A METHOD OF PRODUCING INDOLE
    6.
    发明专利

    公开(公告)号:GB1282660A

    公开(公告)日:1972-07-19

    申请号:GB4887170

    申请日:1970-10-14

    Applicant: BOFORS AB

    Abstract: 1282660 Indole BOFORS AB 14 Oct 1970 [30 Oct 1969] 48871/70 Heading C2C Indole is produced by reacting 2-(o-nitrophenyl)-ethanol in the gaseous phase with hydrogen or ammonia gas, optionally in admixture with an inert gas, at elevated temperature in the presence of a hydrogenation catalyst. Suitable catalysts are, for example, copper, nickel, cobalt, palladium or copper chromite optionally applied to a carrier, for example aluminium oxide or silica gel.

    PREPARATION OF DIARYL KETONES
    7.
    发明专利

    公开(公告)号:GB1205168A

    公开(公告)日:1970-09-16

    申请号:GB3517568

    申请日:1968-07-23

    Applicant: BOFORS AB

    Abstract: 1,205,168. Diaryl ketones. BOFORS A.B. 23 July, 1968 [4 Aug., 1967], No. 35175/68. Heading C2C. 1,2-Diaryl ketones of formula in which Ar and Ar 1 are unsubstituted or substituted phenyl groups are prepared by oxidizing a 1,2-diaryl ethan of formula with nitric acid in the presence of a substantially inert organic solvent which is substantially immiscible with the nitric acid. Suitable solvents are halogenated hydrocarbons, e.g. chloroform. An example is given of the oxidation of 1-phenyl-2-(o-nitrophenyl) ethanol to o-nitrodesoxy benzoin.

    Preparation of Indole
    8.
    发明专利

    公开(公告)号:GB1193764A

    公开(公告)日:1970-06-03

    申请号:GB3517468

    申请日:1968-07-23

    Applicant: BOFORS AB

    Inventor: BAKKE JAN MAGNUS

    Abstract: 1,193,764. Indole. BOFORS A.B. 23 July, 1968 [4 Aug., 1967], No. 35174/68. Heading C2C. 2,3-Dihydro-indole is dehydrogenated by heating at 50-250‹ C. in the presence of a Group VIII noble metal catalyst and an inert organic solvent to give indole. The preferred catalysts are platinum oxide or palladium supported on active carbon and suitable solvents are, for example, toluene, xylene and benzene.

    A METHOD OF PRODUCING 2-(NITRO-PHENYL) ALKYL HALIDES

    公开(公告)号:GB1201210A

    公开(公告)日:1970-08-05

    申请号:GB3683368

    申请日:1968-08-01

    Applicant: BOFORS AB

    Abstract: 1,201,210. 2-(Nitro-phenyl) alkyl halides. BOFORS A.B. 1 Aug., 1968 [4 Aug., 1967], No. 36833/68. Heading C2C. A method of preparing a 2-(nitrophenyl) alkyl halide comprises halogenating a 2-(nitrophenyl) alkanol with a halogenation agent. Specified halogenation agents include thionyl chlorides, phosphorus tri- and pentachloride, cone. hydrochloric acid, hydriodic acid and phosphorus tribromide or triiodide. Examples describe the preparation of 2-(o-nitrophenyl) ethyl chloride using thionyl chloride or concentrated hydrochloric acid, and of 2-(o-nitrophenyl) ethyl bromide using hydrobromic acid.

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