公开(公告)号：JPH10139747A

公开(公告)日：1998-05-26

申请号：JP31295396

申请日：1996-11-08

Applicant: CHISSO CORP ,  MIYASHITA TOKUJI

Inventor： MIYASHITA TOKUJI

IPC: G03F7/027 ,  C07C233/13 ,  C08F120/56 ,  C08J5/18 ,  H01L21/027 ,  H01L21/312

Abstract: PROBLEM TO BE SOLVED: To obtain the new compound useful for single molecular films, accumulated films, polymer films, fluorinated carbon-insoluble water-repelling polymer thin films, UV light resists, etc., improved in physical strengths, stability and uniformity and excellent in lubricity and water repellency. SOLUTION: A compound of the formula [(n) is 0-2; R is H, methyl; R is a 1-14C perfluoroalkyl], e.g. N-1H,1H-heptafluorobutylacrylamide. The compound of the formula is obtained by reacting a 2-(perfluoroalkyl)alkyl iodide with sodium azide, reducing the obtained corresponding 2-(perfluoroalkyl) alkylamide with lithium aluminum hydride, and subsequently reacting the obtained polyfluoroalkylamine with acrylic acid chloride in the presence of a catalyst. The obtained N-polyfluoroalkyl-substituted acrylamide can give polymers excellent in mechanical strengths, solvent resistance, corrosion resistance and plasma resistance.

公开(公告)号：JP2002162297A

公开(公告)日：2002-06-07

申请号：JP2000358946

申请日：2000-11-27

Applicant: NAT AEROSPACE LAB ,  AMAO YUTAKA ,  MIYASHITA TOKUJI

Inventor： AMAO YUTAKA ,  MIYASHITA TOKUJI

IPC: G01K11/12

Abstract: PROBLEM TO BE SOLVED: To provide a sensor capable of not only enhancing the timely and spatial resolution of the sensor using a temperature sensing film using a temperature indication material, but also manufacturing the sensor with desired sensitivity and resolution with good reproduction. SOLUTION: A temperature indication thin film makes a polymer carrying a temperature sensitive pigment a ultra-thin film by an LB method. The polymer carrying a temperature sensitive pigment can have oxygen impermeability, and further the thin film (pDDA layer) with the oxygen impermeability is desired to be provided on the outside of a ultra-thin film polymer carrying the temperature sensitive pigment.

公开(公告)号：JP2000143831A

公开(公告)日：2000-05-26

申请号：JP13297999

申请日：1999-05-13

Applicant: SHIPLEY FAR EAST LTD ,  MIYASHITA TOKUJI

Inventor： MIYASHITA TOKUJI

IPC: B05D1/20 ,  C08J5/18 ,  C08L33/10 ,  G03F7/039 ,  G03F7/16 ,  H01L21/312

Abstract: PROBLEM TO BE SOLVED: To obtain a polymerie Langmuir-Blodgett film having a thickness which is even and is controllable even on the nanometer level and having controlled molecular orientation and improved sensitivity and resolution by using a poly-N-substituted methacrylamide. SOLUTION: A solution obtained by dissolving in an organic solvent 0.0001-0.005 mol/l of a poly-N-substituted methacrylamide comprising repeating units of the formula and having a number-average molecular weight of 1,000-100,000, particularly, 2,000-30,000 is added dropwise to the surface of water in an amount of 3-5 ml/10 cm2, and the organic solvent is evaporated to obtain a poly-N-substituted methacrylamide polymer monomolecular film. This film is pressed to a specified buildup pressure by means of the movable barrier of a surface pressure indicator and a substrate is moved up and down so as to cross the film. In the formula, R is an 8-18C linear alkyl, a 4 or 5C branched alkyl, an (unsubstituted) 1-16C linear alkyl, a 3-6C branched alkyl, or a phenyl substituted with a substituent selected from hydroxyl and a halogen.

公开(公告)号：JP2009114409A

公开(公告)日：2009-05-28

申请号：JP2007292008

申请日：2007-11-09

Applicant: Chisso Corp ,  Tohoku Univ ,  チッソ株式会社 ,  国立大学法人東北大学

Inventor： MIYASHITA TOKUJI ,  MITSUISHI KATAYA ,  KIM YEJI ,  MITANI SEIJU

IPC: C08F230/08 ,  B05D1/20 ,  B05D7/24 ,  C08F220/56 ,  C08J5/18 ,  G03F7/075 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a monomolecular film or a laminated film therefrom having a plurality of monomolecular films that is useful for a resist material or the like. SOLUTION: The monomolecular film or a laminated film therefrom is produced by coating a substrate with a monomolecular film of a copolymer of an acrylic- or styrenic addition-polymerizable monomer comprising a silsesquioxane derivative and an addition polymerizable monomer represented by formula (B) (wherein R b denotes hydrogen or a methyl: Z 2 is -NH-; and n is an integer of 2-20). COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供具有多个可用于抗蚀剂材料等的单分子膜的单分子膜或层压膜。 解决方案：单分子膜或其层压膜通过用包含倍半硅氧烷衍生物的丙烯酸或苯乙烯可加成聚合单体和由式（B）表示的可加聚单体的共聚物的单分子膜 ）（其中R b表示氢或甲基：Z 2是-NH-; n是2-20的整数）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008202027A

公开(公告)日：2008-09-04

申请号：JP2007292019

申请日：2007-11-09

Applicant: Chisso Corp ,  Tohoku Univ ,  チッソ株式会社 ,  国立大学法人東北大学

Inventor： MIYASHITA TOKUJI ,  WATANABE AKIRA ,  OTSUKA NOBUYUKI ,  MITANI SEIJU

IPC: C08G77/04 ,  G02B5/28 ,  G02B6/12 ,  G02F1/01

Abstract: PROBLEM TO BE SOLVED: To provide an optical element material excellent in thermooptic coefficient, solvent resistance, and heat resistance, and further having stable quality controlled in molecular weight. SOLUTION: The optical element is prepared using a polymer prepared using a cage silsesquioxane derivative represented by formula (1-0) where R is independently a 1-40C alkyl, a 6-40C aryl any hydrogen of which may be substituted by a halogen or a 1-20C alkyl, or a 7-40C arylalkyl in which any hydrogen in an aryl may be substituted by a halogen or a 1-20C alkyl. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供光热系数，耐溶剂性和耐热性优异的光学元件材料，并进一步具有分子量控制的稳定质量。 解决方案：使用由式（1-0）表示的笼型倍半硅氧烷衍生物制备的聚合物制备光学元件，其中R独立地为1-40C烷基，其中任何氢可以被其取代的6-40C芳基 卤素或1-20C烷基或其中芳基中的任何氢可被卤素或1-20C烷基取代的7-40C芳基烷基。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007308527A

公开(公告)日：2007-11-29

申请号：JP2006136228

申请日：2006-05-16

Applicant: Chisso Corp ,  チッソ株式会社

Inventor： MIYASHITA TOKUJI

IPC: C08J5/18 ,  C08F212/14 ,  C08F220/02

Abstract: PROBLEM TO BE SOLVED: To provide a monomolecular film in which hydrophobic groups or hydrophilic groups are regularly oriented at the nanometer-level, to provide a polymer thin film comprising the plurality of monomolecular films laminated. SOLUTION: The method for producing the monomolecular film is characterized as follows. A substrate is coated with the monomolecular film of a copolymer of a fluorosilsesquioxane containing one addition polymerizable functional group with an addition polymerizable monomer according to the Langmuir-Blodgett method. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供疏水基团或亲水基团以纳米级规则取向的单分子膜，以提供包含多个单分子膜的聚合物薄膜。 解决方案：单分子膜的制造方法的特征如下。 根据Langmuir-Blodgett方法，将含有一个可加聚官能团的氟代倍半硅氧烷共聚物的单分子膜与可加聚单体一起涂布在基材上。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2005270925A

公开(公告)日：2005-10-06

申请号：JP2004091997

申请日：2004-03-26

Applicant: Chisso Corp ,  チッソ株式会社

Inventor： MIYASHITA TOKUJI

IPC: G01N35/08 ,  B01J19/00 ,  G01N37/00

Abstract: PROBLEM TO BE SOLVED: To provide a microchannel system by which when two liquids not mixing with each other are allowed to flow in a channel and to come into contact with each other, the two liquids flow while forming an interface between the two and forming layers without aggregating and forming any aggregation and they can be separated again at the microscale, a reaction apparatus using the microchannel system, and the like.
SOLUTION: The microchannel system has a minute channel for moving liquids, at least 2 introduction paths for injecting liquids into the microchannel, at least 1 discharging path for discharging liquids from the microchannel, and the inner surface of the microchannel having a part hydrophilized and a part hydrophobized, wherein the part hydrophilized and the part hydrophobized span each from the upstream end to the downstream end of the channel and the treatment to provide hydrophilicity and/or the treatment to provide hydrophobicity is performed by accumulation of polymer LB membranes. Also provided are a reaction apparatus using the microchannel system and the like.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种微通道系统，当两个彼此不混合的液体允许在通道中流动并彼此接触时，两种液体在形成两者之间的界面的同时流动 并且形成层而不聚集并形成任何聚集体，并且它们可以在微尺度下再次分离，使用微通道系统的反应装置等。 解决方案：微通道系统具有用于移动液体的微通道，用于将液体注入微通道的至少2个引入路径，用于从微通道排出液体的至少一个排出路径，并且微通道的内表面具有部分 亲水化和部分疏水化，其中亲水化部分和部分疏水化的部分从通道的上游端到下游端跨越，并且提供亲水性和/或处理以提供疏水性的处理通过聚合物LB膜的堆积进行。 还提供了使用微通道系统等的反应装置。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2002244298A

公开(公告)日：2002-08-30

申请号：JP2001046502

申请日：2001-02-22

Applicant: CHISSO CORP

Inventor： MIYASHITA TOKUJI

IPC: G03F7/039 ,  C08F212/14 ,  C08F220/18 ,  C08F220/54 ,  C08F230/08 ,  C08K5/00 ,  C08L25/18 ,  C08L33/10 ,  C08L33/24 ,  C08L43/04 ,  G03F7/095 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a polymer built-up film having a high orderly film structure with con trolled molecular orientation, forming a stable coating film and having a smooth film surface and a film thickness adjustable by building-up frequency on a nanometer level and to provide a composite polymer built-up film and a high sensitivity and high resolution resist material comprising the built-up film and a photo-acid generating agent or a polymer built-up film having photo-acid generating function. SOLUTION: The polymer built-up film comprises a copolymer of an N-alkyl substituted acrylamide and tert-butoxycarboxystyrene and a photo-acid generating agent. The composite polymer built-up film comprises a polymer built-up film comprising the above copolymer and a polymer built-up film comprising a copolymer of neopentyl methacrylamide and anthryl methacrylate. A resist material using the polymer built-up film comprising the copolymer of an N-alkyl substituted acrylamide and tert-butoxy carboxystyrene and the photo-acid generating agent and a resist material comprising the composite polymer built-up film comprising the above copolymer and the polymer built-up film comprising the copolymer of neopentyl methacrylamide and anthryl methacrylate are obtained.

公开(公告)号：JP2009298908A

公开(公告)日：2009-12-24

申请号：JP2008154550

申请日：2008-06-12

Applicant: Chisso Corp ,  チッソ株式会社

Inventor： OIKAWA HISAO ,  MIYASHITA TOKUJI ,  WATANABE AKIRA ,  KIMAE YOICHI ,  YOSHIDA KAZUHIRO

IPC: C08G77/50 ,  C08L83/05 ,  C08L83/07

Abstract: PROBLEM TO BE SOLVED: To provide a polymer and a silicone resin molding excellent in transparency, which are little in modulus variation at a glass transition temperature or above and freely foldable, and to provide a substrate for a display element using the silicone resin molding. SOLUTION: The polymer, which includes a silsesquioxane backbone, is obtained by reacting a specific, cage-type silicone compound (1-1) having an alkenyl group, a specific, cage-type silicone compound (2-2) having a Si-H group, and a specific, straight chain-type silicone compound (3-2) having a Si-H group. Let the number of moles of the alkenyl that the compound used for the reaction and represented by (1-1) has be (A), the number of moles of the Si-H that the compound represented by (3-2) has be (C), and the above compounds are reacted so that m in the (3-2) and the ratio of the (C) to (A) satisfy the equation (m+2)×(C)/(A)=1-3 in order to obtain the polymer. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供在玻璃化转变温度以上且可自由折叠时模量变化小的透明性优异的聚合物和有机硅树脂成型体，并且提供使用硅氧烷的显示元件用基材 树脂成型。 解决方案：包含倍半硅氧烷主链的聚合物是通过使具有烯基的特定的保持型硅酮化合物（1-1），特定的笼型硅氧烷化合物（2-2）与 Si-H基和具有Si-H基的特定的直链型硅氧烷化合物（3-2）。 使用（1-1）表示的化合物所用的烯基的摩尔数为（A），由（3-2）表示的化合物的Si-H的摩尔数为 （C）和上述化合物反应，使得（3-2）中的m和（C）与（A）的比率满足式（m + 2）×（C）/（A）= 1 -3以获得聚合物。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2008112942A

公开(公告)日：2008-05-15

申请号：JP2006296509

申请日：2006-10-31

Applicant: Chisso Corp ,  Tohoku Univ ,  チッソ株式会社 ,  国立大学法人東北大学

Inventor： MIYASHITA TOKUJI ,  WATANABE AKIRA ,  HATTORI TAKAYUKI ,  YOSHIDA KAZUHIRO

IPC: H05K1/03 ,  C07F7/10 ,  C08G77/04 ,  C08L83/04 ,  H01L23/14

Abstract: PROBLEM TO BE SOLVED: To provide an electric board material capable of forming a circuit efficiently by an irradiation of laser beams.
SOLUTION: The laser beams are irradiated on a material in which metal particulates are adhered onto a surface of a formed body of a synthetic resin composed of a polymer containing a silsesquioxane structure exemplified in the formula (1), the formula (2) and the formula (3), to manufacture the electric board material. In the formula (1), the formula (2) and the formula (3), each R independently denotes phenyl, cyclopentyl, cyclohexyl, or perfluoroalkyl or t-butyl in which a carbon number is 1-10, and each R
1 independently denotes alkyl or phenyl in which a carbon number is 1-4.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供能够通过激光束的照射有效地形成电路的电路板材料。 解决方案：将激光束照射在金属微粒附着在由含有式（1），式（2）中示例的倍半硅氧烷结构的聚合物构成的合成树脂的成形体的表面上的材料上 ）和公式（3），制造电路板材料。 在式（1）中，式（2）和式（3）各自独立地表示苯基，环戊基，环己基或全氟烷基或叔丁基，其中碳数为1-10，并且每个R 1 独立地表示碳数为1-4的烷基或苯基。 版权所有（C）2008，JPO＆INPIT