公开(公告)号：MY128472A

公开(公告)日：2007-02-28

申请号：MYPI20021717

申请日：2002-05-13

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO ,  OHTSUKA YOSHIHIRO

IPC: C08C19/06 ,  C08F8/08 ,  C08G59/34

Abstract: A PROCESS FOR PRODUCING AN EPOXIDIZED DIENE POLYMER INCLUDES: DISPERSING OR SUSPENDING A DIENE POLYMER (C) HAVING A BALL-REDUCED PARTICLE SIZE OF 0.05 - - 20 MM IN A MEDIUM (A) IN THE PRESENCE OF POWDER PARTICLES (B) INSOLUBLE IN THE MEDIUM (A) , OR IN AN AQUEOUS MEDIUM IN THE PRESENCE OF A PHENOL-BASED STABILIZER AND/OR A PHOSPHORUS-BASED STABILIZER; AND EPOXIDIZING THE DIENE POLYMER (C) BY AN EPOXIDIZING AGENT, THEREFORE, PROBLEMS ASSOCIATED WITH EPOXIDATICN PERFORMED BY DISSOLVING DIENE POLYMER IN A SOLVENT ARE ELIMINATED; AN ECONOMICAL METHOD FOR EPOXIDIZING, PRODUCING, AND PURIFYING A DIENE POLYMER (C) IN A SOLID FORM IS PROVIDED; EPOXIDIZED DIENE POLYMER HAVING AN EXCELLENT HEAT STABILITY CAN BE OBTAINED.

公开(公告)号：MY140720A

公开(公告)日：2010-01-15

申请号：MYPI20015209

申请日：2001-11-13

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO ,  OHTSUKA YOSHIHIRO ,  WATANABE NOBUYUKI

IPC: C08F8/08 ,  C08C19/06 ,  C08F6/00

Abstract: AN EPOXIDIZED GRANULAR THERMOPLASTIC POLYMER WHICH COMPRISES A SHELL LIKE SURFACE LAYER INSOLUBLE IN TOLUENE AT 25°C IS FORMED ON THE POLYMER, AND A PROCESS FOR THE PRODUCTION OF THE EPOXIDIZED GRANULAR THERMOPLASTIC POLYMER CHARACTERIZED IN THAT THE PROCESS COMPRISES: THE FIRST STEP OF EPOXIDIZING A GRANULAR THERMOPLASTIC POLYMER IN A WATER MEDIUM IN THE PRESENCE OF AN ACCELERATING AN EPOXIDATION AGENT OR THE EPOXIDIZING AGENT AND A SOLVENT FOR ACCELERATING AN EPOXIDATION AGENT AND A SOLVENT FOR ACCELERATING AN EPOXIDATION REACTION AND A PHOSPHORIC ACID SERIES COMPOUND: THE SECOND COMPOUND STEP OF THE WASHING WITH WATER, OR THE NEUTRALIZATION AND WASHING WITH WATER OF THE EPOXIDIZED GRANULAR THERMOPLASTIC POLYMER; AND THE THIRD STEP, IF NECESSARY, OF REMOVING THE SOLVENT FOR ACCELERATING EPOXIDATION REACTION WHICH MAY BY USED IN THE FIRST STEP, AS WELL AS A PROCESS FOR THE PRODUCTION OF AN EPOXIDIZED THERMOPLASTIC POLYMER, CHARACTERIZED IN THAT UNDER CONDITION IN WHICH THERMOPLASTIC POLYMER (A) IN THE SOLID-STATE IS DISPERSED OR SUSPENDED IN WATER (B), THE THERMOPLASTIC POLYMER (A) IS EPOXIDIZED BY A PEROXIDE (C) WITH THE DISPERSED OR SUSPENDED STATE MAINTAINED.

公开(公告)号：EP1348718A4

公开(公告)日：2006-05-03

申请号：EP01993628

申请日：2001-11-12

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO ,  OHTSUKA YOSHIHIRO ,  WATANABE NOBUYUKI

IPC: C08C19/06 ,  C08F6/00 ,  C08F8/08

CPC classification number: C08C19/06 ,  C08F6/00 ,  C08F8/08 ,  Y10S525/902 ,  C08F297/046 ,  C08F297/04

Abstract: Epoxidized granular thermoplastic polymers characterized by having a shelly surface layer insoluble in toluene at 25 DEG C; a process for the production of the epoxidized granular thermoplastic polymers, characterized by comprising the first step of epoxidizing a granular thermoplastic polymer in an aqueous medium in the presence of both an epoxidizing agent optionally combined with an epoxidation-accelerating solvent, and a phosphoric acid compound, the second step of subjecting the obtained epoxidized granular thermoplastic polymer to water washing which may be accompanied by neutralization, and, if necessary, the third step of removing the solvent used at need in the first step; and a process for the production of epoxidized thermoplastic polymers, characterized by dispersing a solid thermoplastic polymer (A) in water (B) and epoxidizing the polymer with a peroxide (C) while keeping the polymer in the dispersed or suspended state.

公开(公告)号：EP1403287A4

公开(公告)日：2004-12-01

申请号：EP02769581

申请日：2002-05-13

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO ,  OHTSUKA YOSHIHIRO

IPC: C08C19/06 ,  C08F8/08 ,  C08G59/34

CPC classification number: C08G59/027 ,  C08C19/06 ,  C08F8/08 ,  C08F297/04 ,  C08F297/046

Abstract: A process for producing an epoxidized diene polymer which comprises: dispersing or suspending a diene polymer (C) having a particle diameter in terms of sphere diameter of 0.05 to 20 mm either in a medium (A) in the presence of powder particles (B) insoluble therein or in a water medium in the presence of a phenolic stabilizer and/or phosphorus compound stabilizer; and epoxidizing the diene polymer (C) in the dispersed or suspended state with an epoxidizing agent. Thus, an epoxidized diene polymer having excellent thermal stability is obtained. By the process, the epoxidation of the diene polymer (C) in a solid state and the production and purification of the target polymer are economically conducted. The process is free from various problems associated with the epoxidation of a diene polymer dissolved in a solvent.

公开(公告)号：EP1288259A4

公开(公告)日：2003-07-02

申请号：EP01930068

申请日：2001-05-11

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO

IPC: C08F8/00 ,  C08L63/08 ,  C08L45/00 ,  C08J5/18 ,  C08L23/18

CPC classification number: C08L63/08 ,  C08F8/08 ,  C08L2666/04 ,  C08F297/04

Abstract: A composition comprising as essential ingredients (A) 80 to 95 wt.% noncrystalline cyclic polyolefin and (B) 20 to 5 wt.% epoxidized diene block copolymere. The composition gives a noncrystalline cyclic polyolefin sheet which has a degree of heat distortion of 5% or lower at a heat fusion temperature of 95 to 160°C. The sheet is excellent in moldability, dimensional stability, and bonding strength in fusion bonding and is excellent also in impact resistance, flexing resistance, and suitability for embossing.

公开(公告)号：JP2002097289A

公开(公告)日：2002-04-02

申请号：JP2000290958

申请日：2000-09-25

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO

IPC: B01D71/80 ,  B01D71/82 ,  B01J47/12 ,  C08G59/50 ,  C08J5/22

Abstract: PROBLEM TO BE SOLVED: To provide a practical anion exchange membrane having thin gage, low electric resistance, high mechanical strength, high selective permeability of anions and durability together with good moldability. SOLUTION: This anion exchange membrane comprises an epoxized diene block copolymer as the base material and has a crosslinked structure with a multivalent amine.

公开(公告)号：JP2001323231A

公开(公告)日：2001-11-22

申请号：JP2000140437

申请日：2000-05-12

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO

IPC: C08J7/04 ,  B32B7/12 ,  B32B27/00 ,  C09J7/02 ,  C09J123/00 ,  C09J153/02 ,  C09J163/08

Abstract: PROBLEM TO BE SOLVED: To obtain a protective film having a temporary adhesive force of moderateness to an adherend, slight adhesion advance, not contaminating an adherend with an adhesive when the film is peeled from the adherend and not damaging the adherend when the film is peeled. SOLUTION: This protective film is characterized in that an adhesive layer comprising a polyolefin-based resin and a block copolymer composed of a polymer block consisting essentially of a vinylaromatic hydrocarbon compound and a polymer block consisting essentially of a conjugated diene compound or an epoxidized diene-based copolymer obtained by epoxidizing a partially hydrogenated substance of the block copolymer is laminated to one side of a substrate composed of a thermoplastic resin.

公开(公告)号：JP2007332389A

公开(公告)日：2007-12-27

申请号：JP2007243378

申请日：2007-09-20

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： YABUI AKIHIRO ,  OTSUKA YOSHIHIRO

IPC: C08F8/08

Abstract: PROBLEM TO BE SOLVED: To conquer the stickiness of epoxidized thermoplastic polymers and the troublesome handling by blocking nature or the like and to provide epoxidized thermoplastic polymers excellent in workability and processes for their production. SOLUTION: An epoxidized granular thermoplastic polymer comprises a shell-like surface layer insoluble in toluene at 25°C formed on the polymer. The process for the production of the epoxidized granular thermoplastic polymer comprises: the first step of epoxidizing a granular thermoplastic polymer in a water medium in the presence of an epoxidizing agent or the epoxidizing agent and a solvent for accelerating an epoxidation reaction and a phosphoric acid series compound; the second step of the washing with water, or the neutralization and washing with water of the epoxidized granular thermoplastic polymer; and the third step, if necessary, of removing the solvent for accelerating epoxidation reaction which may be used in the first step. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 待解决的问题：解决环氧化热塑性聚合物的粘性和通过阻断性质等麻烦的处理，并提供可加工性优异的环氧化热塑性聚合物及其制备方法。 解决方案：环氧化颗粒状热塑性聚合物包含在聚合物上形成的25℃不溶于甲苯的壳状表面层。 生产环氧化颗粒状热塑性聚合物的方法包括：在环氧化剂或环氧化剂和用于加速环氧化反应和磷酸系的溶剂的存在下，在水介质中环氧化粒状热塑性聚合物的第一步骤 复合; 用水洗涤的第二步骤，或环氧化颗粒状热塑性聚合物用水中和和洗涤; 如果需要，可以在第一步骤中除去用于加速环氧化反应的溶剂的第三步骤。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2002179928A

公开(公告)日：2002-06-26

申请号：JP2000383412

申请日：2000-12-18

Applicant: DAICEL CHEM

Inventor： MIKI AKIKO ,  ONISHI MASAYA ,  YABUI AKIHIRO

IPC: C08L101/00 ,  C08L25/12 ,  C08L53/00 ,  C08L67/00

Abstract: PROBLEM TO BE SOLVED: To provide a heat-sensitive, thermoplastic resin composition processable by a general molding method such as injection molding, extrusion molding and the like, excellent in mechanical characteristics, applicable to various fields and having good transparency in the room temperature region though turned opaque at a higher temperature. SOLUTION: The heat-sensitive, thermoplastic resin composition comprises a noncrystalline polyester resin (A) and a vinyl cyanide/aromatic vinyl copolymer (B). In another embodiment, the heat-sensitive, thermoplastic resin composition comprises a noncrystalline polyester resin (A), a vinyl cyanide/aromatic vinyl copolymer (B), and an epoxidized diene-based block copolymer (C) and/or a diene-based block copolymer (D).

公开(公告)号：JP2002098662A

公开(公告)日：2002-04-05

申请号：JP2000290957

申请日：2000-09-25

Applicant: DAICEL CHEM

Inventor： YABUI AKIHIRO

IPC: G01N27/333 ,  C08F8/00 ,  C08F8/08 ,  C08F8/36 ,  C08F297/04 ,  C08J5/22 ,  G01N27/414 ,  G01N27/416

Abstract: PROBLEM TO BE SOLVED: To provide a sensitive film containing a polymer where an anion ion exchange group is subjected to covalent bond, and an anion ion selective electrode that is highly selective using the reactive film and is highly reliably in measurement. SOLUTION: In the anion ion selective reactive film containing the polymer of anion exchange properties, epoxidation diene-family block copolymer is used as one raw material constituent for the polymer with the anion ion exchange properties. Further, by forming the epoxy group of the epoxidation diene-family block copolymer into hydroxyl group, hydroxyl group is subjected to direct covalent bond to the polymer with the anion exchange properties. The anion selective electrode uses the anion selective film.