,N''-DISUBSTITUTED ALLOPHANIC ACID ESTER GROUP DISSOLVED IN A LIQUID POLYISOCYANATE WHICH IS FREE FROM ALLOPHANIC ACID ESTER GROUPS.
Abstract:
POLYURETHANE BASED COATING COMPOSITIONS ARE PREPARED BY REACTING AN ORGANIC POLYISOCYANATE AND A COMPOUND CONTAINING TERMINAL HYDROXYL GROUPS REACTIVE WITH ISOCYANATES IN THE PRESENCE OF A HYDROPHOBIC INCORPORATION COMPOUND HAVING THE FORMULA
HO-CH(-R")-CH2-N(-R)-CH2-CH(-R'')-OH
WHEREIN R IS A C12 TO C20 ALKYL, ALKYLCARBONYL OR ALKYLAINOCARBONYL THE ALKYL MOIETY OF WHICH CONTAINS 12 TO 20 CARBON ATOMS AND R'' AND R" ARE HYDROGEN OR C1 TO C2 ALKYL. THE COMPOUNDS OF THE INVENTION ARE SUITABLE FOR COATING OR BONDING PAPER, TEXTILE SHEET STRUCTURES OR FILMS, ORGANIC OR INORGANIC MATERIALS.
Abstract:
1288688 Polyurethane foams FARBENFABRIKEN BAYER AG 17 Dec 1970 [17 Jan 1970] 59899/70 Headings C3C and C3R Polyurethane foams are prepared by reacting, in the presence of a blowing agent, a polyether polyol which has a M.W. of 750 to 10,000 and in which at least 10% of the hydroxyl groups are primary with an allophanate polyisocyanate which contains at least two NCO groups and at least one N,N 1 -disubstituted allophanate group and which is dissolved at a concentration of 10 to 70% by weight in one or more liquid polyisocyanates which do not contain allophanate groups. The polyether is suitably prepared by reacting a polyol or polyamine with an alkylene oxide and may be used in admixture with at least one other compound containing reactive hydrogen atoms. The allophanate polyisocyanates are suitably prepared by reacting N-substituted carbamic acid esters which may contain isocyanate groups with mono- and/or polyfunctional isocyanates. Suitably this is achieved by reacting in one stage a hydroxyl containing compound with excess polyisocyanate and heating the first formed reaction product at 100 to 160‹ C. to form the allophanate polyisocyanate which is dissolved in monomeric polyisocyanate if sufficient polyisocyanate has been added. Alternatively the allophanate polyisocyanate may be formed first and then dissolved in a monomeric polyisocyanate in a separate stage. In a typical example, a linear propylene glycol/ propylene oxide/ethylene oxide polyether, 1,4- butylene glycol, water and triethylene diamine are reacted with an isocyanate solution prepared by reacting 2,2-dimethylpropane-1,3-diol with a large excess of toluene-2,4- and -2,6-diisocyanates to first form the bis-carbamic acid ester diisocyanate dissolved in the monomeric diisocyanate which reaction mixture is then heated to 150‹C. to form a solution of allophanatepolyisocyanate in the monomeric diisocyanate. Uses:-Cushioning material, mattresses, packaging, foils for laminates, insulating material, and in construction of motor cars and aircraft.
Abstract:
Soluble polyisocyanates of isocyanurate structure are produced by heating polyisocyanates in the presence of Mannich bases and carbamic acid esters of isocyanates and secondary alcohols. When such a process is used, the polymerization reactions begin without incubation times and the catalysts need not be inactivated by introducing additives because they deactivate themselves at high temperatures.
Abstract:
1288688 Polyurethane foams FARBENFABRIKEN BAYER AG 17 Dec 1970 [17 Jan 1970] 59899/70 Headings C3C and C3R Polyurethane foams are prepared by reacting, in the presence of a blowing agent, a polyether polyol which has a M.W. of 750 to 10,000 and in which at least 10% of the hydroxyl groups are primary with an allophanate polyisocyanate which contains at least two NCO groups and at least one N,N 1 -disubstituted allophanate group and which is dissolved at a concentration of 10 to 70% by weight in one or more liquid polyisocyanates which do not contain allophanate groups. The polyether is suitably prepared by reacting a polyol or polyamine with an alkylene oxide and may be used in admixture with at least one other compound containing reactive hydrogen atoms. The allophanate polyisocyanates are suitably prepared by reacting N-substituted carbamic acid esters which may contain isocyanate groups with mono- and/or polyfunctional isocyanates. Suitably this is achieved by reacting in one stage a hydroxyl containing compound with excess polyisocyanate and heating the first formed reaction product at 100 to 160‹ C. to form the allophanate polyisocyanate which is dissolved in monomeric polyisocyanate if sufficient polyisocyanate has been added. Alternatively the allophanate polyisocyanate may be formed first and then dissolved in a monomeric polyisocyanate in a separate stage. In a typical example, a linear propylene glycol/ propylene oxide/ethylene oxide polyether, 1,4- butylene glycol, water and triethylene diamine are reacted with an isocyanate solution prepared by reacting 2,2-dimethylpropane-1,3-diol with a large excess of toluene-2,4- and -2,6-diisocyanates to first form the bis-carbamic acid ester diisocyanate dissolved in the monomeric diisocyanate which reaction mixture is then heated to 150‹C. to form a solution of allophanatepolyisocyanate in the monomeric diisocyanate. Uses:-Cushioning material, mattresses, packaging, foils for laminates, insulating material, and in construction of motor cars and aircraft.