Abstract:
PROBLEM TO BE SOLVED: To provide a fluorine-containing elastomeric material excellent in processability and crosslinkability while keeping mechanical properties and thermal resistance, and to provide a composition for crosslinking. SOLUTION: The fluorine-containing elastomeric copolymer is obtained by copolymerizing (A) a fluorine-containing vinyl ether monomer mixture which is a mixture of a fluorine-containing vinyl ether monomer (Ia) expressed by formula (I) (wherein Rf is a perfluoroalkylidene group or a perfluorooxyalkylidene group; X is a CN group, COOH group or COOR group) and having a peak at -143 to -145 ppm in 19 F-NMR, and a fluorine-containing vinyl ether monomer (Ib) being a structural isomer of the monomer (Ia) and having a peak at -141 to -142 ppm in 19 F-NMR, where the mixing ratio (Ib)/(Ia) in terms of the peak intensity at -141 to -142 ppm/the peak intensity at -143 to -145 ppm of ≥0.02, (B) a fluorine-containing vinyl monomer excluding the fluorine-containing vinyl ether monomers (Ia) and (Ib), and optionally (C) a non-fluorine-based monomer. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To provide a laminate in which a layer made of thermoplastic elastomer and a layer made of fluorine-containing polymer are rigidly made to adhere. SOLUTION: The laminate is obtained by laminating a thermoplastic elastomer layer A made of thermoplastic elastomer 1a and fluorine-containing polymer layer B made of fluorine-containing polymer b1 via an intermediate layer C. The layer C contains thermoplastic polymer a2 having adhesive properties to the elastomer a1 and fluorine-containing polymer b2 having adhesive properties to the polymer b1. The morphology in the layer C has a sea-island structure. The the polymer a2 forms sea phase and the polymer b2 forms island phase in the vicinity of the boundary to the layer A. The polymer b2 forms a sea phase and the polymer a2 forms an island phase in the vicinity of the boundary to the layer B.
Abstract:
PROBLEM TO BE SOLVED: To provide a composition for crosslinking a fluororubber giving a crosslinked product having particularly improved mechanical strength and compression set at a high temperature. SOLUTION: The composition for crosslinking a fluororubber comprises a perfluoroelastomer having a carboxy group and/or an alkoxycarbonyl group at both ends of a main chain, as a crosslinkable group, and a crosslinking agent reacting with the carboxy group or the alkoxycarbonyl group and being used in an oxazole crosslinking system, an imidazole crosslinking system, or a thiazole crosslinking system. COPYRIGHT: (C)2007,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide an elastomer composition capable of cross-linking which gives a cross-linked product having improved mechanical strength and heat resistance. SOLUTION: This elastomer composition for cross-linking comprises (A) a compound containing at least two cross-linkable reactive groups represented by formula (I) and (B) an elastomer having a cross-linkable position that is reactable with the cross-linkable reactive groups (I).
Abstract:
PROBLEM TO BE SOLVED: To provide a crosslinkable elastomer composition in which generation of HF under high temperature conditions can be reduced, a change in weight to both NF 3 plasma treatment and O 3 treatment in a semiconductor manufacturing process is small and generation of foreign substances (particles) in these treatments is suppressed significantly. SOLUTION: The crosslinkable elastomer composition contains a filler formed of a non-oxide ceramic in an amount of 1-50 parts by weight to 100 parts by weight of a crosslinkable elastomer. COPYRIGHT: (C)2009,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a fluoroelastomer composition having a short crosslinking time. SOLUTION: The fluoroelastomer composition comprises two or more perfluoroelastomers (A) that have a tetrafluoroethylene unit, a perfluoroalkyl vinyl ether unit (a) and a monomer unit (b) bearing at least one selected from the group consisting of a nitrile group, a carboxy group and an alkoxycarboxy group and are different in the content of the perfluoroalkyl vinyl ether unit (a) from each other. COPYRIGHT: (C)2009,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a cross-linkable fluorine elastomer composition that is prepared by using a very clean filler reduced in both of an amount of moisture generation and an amount of organic outgas generation and is suitable as a molding material for semiconductor production apparatuses and to provide molded articles. SOLUTION: The cross-linkable fluorine elastomer composition comprises the filler that has a weight-reduction ratio per unit surface area of not more than 2.5 × 10 -5 wt.%/m 2 , when being heated at 200°C for two hours and the total amount of organic gas generated of less than 2.5 ppm, when heated at 200°C for 15 minutes and the cross-linkable fluorine elastomer. The molded particle is produced from the cross-linkable composition. COPYRIGHT: (C)2007,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a compatibility-improving agent for a thermoplastic resin composition consisting of various heat resistant thermoplastic resins and a functional group-containing fluorine polymer well compatible with them and capable of being uniformly dispersed. SOLUTION: This compatibility-improving agent for the thermoplastic resin composition consists of a blended material obtained by mixing (a) 0.1-99 wt.% flurorine-containing polymer containing hydroxyl or epoxy group on at least one of the terminals of a main or side chain of the polymer and having 2,000-1,000,000 number-average molecular weight and (b) 1-99.9 wt.% heat- resistant thermoplastic resin such as a polyamide or an aromatic polyester having ≥150°C crystal melting point or glass transition point. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To provide a molded product of a fluorine-containing elastomer capable of withstanding the use at a high temperature of ≥230°C. SOLUTION: A modified inorganic filler is an inorganic filler (except a carbon filler) having ≤0.5 μm primary average particle diameter and is obtained by subjecting the inorganic filler to a treatment for reducing the surface activity thereof. A fluorine-containing elastomer composition for crosslinking comprises the fluorine-containing elastomer having crosslinkable groups and a crosslinking agent and/or a crosslinking promoter. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To obtain a filler which shows a specified or smaller difference between the weights before and after irradiation with an oxygen plasma and irradiation with a CF4 plasma under specified conditions, which filler has thermally and chemically stable aromatic rings in the main chain and has a specified or higher heat resistance temperature. SOLUTION: This filler shows a difference of at most 4 mg/cm2 between the weights before and after irradiation with an oxygen plasma and with a CF4 plasma under conditions including a flow rate of 200 scm, a pressure of 280 mTor, an RF electric power of 400 W, and an irradiation time of 54 min, has aromatic rings in the main chain, and has a heat resistance temperature of at least 150 deg.C. It is desirable that the filler is a synthetic polymer having amide bonds or imide bonds in the main chain. The synthetic polymer is exemplified by a polyimide or a polyamide-imide. It is desirable that the crosslinkable elastomer composition is one which comprises 100 pts.wt. crosslinkable elastomer, 1-150 pts.wt. above filler, and 0.05-10 pts.wt. crosslinking agent and in which the crosslinkable elastomer is a fluoro or silicone elastomer.