Abstract:
The invention relates to novel quaternary amino alcohol functional organosilicon compounds, aqueous compositions containing the latter, and a method for their production, in particular in the form of oligomers and polymers which can be present in the partially or fully hydrolyzed form and are in particular water-soluble. The compositions comprise only an extremely small portion of VOCs. The invention further relates to their use, preferably in the production of inkjet photographic papers.
Abstract:
Aqueous dispersion obtainable by placing in water an aggregated titanium dioxide powder having a specific surface area of from 20 to 150 m 2 /g in such an amount that the desired dispersion comprises at least 20 wt.% titanium dioxide, and at least one amino alcohol having from 1 to 6 carbon atoms, and at least one carboxylic acid from the group comprising dibasic carboxylic acids and/or hydroxycarboxylic acids having from 2 to 6 carbon atoms, - the amino alcohol being present in the dispersion in an amount of from 2.5 to 7.0 µmol./m 2 specific surface area TiO 2 and the carboxylic acid being present in an amount of from 1.0 to 3.5 µmol./m 2 specific surface area TiO 2 , - producing a pre-dispersion by introducing energy in an amount of less than 200 kJ/m 3 and then producing a dispersion in which the aggregated titanium dioxide powder has a mean, volume-related aggregate diameter of less than 150 nm by grinding the pre-dispersion by means of a high-energy mill at a pressure of at least 500 bar. The dispersion can be used in the coating of glass, ceramics and metal surfaces.
Abstract translation:通过将具有20至150m 2 / g的比表面积的聚集的二氧化钛粉末放置在水中而获得的水溶液,其量使得所需的分散体包含至少20重量%的二氧化钛 和至少一种具有1至6个碳原子的氨基醇,和至少一种含有二元羧酸和/或具有2至6个碳原子的羟基羧酸的羧酸, - 氨基醇存在于分散体 其量为2.5至7.0μmol/ m 2比表面积TiO 2,羧酸的存在量为1.0-3.5μmol/ m 2 比表面积TiO 2 2,通过引入少于200kJ / m 3的量的能量产生预分散,然后 产生其中聚集的二氧化钛粉末通过研磨预分散剂具有小于150nm的平均体积相关聚集体直径的分散体 通过在至少500巴的压力下的高能磨机。 分散体可用于玻璃,陶瓷和金属表面的涂层。
Abstract:
Aluminium oxide powder produced by flame hydrolysis and consisting of aggregates of primary particles, having a BET surface area of from 100 to 250 m /g, a dibutyl phthalate absorption of from 50 to 450 g/100 g of aluminium oxide powder, which powder shows only crystalline primary particles in high-resolution TEM pictures. It is prepared by vaporising aluminium chloride, transferring the vapour by means of a carrier gas to a mixing chamber and, separately therefrom, supplying hydrogen, air (primary air), which may optionally be enriched with oxygen and/or may optionally be pre-heated, to the mixing chamber, then igniting the mixture of aluminium chloride vapour, hydrogen, air in a burner and burning the flame into a reaction chamber that is separated from the surrounding air, subsequently separating the solid material from the gaseous substances and then treating the solid material with steam and optionally with air, the discharge rate of the reaction mixture from the mixing chamber into the reaction chamber being at least 10 m/s, and the lambda value being from 1 to 10 and the gamma value being from 1 to 15. It can be used as an ink-absorbing substance in ink-jet media.
Abstract:
Powder consisting of particles with a core of titanium dioxide and a coating of silicon dioxide, which powder has a content of silicon dioxide of between 0.5 and 40 wt.%, a BET surface of between 5 and 300 m /g, and which consists of primary particles that have a coating of silicon dioxide and a core of titanium dioxide. The powder is produced according to a process in which a vaporisable silicon compound and a vaporisable titanium compound are mixed corresponding to the subsequently desired ratio of SiO2 and TiO2 in the product, are vaporised at temperatures of 200°C or less, and conveyed by means of an inert gas stream together with hydrogen and air or with oxygen-enriched air to the central pipe (core) of a known burner, the reaction mixture is ignited at the mouth of the burner and introduced together with secondary air, is combusted in a cooled flame pipe, following which the titanium dioxide powder coated with silicon dioxide is separated from the gaseous reaction products and if necessary is freed in moist air from adhering hydrogen chloride, the ratio of primary air to secondary air being greater than 0.3, the ratio of core hydrogen to secondary air being greater than 1, and the ratio of titanium dioxide precursor to secondary air being greater than 0.5. Sunscreen agent containing the powder in an amount of between 0.01 and 25 wt.%.
Abstract:
Dispersión acuosa obtenible - al disponer en agua un polvo de dióxido de titanio agregado que tiene un área superficial específica de 20 a 150 m2/g en una cantidad tal que la dispersión deseada comprenda al menos 20% en peso de dióxido de titanio, y al menos un amino alcohol que tenga de 1 a 6 átomos de carbono y al menos un ácido carboxílico del grupo que comprende ácidos carboxílicos dibásicos y/o ácidos hidroxicarboxílicos que tienen de 2 a 6 átomos de carbono, - estando presente el aminoalcohol en la dispersión en una cantidad de 2,5 a 7,0 μmol/m2 de área de superficie específica de TiO2 y estando presente el ácido carboxílico en una cantidad de 1,0 a 3,5 μmol/m2 de área de superficie específica de TiO2, - produciendo una pre-dispersión mediante la introducción de energía en una cantidad inferior a 200 kJ/m3 y luego produciendo una dispersión en la que el polvo de dióxido de titanio agregado tiene un diámetro de agregado medio relacionado con el volumen de menos de 150 nm moliendo la pre-dispersión por medio de un molino de alta energía a una presión de al menos 500 bares.
Abstract:
Dispersion obtainable by reacting a) in 50 to 75 parts by weight of water b) 25 to 50 parts by weight of silica particles having a BET surface area of 30 to 500 m2/g and c) 100 to 300 µg/m2 BET surface area of the silica particles from b) parts by weight of one or more aminofunctional, organosilicon compounds, the aminofunctional, organosilicon compound being a quaternary, aminofunctional, organosilicon compound which is obtainable by reacting at least one haloalkylfunctional silane as component A with a tertiary amine as component B in the presence of a defined amount of water and at least partly removing the resulting hydrolysis alcohol from the system.
Abstract:
Process for preparing ultrafine powders based on polyamides by contacting polyamides having a relative solution viscosity &eegr;rel in the range from 1.5 to 2.0, measured in 0.5% m-cresol solution at 25° C., with an alcoholic medium in the presence of inorganic particles suspended therein under the action of pressure and/or temperature to generate an at least partial solution, and then precipitating the polyamide from the at least partial solution; the resulting ultrafine polyamide powders have a specific BET surface area of 5-100 m2/g; a fineness d50 of less than 70 μm; an apparent density AD from 250 to 1000 g/l; and a particle content of 0.1 to 80% by weight of inorganic particles based on the total weight of the polyamide powder; which powders are equally suitable for coatings and for mouldings and components with improved mechanical properties.
Abstract:
A method and device for producing a finely divided dispersion of solids having a mean particle size of 10 nm to 10 µm, in which at least two flows of a predispersion are sprayed by means of pumps, preferably high-pressure pumps, through one nozzle each into a grinding chamber enclosed by a reactor housing onto a collision point, wherein the grinding chamber is flooded with the predispersion and the finally divided dispersion is removed from the grinding chamber by the overpressure of the predispersion continuing to flow into the grinding chamber.