Abstract:
The methods disclosed herein allow for the recovery of at least 55% of residual heavy oil from porous structures. In the disclosed methods, porous structures are contacted with emulsions having an aqueous continuous phase and an organic dispersed phase. The organic dispersed phase includes organic compounds having five or fewer carbon atoms (such as natural gas), which are typically difficult to emulsify because they are unstable at ambient conditions. To solve that problem, the emulsions disclosed herein are stabilized by nanoparticles having hydrophilic exterior surfaces. The nanoparticles make up at least 0.1% of the emulsion by weight. The use of hydrophilic nanoparticles as stabilizers combines the utility of natural gas liquids in enhanced oil recovery (due to their high solubility in residual oil and attendant viscosity reduction) with the utility of emulsions (delivery of viscosity-reducing agents along with an immiscible phase to push out the trapped oil).
Abstract:
The present disclosure provides a polymer gel and method of making and using the same for use in high-permeability layers. This precision conformance control is accomplished by using paramagnetic nanoparticles and the application of the magnetic oscillation of prescribed frequency at the wellbore. If the polymer gel were created unintentionally at a certain layer, or there is a need to remove the gel blockage at the later stage of oil production, the gel could be broken and removed to restore the productivity from the layer.
Abstract:
Hydrophobic paramagnetic nanoparticles can be injected with the enhanced oil recovery injection water by incorporating them inside of surfactant micelles to serve as an oil tracer. A variety of paramagnetic nanoparticles that show different susceptibility and magnetization responses to applied magnetic oscillation can be injected at different injectors, so that the origin of the oil from the different enhanced oil recovery patterns could be quantitatively identified. The concentrations of the nanoparticles in the produced crude oil and brine can be easily and instantly measured individually, employing the magnetic susceptibility meter without contacting the fluids directly.
Abstract:
A magnetic nanoparticle suitable for imaging a geological structure having one or more magnetic metal or metal oxide nanoparticles with a polymer grafted to the surface to form a magnetic nanoparticle, wherein the magnetic nanoparticle displays a colloidal stability under harsh salinity conditions or in a standard API brine.
Abstract:
A magnetic nanoparticle suitable for imaging a geological structure having one or more magnetic metal or metal oxide nanoparticles with a polymer grafted to the surface to form a magnetic nanoparticle, wherein the magnetic nanoparticle displays a colloidal stability under harsh salinity conditions or in a standard API brine.