Abstract:
The present invention provides an additive for a non-aqueous electrolytic solution including a phosphazene derivative which is solid at 25 DEG C and represented by the following formula (1): (PNR2)n wherein R represents a monovalent substituent or a halogen atom; and n represents a number of 3 to 6. More particularly, the present invention provides a non-aqueous electrolytic solution secondary cell and a non-aqueous electrolytic solution electric double layer capacitor which contain the additive for the non-aqueous electrolytic solution, which have excellent self-extinguishability or flame retardancy, and resistance to deterioration, and which have low internal resistance and excellent conductivity due to low viscosity of the non-aqueous electrolytic solution.
Abstract:
The present invention provides additives for a non-aqueous electrolytic solution secondary cell and a non-aqueous electrolytic solution electric double layer capacitor comprising a phosphazene derivative represented by formula (1): (PNF2)n wherein n represents 3 to 14, and provides the non-aqueous electrolytic solution secondary cell and the non-aqueous electrolytic solution electric double layer capacitor each containing a non-aqueous electrolytic solution which has the additive for the non-aqueous electrolytic solution secondary cell or the additive for the non-aqueous electrolytic solution electric double layer capacitor and a supporting salt, an anode, and a cathode.
Abstract:
A nonaqueous electrolyte secondary cell comprising a nonaqueous electrolyte which comprises a lithium ion and a phosphazene derivative having a flash point of 100°C or more (first embodiment), which comprises a supporting electrolyte, an organic solvent and a phosphazene derivative, the electrolyte having a potential window of a range wider than that of the phosphazene derivative (a lower limit value of +0.5 V or lower, a higher limit value of +4.5 V or more) (second embodiment), which comprises a supporting electrolyte and a solution of a lithium salt (0.5 mol/l) having a conductivity of 2.0 mS/cm or more (third embodiment), or which comprises a supporting electrolyte and a phosphazene having a relative permittivity of 15 or more at 25°C and a viscosity of 20 mPa/s (20 cP) or less (fourth embodiment). The nonaqueous electrolyte secondary cell is free from the danger of firing, explosion in the case of short circuit, or the like, has long term stability and safety, has a low internal resistance, and is excellent in various properties such as discharging characteristics at a low temperature, self-extinguishing property or flame retardancy, high voltage and high discharge capacity; and further is easy to manufacture.
Abstract:
A method of producing a silicon carbide single crystal in which a sublimation raw material 40 is accommodated at the side of vessel body 12 in a graphite crucible 10, placing a seed crystal of a silicon carbide single crystal at the side of cover body 11 of the graphite crucible 10, the sublimation raw material 40 is sublimated by a first induction heating coil 21 placed at the side of sublimation raw material 40, a re-crystallization atmosphere is form by a second induction heating coil 20 placed at the side of cover body 11 so that the sublimation raw material 40 sublimated by the first induction heating coil 21 is re-crystallizable only in the vicinity of the seed crystal of a silicon carbide single crystal, and the sublimation raw material 40 is re-crystallized on the seed crystal of a silicon carbide single crystal, and a silicon carbide single crystal 60 is grown while keeping the whole surface of its growth surface in convex shape through the all growth processes. A high quality silicon carbide single crystal with large diameter excellent in dielectric breakdown property, heat resistance, radiation resistance and the like, suitable for electronic and optical devices and the like, and showing no contamination of polycrystals and polymorphs, no defect of micropipes and the like can be produced efficiently without cracking and the like.
Abstract:
An additive for a non-aqueous liquid electrolyte, characterized in that it comprises a phosphazene derivative represented by the following general formula (1): (PNR2)n wherein R represents a fluorine atom or a fluorine- containing substituent, provided that at least one of all R's is a fluorine- containing substituent, n represents 3 to 14; and a non-aqueous liquid electrolyte secondary cell and a non-aqueous liquid electrolyte electric double layer capacitor comprising the additive for a non-aqueous liquid electrolyte which are excellent in low temperature characteristics and exhib it good resistance to deterioration and good flame retardancy, and accordingly are significantly high in safety. The substituent is preferably an alkoxy group.
Abstract:
An additive for a non-aqueous liquid electrolyte secondary cell or a non- aqueous liquid electrolyte electric double layer capacitor, characterized in that it comprises a phosphazene derivative represented by the following general formula (1): (PNF2)n, wherein n represents 3 to 14; and a non-aqueou s liquid electrolyte secondary cell or a non-aqueous liquid electrolyte electr ic double layer capacitor, characterized in that it has a non-aqueous liquid electrolyte electric double layer capacitor, characterized in that it has a non-aqueous liquid electrolyte comprising a supporting electrolyte and the additive for a non-aqueous liquid electrolyte secondary cell, a positive electrode and a negative electrode.
Abstract:
The present invention provides additives for a non-aqueous electrolytic solution secondary cell and a non-aqueous electrolytic solution electric double layer capacitor comprising a phosphazene derivative represented by formula (1): (PNF2)n wherein n represents 3 to 14, and provides the non-aqueous electrolytic solution secondary cell and the non-aqueous electrolytic solution electric double layer capacitor each containing a non-aqueous electrolytic solution which has the additive for the non-aqueous electrolytic solution secondary cell or the additive for the non-aqueous electrolytic solution electric double layer capacitor and a supporting salt, an anode, and a cathode.