公开(公告)号：US20020172642A1

公开(公告)日：2002-11-21

申请号：US10078122

申请日：2002-02-19

Applicant: Conoco Inc.

Inventor： Hasan Dindi ,  William Manogue ,  Norman Herron ,  Tianyan Niu

IPC: C01B003/26

CPC classification number: B01J23/89 ,  B01J8/025 ,  B01J8/0278 ,  B01J19/006 ,  B01J19/2485 ,  B01J23/005 ,  B01J23/464 ,  B01J2208/00548 ,  B01J2208/00557 ,  B01J2208/00849 ,  B01J2219/00774 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1282 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/169 ,  Y02P20/52

Abstract: Rhodium-spinel catalysts with activity for efficiently catalyzing the net partial oxidation of methane at high selectivities for CO and H2 products are disclosed, along with their method of making. A syngas production process employing such catalysts for the net catalytic partial oxidation of a C1-C5 hydrocarbon (e.g., natural gas or methane) to a product gas mixture comprising CO and H2 is also disclosed. Preferred reaction conditions include maintaining the catalyst at a temperature of about 400-1,200null C., superatmospheric pressure, and flow rate sufficient to pass the reactant gas mixture over the catalyst at space velocities of at least about 100,000-25,000,000 hrnull1.

Abstract translation: 公开了具有用于有效催化CO和H 2产物的高选择性的甲烷净部分氧化的活性的铑 - 尖晶石催化剂及其制备方法。 还公开了使用这种催化剂将C1-C5烃（例如天然气或甲烷）净化催化部分氧化成包含CO和H 2的产物气体混合物的合成气生产方法。 优选的反应条件包括将催化剂保持在约400-1200℃的温度，超大气压力和足以使反应气体混合物在至少约100,000-25,000,000小时-1的空间速度下通过催化剂的流速。