公开(公告)号：CA2077548A1

公开(公告)日：1991-09-06

申请号：CA2077548

申请日：1991-03-05

Applicant: CATALYTICA INC

Inventor： GRATE JOHN H ,  MAHAJAN SURESH ,  HAMM DAVID R ,  KLINGMAN KENNETH A ,  DOWNEY SHANNAN L

IPC: B01J31/16 ,  B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C29/141 ,  C07C45/28 ,  C07C45/30 ,  C07C45/34 ,  C07C47/06 ,  C07C49/10 ,  C07C49/04 ,  C07C47/07 ,  C07C49/385

Abstract: 2077548 9113853 PCTABS00007 The present invention provides reaction mixtures useful for oxidation of olefins to carbonyl products, comprising an olefin and an aqueous catalyst solution comprising a palladium catalyst, a polyoxoacid or polyoxoanion oxidant comprising vanadium, and dissolved olefin. It also provides processes for oxidation of olefins to carbonyl products, comprising mixing an olefin with an aqueous catalyst solution. It also provides processes for oxidation of olefins to carbonyl products by dioxygen, comprising mixing an olefin with an aqueous catalyst solution, and further comprising mixing dioxygen with the aqueous catalyst solution. In certain reaction mixtures and related processes of the present invention, the concentration of dissolved olefin in the aqueous catalyst solution is effective for its oxidation rate to not be limited by its rate of its diffusion into the aqueous solution. In other reaction mixtures and related processes of the present invention, the concentration of dissolved olefin in the aqueous catalyst solution is effective for its oxidation rate to be proportional to the palladium catalyst concentration. In other processes of the present invention, the olefin is mixed with the aqueous catalyst solution under mixing conditions effective for providing an olefin oxidation rate of at least 1 (millimole olefin/liter solution)/second. In other processes of the present invention, dioxygen is mixed with an aqueous reduced vanadium-polyoxoanion solution under mixing conditions effective for providing a dioxygen reaction rate of at least 1 (millimole dioxygen/liter solution)/second. In other reaction mixtures and related processes of the present invention, the aqueous solution is essentially free of sulfuric acid and sulfate ions.

公开(公告)号：BR9106139A

公开(公告)日：1993-03-09

申请号：BR9106139

申请日：1991-03-05

Applicant: CATALYTICA INC

Inventor： GRATE JOHN H ,  HAMM DAVID R ,  KLINGMAN KENNETH A ,  SAXTON ROBERT J ,  DOWNEY SHANNAN L

IPC: B01J31/16 ,  B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C29/141 ,  C07C45/28 ,  C07C45/30 ,  C07C45/34 ,  C07C47/06 ,  C07C49/10 ,  C07C45/35

Abstract: PCT No. PCT/US91/01508 Sec. 371 Date Sep. 4, 1992 Sec. 102(e) Date May 24, 1991 PCT Filed Mar. 5, 1991 PCT Pub. No. WO91/13851 PCT Pub. Date Sep. 19, 1991.The present invention provides aqueous catalyst solutions useful for oxidation of olefins to carbonyl products, comprising a palladium catalyst, a polyoxoacid or polyoxoanion oxidant comprising vanadium, and chloride ions. It also provides processes for oxidation of olefins to carbonyl products, comprising contacting olefin with the aqueous catalyst solutions of the present invention. It also provides processes for oxidation of olefins to carbonyl products by dioxygen, comprising contacting olefin with the aqueous catalyst solutions of the present invention, and further comprising contacting dioxygen with the aqueous catalyst solutions. The present invention also provides a process for the oxidation of palladium(0) to palladium(II) comprising contacting the palladium(0) with an aqueous solution comprising chloride ions and a polyoxoacid or polyoxoanion oxidant comprising vanadium.

公开(公告)号：CA2077552A1

公开(公告)日：1991-09-06

申请号：CA2077552

申请日：1991-03-05

Applicant: CATALYTICA INC

Inventor： GRATE JOHN H ,  HAMM DAVID R ,  KLINGMAN KENNETH A ,  SAXTON ROBERT J ,  DOWNEY SHANNAN L

IPC: B01J31/16 ,  B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C29/141 ,  C07C45/28 ,  C07C45/30 ,  C07C45/34 ,  C07C47/06 ,  C07C49/10 ,  B01J27/186 ,  C07C49/04 ,  C07C47/07 ,  C07C49/385

Abstract: 2077552 9113854 PCTABS00007 The present invention provides aqueous catalyst solutions useful for oxidation of olefins to carbonyl products, comprising a palladium catalyst and a polyoxoacid or polyoxoanion oxidant comprising vanadium. It also provides processes for oxidation of olefins to carbonyl products, comprising contacting olefin with the aqueous catalyst solutions of the present invention. It also provides processes for oxidation of olefins to carbonyl products by dioxygen, comprising contacting olefin with the aqueous catalyst solutions of the present invention, and further comprising contacting dioxygen with the aqueous catalyst solutions. In certain aqueous catalyst solutions and related processes of the present invention, the solution has a hydrogen ion concentration greater than 0.10 mole per liter when essentially all of the oxidant is in its oxidized state. In other aqueous catalyst solution and related processes of the present invention, the solution is essentially free of sulfuric acid and sulfate ions.

公开(公告)号：BR9106140A

公开(公告)日：1993-03-09

申请号：BR9106140

申请日：1991-03-05

Applicant: CATALYTICA INC

Inventor： GRATE JOHN H ,  MAHAJAN SURESH ,  HAMM DAIVD R ,  KLINGMAN KENNETH A ,  DOWNEY SHANNAN L

IPC: B01J31/16 ,  B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C29/141 ,  C07C45/28 ,  C07C45/30 ,  C07C45/34 ,  C07C47/06 ,  C07C49/10 ,  C07C45/35

Abstract: PCT No. PCT/US91/01508 Sec. 371 Date Sep. 4, 1992 Sec. 102(e) Date May 24, 1991 PCT Filed Mar. 5, 1991 PCT Pub. No. WO91/13851 PCT Pub. Date Sep. 19, 1991.The present invention provides aqueous catalyst solutions useful for oxidation of olefins to carbonyl products, comprising a palladium catalyst, a polyoxoacid or polyoxoanion oxidant comprising vanadium, and chloride ions. It also provides processes for oxidation of olefins to carbonyl products, comprising contacting olefin with the aqueous catalyst solutions of the present invention. It also provides processes for oxidation of olefins to carbonyl products by dioxygen, comprising contacting olefin with the aqueous catalyst solutions of the present invention, and further comprising contacting dioxygen with the aqueous catalyst solutions. The present invention also provides a process for the oxidation of palladium(0) to palladium(II) comprising contacting the palladium(0) with an aqueous solution comprising chloride ions and a polyoxoacid or polyoxoanion oxidant comprising vanadium.

公开(公告)号：CA2077549A1

公开(公告)日：1991-09-06

申请号：CA2077549

申请日：1991-03-05

Applicant: CATALYTICA INC

Inventor： COOK MICHAEL L ,  FELLMANN JERE D ,  HAMM DAVID R ,  MAHAJAN SURESH ,  MURAOKA MARK T ,  ROSTRUP-NIELSEN THOMAS ,  SMITH ARNOLD R ,  GRATE JOHN H ,  SAXTON ROBERT J ,  KLINGMAN KENNETH A

IPC: B01J31/16 ,  B01J23/44 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C29/141 ,  C07C45/28 ,  C07C45/30 ,  C07C45/34 ,  C07C47/06 ,  C07C49/10

Abstract: 2077549 9113852 PCTABS00007 This invention is to the production of methyl ethyl ketone (MEK) from mixed normal butenes using polyoxoanion oxidants in an aqueous solution, catalyzed by palladium and preferably containing minor amounts of dissolved chloride ion. An intermediate MEK stream is hydrogenated to remove trace amounts of butyraldehyde from the product MEK stream.