公开(公告)号：US3597253A

公开(公告)日：1971-08-03

申请号：US3597253D

申请日：1968-01-17

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  PFLEGER HANS ,  BERNDT WILHELM ,  NAUROTH PETER ,  FERCH HORST ,  EISENMENGER EDITH

IPC: C09C1/00 ,  C01B33/20 ,  C09C1/28 ,  C09C3/00

CPC classification number: C01B33/20 ,  Y10T428/2998

Abstract: PRODUCTION OF ORGANICALLY MODIFIED FINELY DIVIDED ALKALINE EARTH METAL AND EARTH METAL SILICATES AND SILICAS BY WET PRECIPITION OF SUCH SILICATES AND SILICAS FROM ALKALI METAL SILICATE SOLUTIONS WITH AQUEOUS SOLUTIONS OF ALKALINE EARTH METAL OR EARTH METAL SALTS OR ACIDS, PREFERABLY AT TEMPARATURES BETWEEN ABOUT 10 AND 90* C. IN THE PRESENCE OF WATER SOLUBLE REACTIVE POLYMERIC MATERIALS, FOR INSTANCE, POLYMERS CONTAINING THE REACTIVE AMINO, HYDROXYL, CARBOXYL, AMIDE OR KETO GROUPS. THE THUS OBTAINED MODIFIED SILICATES AND SILICAS CAN BE FURTHER MODIFIED BY EFFECTING REACTIONS WITH THE REACTIVE GROUPS OF THE BOUND POLYMERS IN THE SILICATES AND SILICAS.

公开(公告)号：US3656981A

公开(公告)日：1972-04-18

申请号：US3656981D

申请日：1970-04-24

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  PFLEGER HANS ,  FERCH HORST ,  EISENMENGER EDITH

IPC: C01B33/187 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  B01J39/16 ,  C01B33/193 ,  C08F8/00 ,  C09C1/00 ,  C09C1/28 ,  C09C1/30 ,  C09D7/00 ,  C09C3/00

CPC classification number: B01J39/17 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  C01B33/193 ,  C01P2004/61 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/80 ,  C08F8/00 ,  C09C1/3072 ,  C09D7/42

Abstract: A finely divided organically modified silica is formed by adding an inorganic acid at an elevated temperature to an aqueous alkali methyl silicate solution in contact with a water-soluble reactive organic polymer which is present in an amount of from about 3 to about 24 percent by weight relative to the weight of the thus precipitated silica.

Abstract translation: 通过将无机酸在升高的温度下加入与水溶性反应性有机聚合物接触的碱性甲基硅酸钠水溶液中形成细碎的有机改性二氧化硅，其以约3至约24重量％ 相对于如此沉淀的二氧化硅的重量。

公开(公告)号：GB1155523A

公开(公告)日：1969-06-18

申请号：GB2796267

申请日：1967-06-16

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  PFLEGER HANS ,  FERCH HORST ,  EISENMENGER EDITH

IPC: C01B33/187 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  B01J39/16 ,  B01J39/17 ,  C01B33/193 ,  C08F8/00 ,  C09C1/00 ,  C09C1/28 ,  C09C1/30 ,  C09D7/00

Abstract: 1,155,523. Organically - modified silica. DEUTSCHE GOLD-UND SILBER-SCHEIDEANSTALT. 16 June, 1967 [18 June, 1966], No. 27962/67. Heading C1A. Finely-divided organically modified silica is precipitated, preferably at 50-90‹ C., from a silicate solution, e.g. water glass, by an inorganic or organic acid in the presence of one or more water-soluble organic polymers capable of undergoing modification of their properties by chemical reactions and of combination with silica, e.g. polyvinyl alcohol, polyethylene imine, polyacrolein, polymethacrylic acid, polyethylene oxide, polyvinyl pyrrolidone, polyvinyl-3- methyl pyrrolidone, vinyl pyrrolidone/vinyl acetate copolymers, polyacrylamide. The polymer(s) may be dissolved in the reaction mixture before precipitation or gradually added thereto during precipitation; in some cases a pure silica core may be formed around an organicallymodified shell. The polymers may be caused to undergo organic reactions, e.g. substitution, addition, salt or complex formation, or may be refined by substantive, reactive or leuco dyes at any time after silica is first formed (although not necessarily precipitated): examples of such reactions are given.

公开(公告)号：DK134930B

公开(公告)日：1977-02-14

申请号：DK313567

申请日：1967-06-16

Applicant: DEGUSSA

Inventor： EISENMENGER EDITH ,  BESCHKE HELMUT ,  PFLEGER HANS ,  FERCH HORST

IPC: C01B33/187 ,  B01J21/00 ,  B01J21/04 ,  B01J21/08 ,  B01J39/16 ,  B01J39/17 ,  C01B33/193 ,  C08F8/00 ,  C09C1/00 ,  C09C1/28 ,  C09C1/30 ,  C09D7/00 ,  C01B33/18

公开(公告)号：BR8903808A

公开(公告)日：1990-03-20

申请号：BR8903808

申请日：1989-07-31

Applicant: DEGUSSA

Inventor： FERCH HORST ,  MATHIAS JOHANN ,  KAHNT GUNTER ,  KUPFER CHRISTIAN

IPC: A01G7/06 ,  A01N59/00 ,  A01N61/00

公开(公告)号：CA815598A

公开(公告)日：1969-06-17

申请号：CA815598D

Applicant: DEGUSSA

Inventor： FERCH HORST ,  GRUTTNER SIEGFRIED

公开(公告)号：BR8903809A

公开(公告)日：1990-03-20

申请号：BR8903809

申请日：1989-07-31

Applicant: DEGUSSA

Inventor： FERCH HORST ,  MATHIAS JOHANN ,  KAHNT GUNTER ,  KUPFER CHRISTIAN

IPC: A01C1/00 ,  A01C1/02 ,  A01C1/06 ,  A01N59/00 ,  A01N61/00 ,  A01N25/26

公开(公告)号：CA864016A

公开(公告)日：1971-02-16

申请号：CA864016D

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  EISENMENGER EDITH ,  FERCH HORST ,  PFLEGER HANS

公开(公告)号：GB1139620A

公开(公告)日：1969-01-08

申请号：GB2932367

申请日：1967-06-26

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  PFLEGER HANS ,  FERCH HORST ,  EISENMENGER EDITH

IPC: C09C1/00 ,  C09C1/28 ,  C09C1/40 ,  C09C1/56

Abstract: 1,139,620. Modified carbon black. DEUTSCHE GOLDUND SILBER-SCHEIDEANSTALT. 26 June, 1967 [24 June, 1966], No. 29323/67. Heading C1A. [Also in Division C4] A grey pigment comprising carbon black and a finely divided metal and/or metalloid oxide is obtained by activating the surface of the carbon black by reaction with a silicon or titanium halide, particularly the tetrachloride, and subsequently hydrolysing the activated carbon by introducing it either into water, or into a suspension of a finely divided precipitated or pyrogenic oxide of silicon and/or titanium and/or aluminium, or into a precipitation solution of a salt of one of these elements. The process is applicable to lamp black, of average particle size 100-200 mÁ, or to furnace black of 20-100 mÁ.

公开(公告)号：CA781538A

公开(公告)日：1968-03-26

申请号：CA781538D

Applicant: DEGUSSA

Inventor： BRUNNER HELMUT ,  FERCH HORST ,  KALLRATH GOTTFRIED ,  BIEGLER HANNS