公开(公告)号：EP1285931A4

公开(公告)日：2005-11-09

申请号：EP02705177

申请日：2002-03-14

Applicant: DAICEL CHEM

Inventor： SHIBATA TOHRU ,  SHUTO YUICHIRO ,  ITO MASAAKI ,  ASAI TANEMI

IPC: C08B3/06 ,  C08B3/24

CPC classification number: C08B3/06 ,  C08B3/24

公开(公告)号：EP1048683A4

公开(公告)日：2002-09-25

申请号：EP99972231

申请日：1999-11-15

Applicant: DAICEL CHEM

Inventor： SAKANE MASANORI ,  TANIGAWA MICHIYO ,  SHIMIZU KUNIO ,  KAJIKAWA YASUTERU ,  ITO MASAAKI

IPC: C08G18/42 ,  C08G18/63 ,  C08G18/72 ,  C08G63/00 ,  C08G63/08 ,  C08G63/78 ,  C08G63/91 ,  C09D167/04 ,  C09D175/04 ,  C05G3/00 ,  C08F299/04 ,  C08J5/18 ,  C09D5/24 ,  C09D101/10 ,  C09D151/02

CPC classification number: C08G63/78 ,  C08G18/4277 ,  C08G18/4286 ,  C08G18/631 ,  C08G18/728 ,  C08G63/00 ,  C08G63/08 ,  C08G63/912 ,  C08G2230/00 ,  C09D167/04 ,  C09D175/04 ,  Y10T428/164 ,  C08L2666/02

Abstract: An aliphatic polyester which is obtained by reacting a lactone and a lactide with a high-boiling monohydric alcohol or a metal alkoxide through ring-opening polymerization and in which the contents of terminal OH and COOH have been reduced to 50 % or lower and 30 % or lower, respectively, or reduced to lower values by bonding ends of the yielded polymer to a diisocyanate. It has regulated thermal, hydrolytic, and biological degradability. From the polyester composition is obtained an agricultural or horticultural, particulate composition which is capable of being regulated with respect to the duration of fertilization and leaves no decomposition products remaining in the soil. From the resin consisting mainly of a fatty acid/cellulose ester derivative are obtained: a base film for marking films which is free from problems such as the volatilization or migration of plasticizers; a thermal transfer image receptor which is capable of forming recorded images and is excellent in releasability, developed-color density, and brightness; a conductive coating composition excellent in storage stability, adhesion, and conductivity; and a one-pack type coating material, moisture-curable graft copolymer, and coating composition which each is neither toxic nor stimulant and has excellent dryability. The copolymer in which the average length of the lactide and lactone unit chains has been regulated is excellent in heat resistance and impact resistance.

公开(公告)号：EP1632469A4

公开(公告)日：2006-10-04

申请号：EP04745777

申请日：2004-06-04

Applicant: DAICEL CHEM

Inventor： NAKAMOTO MASANOBU ,  ITO MASAAKI

IPC: C07C67/00 ,  C07C67/10 ,  C07B61/00 ,  C07C69/003 ,  C07C69/54

CPC classification number: C07C67/10 ,  C07C69/54

Abstract: A process for producing a lactone polyester/unsaturated monomer represented by the structural formula (1), characterized by reacting a carboxylated, radical-polymerizable, unsaturated monomer with a cyclic lactone in the presence of water added in an amount of 1 to 50 parts by weight per 100 parts by weight of the sum of the carboxylated, radical-polymerizable, unsaturated monomer and the cyclic lactone with the aid of an acid catalyst at ordinary pressure and subsequently conducting a dehydration reaction under vacuum so as to remove low-boiling matters to thereby form an ester linkage between the carboxylated, radical-polymerizable, unsaturated monomer and a lactone oligomer which is a by-product of a reaction initiated by the water added and reduce the hydroxy value to 5.0 mg-KOH/g or lower. Thus, a carboxy-terminated lactone polyester/unsaturated monomer of practical quality can be produced at low cost. Formula (1) (In the formula, R1, R2, R3, R4, R5, R6, and R7 each represents hydrogen or a substituent selected among C1-10 (un)substituted alkyl, (un)substituted aryl, (un)substituted alkoxycarbonyl, (un)substituted alkoxy, (un)substituted aryloxy, and halogeno; n is an integer of 1 to 7; and m is an integer of 1 to 100.)

Abstract translation: 一种方法产生结构式（1）的不饱和内酯衍生的聚酯单体：其中R 1，R 2，R 3，R 4，R 5，R 6和R 7各自表示选自氢原子， 取代或未取代的具有1-10个碳原子的烷基，取代或未取代的芳基，取代或未取代的烷氧基羰基，取代或未取代的烷氧基，取代或未取代的芳氧基和卤素原子; n表示1〜7的整数， m表示1〜100的整数，使用含羧基的自由基聚合性不饱和单体与环状内酯，使用酸性催化剂，在常压下，在1〜50重量份的水的存在下，向100重量份的 含羧基的可自由基聚合的不饱和单体和环状内酯的总量; 并在减压下进行脱水以除去低沸点组分，以在副产的水引发的内酯低聚物和含羧基的可自由基聚合的不饱和单体之间形成酯键，从而将羟值降低至5.0mg KOH / g以下 。 可以以低成本生产具有实际质量的具有末端羧基的不饱和内酯衍生的聚酯单体。

公开(公告)号：EP1354908A4

公开(公告)日：2005-11-30

申请号：EP01998583

申请日：2001-11-30

Applicant: DAICEL CHEM

Inventor： KATAYAMA HIROSHI ,  OKANO YOSHIMICHI ,  IIYAMA TAKASHI ,  ITO MASAAKI ,  TERANISHI TADASHI ,  OMAE HITOMI ,  SUMIMOTO SATORU ,  NISHIMURA KENJI ,  NAKATA KOJI ,  SHIMIZU KUNIO ,  MURAKAMI TADASHI

IPC: C08G18/42 ,  C08G63/08 ,  C08G63/60 ,  C08G63/91 ,  C08L75/06 ,  C08G85/00 ,  C08G63/68 ,  C08J5/00 ,  C08L67/00

CPC classification number: C08G63/91 ,  C08G18/4277 ,  C08G63/08 ,  C08G63/60 ,  C08G2230/00 ,  C08G2310/00 ,  C08L75/06 ,  C08L2666/18

Abstract: A high-molecular aliphatic polyester copolymer; a high-molecular aliphatic polyester copolymer containing polylactic acid; processes for industrially producing these copolymers; compositions of these copolymers; and various uses thereof. These copolymers have practical properties which make the copolymers moldable. They are free from the problem of plasticizer bleeding and can be degraded by microorganisms present in soils or water. They give moldings, such as sheets and films, which combine a sufficient strength with tear resistance. When the copolymers are ones having a branched structure, they give a molding having excellent mechanical properties. The moldings obtained from compositions containing either of these copolymers are excellent in elongation and biodegradability and have a satisfactory balance therebetween. In particular, blending with one or more other biodegradable resins gives a molding having better moldability.

公开(公告)号：DE69708032T2

公开(公告)日：2002-03-14

申请号：DE69708032

申请日：1997-12-15

Applicant: DAICEL CHEM

Inventor： TAKAHASHI IKUO ,  ITO MASAAKI

IPC: C07C67/00 ,  C07C67/02 ,  C07C69/017

Abstract: This method provides a novel trimethylcatechol diester, i.e. 3,4,5-trimethylcatechol diester, at a high yield by reacting 2,6,6-trimethylcyclohexe-2-en-1,4-dione with an acylating agent in the presence of an acid catalyst. The acylating agent includes a C2-4 carboxylic acid anhydride (e.g. acetic anhydride) and a C2-4 carboxylic acid halide (e.g. acetyl chloride). The catalyst includes a protonic acid and a Lewis acid. Use of a polar solvent (e.g. halogenated hydrocarbon), as the reaction catalyst, results in an enhanced efficiency in the production of the object compound.

公开(公告)号：DE69708032D1

公开(公告)日：2001-12-13

申请号：DE69708032

申请日：1997-12-15

Applicant: DAICEL CHEM

Inventor： TAKAHASHI IKUO ,  ITO MASAAKI

IPC: C07C67/00 ,  C07C67/02 ,  C07C69/017

Abstract: This method provides a novel trimethylcatechol diester, i.e. 3,4,5-trimethylcatechol diester, at a high yield by reacting 2,6,6-trimethylcyclohexe-2-en-1,4-dione with an acylating agent in the presence of an acid catalyst. The acylating agent includes a C2-4 carboxylic acid anhydride (e.g. acetic anhydride) and a C2-4 carboxylic acid halide (e.g. acetyl chloride). The catalyst includes a protonic acid and a Lewis acid. Use of a polar solvent (e.g. halogenated hydrocarbon), as the reaction catalyst, results in an enhanced efficiency in the production of the object compound.

公开(公告)号：ID20726A

公开(公告)日：1999-02-25

申请号：ID981026

申请日：1998-07-20

Applicant: DAICEL CHEM

Inventor： KATAYAMA MASAHIRO ,  ITO MASAAKI ,  OTSUKA YOSHIHIRO

IPC: C08L69/00 ,  C08L101/00 ,  C08L25/10 ,  C08L25/04

Abstract: A thermoplastic resin composition can be obtained by adding about 0.1 to 20 parts by weight of a diene-series block copolymer (2) to 100 parts by weight of a resin composition containing a polycarbonate-series resin (1) as a basic component of which the proportion of terminal hydroxy groups relative to the whole of the terminals is 1 mole% or above (about 5 to 40 mole%). The polycarbonate-series resin base may further comprise a thermoplastic resin composition (3) such as a rubber-modified styrenic resin. The block copolymer component (2) includes an epoxy-modified block copolymer, etc. When added an organophosphorus compound as a flame retardant (4), or a fluorine-containing resin as a flame-retartant auxiliary (5), a halogen-free flame-retardant thermoplastic resin composition can be obtained. A thermoplastic resin with an improved flowability and impact strength can be obtained by modifying a polymer blend of the polycarbonate-series resin and the styrenic-series resin in quality.

公开(公告)号：JP2002293900A

公开(公告)日：2002-10-09

申请号：JP2001101183

申请日：2001-03-30

Applicant: DAICEL CHEM

Inventor： KATAYAMA HIROSHI ,  OKANO YOSHIMICHI ,  ITO MASAAKI

IPC: C08G63/60 ,  C08G63/87 ,  C08G63/91 ,  C08L101/16

Abstract: PROBLEM TO BE SOLVED: To obtain a biodegradable high molecular weight copolyester having practically usable physical properties and formable into a film as well, and to provide a method for producing the copolyester enabling to supply it industrially. SOLUTION: This high molecular weight aliphatic copolyester having weight average molecular weight of >=40,000 is composed of a repeating unit (P) derived from succinic acid-1,4-butane diol, a repeating unit (Q) derived from ε- caprolactone and a repeating unit (R) derived from a lactide.

公开(公告)号：JP2001303019A

公开(公告)日：2001-10-31

申请号：JP2000121719

申请日：2000-04-21

Applicant: DAICEL CHEM

Inventor： TAKEMOTO SHIN ,  ITO MASAAKI

IPC: C09J7/02 ,  C09J11/06 ,  C09J201/00 ,  G09F3/10

Abstract: PROBLEM TO BE SOLVED: To provide a water soluble heat sensitive self-adhesive composition capable of giving a heat sensitive self-adhesive sheet having such a property that the sheet attached to an adherend such as a container, is easily released by the use of water at ordinary temperature, when the composition is used as a self-adhesive for the heat sensitive self-adhesive sheet (label). SOLUTION: This water soluble heat sensitive self-adhesive composition contains a solid plasticizer, a thermoplastic resin, and a tackifier, wherein the composition further contains a hydrophilic component in an amount of 0.05-5 wt.% converted to a solid material. The solid plasticizer preferably comprises (i) a polyester compound of a hydroxy compound with a polybasic acid, (ii) an ester compound of a polyhydroxy compound with an organic monobasic acid, and (iii) a phosphor compound. The hydrophilic component preferably comprises at least one component selected from a group comprising a nonionic surfactant having a hydrophilic-lipophilic balance (HLB) of >=15, phosphoric acid ester salts, and dialkylsulfosuccinic acid salts.

公开(公告)号：JPH11277688A

公开(公告)日：1999-10-12

申请号：JP8157098

申请日：1998-03-27

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： ITO MASAAKI ,  IGUCHI TAKEHIKO

IPC: B32B27/30 ,  C09D7/12 ,  C09D171/00

Abstract: PROBLEM TO BE SOLVED: To obtain a styrenic resin sheet capable of continuing anti-fogging properties at low temp. and high temp. for a long time. SOLUTION: An anti-fogging styrenic resin sheet is obtained by applying an anti-fogging agent containing sugar fatty acid ester and polyglycerine fatty acid ester with an HLB of about 11-18 to at least one surface of a styrenic resin sheet. The ratio of sugar fatty acid ester and polyglycerine fatty acid ester is about former/latter = 55/45-98/2 (pts.wt.). Polyglycerine fatty acid ester is constituted of about 12-26C fatty acid. The anti-fogging agent may contain about 0-50 pts.wt. of a nonionic surfactant and/or about 0-400 pts.wt. of a mold release agent per 100 pts.wt. of fatty acid esters. The styrenic resin sheet can be produced by applying the anti-fogging agent to at least one surface of the sheet and suitable for molding a container.

Abstract translation: 要解决的问题：获得能够在低温下持续防雾性能的苯乙烯树脂片。 和高温 需很长时间。 解决方案：通过将含有约11-18的HLB的糖脂肪酸酯和聚甘油脂肪酸酯的防雾剂施加到苯乙烯树脂片的至少一个表面上来获得防雾苯乙烯树脂片。 糖脂肪酸酯和聚甘油脂肪酸酯的比率约为前者/后者= 55 / 45-98 / 2（重量）。 聚甘油脂肪酸酯由约12-26℃脂肪酸构成。 防雾剂可以含有约0-50重量份 的非离子表面活性剂和/或约0-400重量份 的脱模剂每100重量份 的脂肪酸酯。 苯乙烯树脂片可以通过将防雾剂施加到片材的至少一个表面并适于成型容器来制造。