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1.发明申请METHOD FOR CHEMICALLY MODIFYING A POLYMER MATRIX THROUGH THE THICKNESS THEREOF 审中-公开通过其厚度对聚合物基质进行化学修饰的方法
公开(公告)号：WO2010125191A3
公开(公告)日：2011-01-13
申请号：PCT/EP2010055923
申请日：2010-04-30
Applicant: COMMISSARIAT ENERGIE ATOMIQUE , BERTHELOT THOMAS , BAUDIN CECILE
Inventor： BERTHELOT THOMAS , BAUDIN CECILE
CPC classification number: C23C18/1601 , C08J3/28 , C08J7/123 , C08J7/16 , C08J2323/26 , C08J2327/18 , C23C18/18 , C23C18/1844 , C23C18/1893 , C23C18/2086 , Y10T428/1352
Abstract: The invention relates to a method for chemically modifying a polymer matrix through the thickness thereof, said polymer matrix being selected from among fluoropolymer matrices and aliphatic polymer matrices. The method includes at least one step consisting in irradiating the matrix with UV light having a wavelength of less than 300 nm in order to generate zones in the thickness of the matrix that have: short polymer chains formed by scission of the existing chains during the passage of the UV rays, and free radicals known as "activated zones". The invention also relates to the polymer matrix that can be chemically modified using one such method.
Abstract translation: 本发明涉及一种通过其聚合物基体的厚度对聚合物基质进行化学改性的方法，所述聚合物基体选自含氟聚合物基体和脂族聚合物基质。 该方法包括至少一个步骤，其包括用波长小于300nm的UV光照射基质，以便产生基质厚度的区域，该区域具有：在通道期间通过现有链条的断开而形成的短聚合物链 的紫外线，以及称为“活化区”的自由基。 本发明还涉及可以使用一种这样的方法化学改性的聚合物基质。
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2.发明申请METHOD FOR PREPARING AN ORGANIC FILM AT THE SURFACE OF A SOLID SUBSTRATEIN NON-ELECTROCHEMICAL CONDITIONS, SOLID SUBSTRATE THUS FORMED AND PREPARATION KIT 审中-公开在固体底物非电化学条件表面上制备有机膜的方法，该形成和制备试剂盒的固体基质
公开(公告)号：WO2008078052A2
公开(公告)日：2008-07-03
申请号：PCT/FR2007052556
申请日：2007-12-19
Applicant: COMMISSARIAT ENERGIE ATOMIQUE , MEVELLEC VINCENT , ROUSSEL SEBASTIEN , PALACIN SERGE , BERTHELOT THOMAS , BAUDIN CECILE , TRENGGONO ADHITYA , DENIAU GUY
Inventor： MEVELLEC VINCENT , ROUSSEL SEBASTIEN , PALACIN SERGE , BERTHELOT THOMAS , BAUDIN CECILE , TRENGGONO ADHITYA , DENIAU GUY
CPC classification number: C09D4/00 , B82Y30/00 , C08J7/02 , C08J7/04 , C23C18/04 , C23C18/08 , C23C18/14 , C23C18/28 , C23C18/31 , H01L51/0006 , H01L51/0021 , H01L51/0075 , Y10T428/31616 , Y10T428/31681
Abstract: The present invention relates to a method for preparing an organic film at the surface of a solid substrate, comprising a step of contacting said surface with a liquid solution containing (i) at least one solvent, at least one adhesion primer in non-electrochemical conditions and for generating radicalar entities from the adhesion primer. The liquid solution may further include (iii) at least one monomer different from the adhesion primer and polymerisable in a radicalar manner. The present invention also relates to an electrically non-conductive solid substrate on which an organic film is grafted according to said method, and to a kit for preparing an essentially polymeric organic film at the surface of the solid substrate.
Abstract translation: 本发明涉及一种在固体基质表面制备有机膜的方法，包括使所述表面与液体溶液接触的步骤，所述液体溶液含有（i）至少一种溶剂，至少一种非电化学条件下的粘合底漆 并用于从粘附底物产生真实实体。 液体溶液可以进一步包括（iii）至少一种不同于粘合引物的单体，并且可以以激进的方式聚合。 本发明还涉及根据所述方法在其上接枝有机膜的非导电固体基材，以及用于在固体基材表面制备基本上聚合的有机膜的试剂盒。
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3.发明申请PER (3,6-ANHYDRO) CYCLODEXTRINE DERIVATIVES, PRODUCTION AND USE THEREOF IN TRANSPORTING METAL ELEMENTS TO BIOLOGICAL TARGETS OR IN ORDER TO DECONTAMINATE BIOLOGICAL FLUIDS OR TARGETS 审中-公开PER（3,6-ANHYDRO）环糊精衍生物及其在将金属元素转移到生物靶上或为了去污染生物流体或靶标而生产和使用
公开(公告)号：WO2004071639A3
公开(公告)日：2004-10-07
申请号：PCT/FR2004050048
申请日：2004-02-06
Applicant: COMMISSARIAT ENERGIE ATOMIQUE , BAUDIN CECILE , PERLY BRUNO , DALBIEZ JEAN-PIERRE
Inventor： BAUDIN CECILE , PERLY BRUNO , DALBIEZ JEAN-PIERRE
CPC classification number: B01J20/262 , B01J20/26 , B01J20/265 , B01J45/00 , C08B37/0012 , C08B37/0015
Abstract: The invention relates to a derivative of per(3,6-anhydro)cyclodextrine of formulae (I) or (II) wherein at least one R represents a radical selected from peptides, proteins, lipids, oligo or polynucleotides and oligo or polysaccharides, biopolymers, and the other possible identical or different R s represent a group selected from OH, OR , 0M, SH, SR , OCOR , NH2, NHR , NR R , CONH2, CONHR , CONR R , CN, CO0R , OCH2COOH, COOH, OSO2R , N3 and R , wherein R and R are identical or different and represent a hydrocarbon, aliphatic or aromatic, saturated or unsaturated group which is optionally substituted by halogen atoms which can comprise one or several heteroatoms selected from 0, S and N, M represents a monovalent cation selected from alkaline metal cations; R s represent a single bond or a spacer group and n is equal to 6, 7 or 8. Said derivatives can be used to transport metal elements to biological targets or to decontaminate biological fluids or targets.
Abstract translation: 本发明涉及式（I）或（II）的全（3,6-脱水）环糊精的衍生物，其中至少一个R 1代表选自肽，蛋白质，脂质，寡核苷酸或多核苷酸和寡聚 多糖，生物聚合物和其他可能的相同或不同的R 1表示选自OH，OR 3，OM，SH，SR 3，OCOR 3，NH 2，NHR 3， NR 3 R 4，CONH 2，CONHR 3，CONR 3 R 4，CN，COOR 3，OCH 2 COOH，COOH，OSO 2 R 3，N 3和R 3，其中 R 3和R 4相同或不同且表示任选被卤素原子取代的烃基，脂族或芳族饱和或不饱和基团，所述卤素原子可包含一个或数个选自O，S和N的杂原子，M表示 选自碱金属阳离子的一价阳离子; R 2s'代表单键或间隔基团，并且n等于6,7或8.所述衍生物可用于将金属元素转运至生物靶标或去污染生物流体或靶标。
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公开(公告)号：DE69705133T2
公开(公告)日：2002-03-07
申请号：DE69705133
申请日：1997-01-28
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： BAUDIN CECILE , PERLY BRUNO , GADELLE ANDREE
Abstract: Substituted per(3,6-anhydro)cyclodextrin derivatives of formula (I) are new. R1 = H, halo, OH, OR2, OM, SH, SR2, OCOR2, NH2, NR2R3, CONR2R3, CONH2, CN, COOR2, COOH, OSO2R2, N3 or R2; R2 = aliphatic or aromatic, optionally unsaturated hydrocarbyl optionally containing at least one O, N or S; R3 = H or R2; M = monovalent cation or metal; and n = 5-7; provided that at least one R1 is not OH and that R1 is not MeO.
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公开(公告)号：ZA9709591B
公开(公告)日：1998-08-11
申请号：ZA9709591
申请日：1997-10-27
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： PERLY BRUNO , BAUDIN CECILE , GOSSELIN PASCAL
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Patent Agency Ranking
公开(公告)号：HU9700280D0
公开(公告)日：1997-03-28
申请号：HU9700280
申请日：1997-01-29
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： BAUDIN CECILE , GADELLE ANDREE , PERLY BRUNO
Abstract: Substituted per(3,6-anhydro)cyclodextrin derivatives of formula (I) are new. R1 = H, halo, OH, OR2, OM, SH, SR2, OCOR2, NH2, NR2R3, CONR2R3, CONH2, CN, COOR2, COOH, OSO2R2, N3 or R2; R2 = aliphatic or aromatic, optionally unsaturated hydrocarbyl optionally containing at least one O, N or S; R3 = H or R2; M = monovalent cation or metal; and n = 5-7; provided that at least one R1 is not OH and that R1 is not MeO.
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公开(公告)号：AU2007337938A1
公开(公告)日：2008-07-03
申请号：AU2007337938
申请日：2007-12-19
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： TRENGGONO ADHITYA , PALACIN SERGE , ROUSSEL SEBASTIEN , BAUDIN CECILE , DENIAU GUY , MEVELLEC VINCENT , BERTHELOT THOMAS
IPC: C08J5/18 , B05D1/32 , B05D3/12 , B05D7/00 , B82B3/00 , C08F2/38 , C08J5/24 , C08J7/12 , C09D4/00 , C09D133/00 , C09D139/08 , H01L51/00
Abstract: The surface of a solid support is contacted with a liquid solution containing protic solvent(s) and adhesion primer(s) under non-electrochemical conditions, and radical entities are formed based on the adhesion primer. An organic film is formed at the surface of solid support. An independent claim is included for non-electrically conductive solid support.
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公开(公告)号：FR2850972B1
公开(公告)日：2005-03-11
申请号：FR0301474
申请日：2003-02-07
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： BAUDIN CECILE , PERLY BRUNO , DALBIEZ JEAN PIERRE
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公开(公告)号：FR2850972A1
公开(公告)日：2004-08-13
申请号：FR0301474
申请日：2003-02-07
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： BAUDIN CECILE , PERLY BRUNO , DALBIEZ JEAN PIERRE
IPC: A61P39/00 , B01J20/26 , B01J45/00 , C08B37/00 , C08B37/16 , C07K5/06 , A61K38/02 , A61K38/05 , A61K51/08 , C07K2/00 , G01N33/68
Abstract: Per(3,6-anhydro)cyclodextrin derivatives are new. Per(3,6-anhydro)cyclodextrin derivatives of formula (I) or (II) are new: [Image] R 1Q, OH, OR 3, OM, SH, SR 3, OCOR 3, NH 2, NHR 3, NR 3R 4, CONH 2, CONHR 3, CONR 3R 4, CN, COOR 3, OCH 2COOH, COOH, OSO 2R 3, N 3or R 3, at least one being Q; Q : a peptide, protein, lipid, oligonucleotide, polynucleotide, oligosaccharide, polysaccharide or biopolymer; R 3, R 4aliphatic or aromatic hydrocarbyl optionally substituted with halogen and optionally containing heteroatoms (O, S, N); M : alkali metal; R 2a bond or a spacer group; and n : 6-8. Independent claims are also included for: (1) preparing the per(3,6-anhydro)cyclodextrin derivatives; (2) metal complexes of the per(3,6-anhydro)cyclodextrin derivatives; (3) diagnostic and therapeutic compositions containing the complexes; (4) decontaminating a metal-contaminated biological medium in vitroby contacting the medium with a per(3,6-anhydro)cyclodextrin derivative as above. ACTIVITY : None given. MECHANISM OF ACTION : Radiotherapy. No biological data is given.
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公开(公告)号：FR2814748A1
公开(公告)日：2002-04-05
申请号：FR0012429
申请日：2000-09-29
Applicant: COMMISSARIAT ENERGIE ATOMIQUE
Inventor： BAUDIN CECILE , PERLY DENIS , GADELLE ANDREE , DEBOUZY JEAN CLAUDE , FAUVELLE FLORENCE
Abstract: Biocompatible gels comprising a peranhydrocyclodextrin (I) or (II), a gelling agent, and water. Biocompatible gels comprising a peranhydrocyclodextrin of formula (I) or (II), a gelling agent, and water. R1 = H, halo, OH, OR2, OM, SH, SR2, OCOR2, NH2, NR2R3, CONR2R3, CONH2, CN, COOR2, COOH, OSO2R2, N3, or R2; R2 = saturated or unsaturated aliphatic or aromatic hydrocarbon, optionally containing 1 or more O, N and/or S; R3 = H or R2; M = monovalent metal or cation; and n = 6-8. An Independent claim is included for dressings comprising a gel as described on a sterile support.
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