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公开(公告)号：MY122370A
公开(公告)日：2006-04-29
申请号：MYPI9905455
申请日：1999-12-15
Applicant: DAICEL CHEM
Inventor： MATSUYAMA AKINOBU , KAWABE MASATO , NAGASAWA TORU
Abstract: A NITRILE COMPOUND HAVING A COMPLICATED STRUCTURE (E.G., 2-HYDROXY-4-METHY/THIOBUTYRONITRI/E) IS CONVERTED INTO -AN AMIDE COMPOUND WITH HIGH PRODUCTION EFFICIENCY, BY USING A NOVEL MICROORGANISM OF WHICH THE GENE 16S RRNA HAS A SPECIFIC BASE SEQUENCE. AS THE MICROORGANISM, RHODOCOCCUS SP. CR4 STRAIN AND RHODOCOCCUS SP. AM4 STRAIN OR THE LIKE IS EMPLOYED.
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公开(公告)号：DE69608834T2
公开(公告)日：2000-10-19
申请号：DE69608834
申请日：1996-03-07
Applicant: DAICEL CHEM
Inventor： KAWABE MASATO , YAMAMOTO KENICHI , MATSUOKA KAZUYUKI
IPC: C07C51/02 , C07C51/06 , C07C51/08 , C07C231/06
Abstract: A nitrile compound or an amide compound is hydrolyzed in the presence of an inorganic acid or other acidic catalyst or an alkali metal hydroxide or other basic catalyst, and the by-produced ammonium salt of the acidic catalyst or the produced salt of a carboxylic acid and a base is electrodialysed to form an acid and ammonia or aqueous ammonia, or to form a base and ammonia. The obtained acid or base may be recycled as a catalyst for the hydrolysis of the nitrile compound or amide compound, and the obtained ammonia is reutilized as a nitrogen source for the nitrile compound or amide comound. Such amide compound may be produced by hydration of a nitrile compound in the presence of a manganese oxide.
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公开(公告)号：ID26483A
公开(公告)日：2001-01-11
申请号：ID20001823
申请日：1999-12-13
Applicant: DAICEL CHEM
Inventor： MATSUYAMA AKINOBU , KAWABE MASATO , NAGASAWA TORU
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公开(公告)号：DE69608834D1
公开(公告)日：2000-07-20
申请号：DE69608834
申请日：1996-03-07
Applicant: DAICEL CHEM
Inventor： KAWABE MASATO , YAMAMOTO KENICHI , MATSUOKA KAZUYUKI
IPC: C07C51/02 , C07C51/06 , C07C51/08 , C07C231/06
Abstract: A nitrile compound or an amide compound is hydrolyzed in the presence of an inorganic acid or other acidic catalyst or an alkali metal hydroxide or other basic catalyst, and the by-produced ammonium salt of the acidic catalyst or the produced salt of a carboxylic acid and a base is electrodialysed to form an acid and ammonia or aqueous ammonia, or to form a base and ammonia. The obtained acid or base may be recycled as a catalyst for the hydrolysis of the nitrile compound or amide compound, and the obtained ammonia is reutilized as a nitrogen source for the nitrile compound or amide comound. Such amide compound may be produced by hydration of a nitrile compound in the presence of a manganese oxide.
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公开(公告)号：EP1055724A4
公开(公告)日：2003-04-23
申请号：EP99959792
申请日：1999-12-13
Applicant: DAICEL CHEM
Inventor： MATSUYAMA AKINOBU , KAWABE MASATO , NAGASAWA TORU
CPC classification number: C12R1/365 , C12P13/02 , Y10S435/822
Abstract: Nitrile compounds having a complicated structure (2-hydroxy-4-methylthiobutyronitrile, etc.) are converted into amide compounds at a high production efficiency with the use of novel microorganisms having a specific base sequence as the 16S rRNA gene base sequence. Examples of these microorganisms include Rhodococcus sp. Cr4 strain and Rhodococcus sp. Am8 strain.
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Patent Agency Ranking
公开(公告)号：JP2000175681A
公开(公告)日：2000-06-27
申请号：JP35622998
申请日：1998-12-15
Applicant: DAICEL CHEM
Inventor： MATSUYAMA AKIKAZU , KAWABE MASATO , NAGASAWA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain a new microorganism as a kind of microorganisms containing 16S rRNA gene having specific base sequences, having the ability to convert a nitrile to the corresponding amide in high production efficiency, and useful in e.g. producing an amide compound for producing feed additives, or the like. SOLUTION: The new kind of microorganism is e.g. Rhodococcus sp.Cr4 strain (FERM BP-6596), containing 16S rRNA gene having respective base sequences of formula I and formula II and having the ability to convert a nitrile to the corresponding amide, thus being useful in producing the corresponding amide compound from a nitrile such as a cyanohydrin of formula III (R1 is a hydrocarbon group or heterocyclic group optionally having substituent(s)). The Rhodococcus sp.Cr4 strain as the new kind of microorganisms has been afforded by isolation using an accumulation method by culture in a selective medium from the soil collected from a certain field soil in Okayama City, Okayama Prefecture, Japan.
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公开(公告)号：JPH11199545A
公开(公告)日：1999-07-27
申请号：JP473198
申请日：1998-01-13
Applicant: DAICEL CHEM
Inventor： KAWABE MASATO , KITAYAMA KENJI
Abstract: PROBLEM TO BE SOLVED: To economically produce the subject industrially useful compound by feeding water so that a specific Broensted acid in the reactional system is kept at a specific concentration and reacting propyne, etc., with carbon monoxide and methanol using a carbonylating catalyst containing the Broensted acid. SOLUTION: Water in an amount of 0.5-5.0 wt.% based on the total weight of a reactional mixture is preferably fed so that the concentration of (iii) a Broensted acid in the reactional system is kept at 1-30 wt.% and (A) propyne and/or an arene, (B) carbon monoxide and (C) methanol are reacted in the presence of (D) a catalyst system containing (i) a supply source of an atom or an ion of a metal belonging to group VIII of the periodic table of elements [e.g. tetrakis(triphenylphosphine)platinum], (ii) a ligand selected from an organophosphorus compound, an organoarsenic compound and an organoantimony compound (e.g. triphenylphosphine) and (iii) methacrylic acid which is the Broensted acid to afford the objective compound.
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公开(公告)号：JP2005035974A
公开(公告)日：2005-02-10
申请号：JP2004127304
申请日：2004-04-22
Applicant: Daicel Chem Ind Ltd , ダイセル化学工業株式会社
Inventor： KAWABE MASATO
CPC classification number: Y02P20/52
Abstract: PROBLEM TO BE SOLVED: To provide a technique for producing 1,6-hexanediol at a low cost by using cyclohexanone as a starting raw material. SOLUTION: In the method, 1,6-Hexanediol is produced by a catalytic reduction reaction of a crude ε-caprolactone fraction obtained from a reaction process of an organic peracid and/or hydroperoxide with cyclohexanone or a by-product fraction composed mainly of residual ε-caprolactone left after separating ε-caprolactone from the crude ε-caprolactone, by-produced oxycaproic acid, adipic acid and their oligomers as they are in the presence of a hydrogenation catalyst or after esterifying the fraction with an alcohol. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract translation: 待解决的问题：提供一种通过使用环己酮作为起始原料以低成本生产1,6-己二醇的技术。 解决方案：在该方法中，通过由有机过酸和/或氢过氧化物与环己酮的反应过程获得的粗ε-己内酯馏分或副产物部分的催化还原反应制备1,6-己二醇或副产物部分 主要是在粗ε-己内酯，副产的氧己酸，己二酸及其低聚物分离ε-己内酯之后留下的残余ε-己内酯，因为它们在氢化催化剂存在下或在用醇酯化之后。 版权所有（C）2005，JPO＆NCIPI
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公开(公告)号：JPH10114698A
公开(公告)日：1998-05-06
申请号：JP27257496
申请日：1996-10-15
Applicant: DAICEL CHEM
Inventor： KAWABE MASATO , HAN RITSUZUI
Abstract: PROBLEM TO BE SOLVED: To keep the catalytic activity over a long period and suppress the formation of by-products by reacting an acetylenic or olefinic unsaturated compound with carbon monoxide having low hydrogen content ion the presence of a carbonylation catalyst. SOLUTION: An acetylenically or olefinically unsaturated compound (preferably a 2-10C α-acetylenically or α-olefinically unsaturated compound) is carbonylated by reacting with carbon monoxide in the presence of a carbonylation catalyst. The reaction is carried out by using carbon monoxide having a hydrogen content of to 1×10 mol in terms of metallic atom and that of carbon monoxide is 1-5mol based on 1mol of the unsaturated compound.
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公开(公告)号：JPS63162655A
公开(公告)日：1988-07-06
申请号：JP31444186
申请日：1986-12-25
Applicant: DAICEL CHEM
Inventor： KAWABE MASATO , TANAKA YASUTAKA
Abstract: PURPOSE:To obtain one isomer of phenylpropionic acid useful as a drug economically, efficiently and in high purity, by dissolving an isomer mixture of a phenylpropionic acid in a solvent and carrying out crystallization. CONSTITUTION:An isomer mixture of a phenylpropionic acid shown by the formula (R is H, alkyl, alkenyl or aryl) is dissolved in a solvent (e.g. hexane, heptane, methanol, acetone, ethyl acetate, etc.). The concentration of the solution is ordinarily up to about 15wt%. After the dissolution, crystal is precipitated by methods of (i) changing temperature of the solution, (ii) adding a solvent such as water, etc., (iii) distilling away part of the solvent, etc., to give the aimed compound. When purity of the crystal is insufficient, the crystal is redissolved in the solvent and crystallization is repeated to improve purity.
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