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1.
公开(公告)号:JPH1087675A
公开(公告)日:1998-04-07
申请号:JP19389097
申请日:1997-07-18
Applicant: DEGUSSA
Inventor: GORL UDO , LAMBERTZ HORST
IPC: C08L19/00 , B60C1/00 , C07F7/08 , C07F7/18 , C08G77/48 , C08K5/548 , C08L7/00 , C08L21/00 , C08L83/08
Abstract: PROBLEM TO BE SOLVED: To obtain the subject mixture suitable for producing tire excellent in resistance to wet skid, etc., without causing scorch at a high temperature which may occur during production of vulcanizable rubber compound by including a specific organosilanepolysulfane. SOLUTION: This organosilinepolysulfane mixture is represented by the formula [R is a 1-8C alkyl; (x) is 1-8; (z) is 0-6, with the proviso that a ratio of a polysulfane in which (z) is an integer of 2-6 is
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公开(公告)号:AU723875B2
公开(公告)日:2000-09-07
申请号:AU2872197
申请日:1997-07-17
Applicant: DEGUSSA
Inventor: GORL UDO , LAMBERTZ HORST
IPC: C08L19/00 , B60C1/00 , C07F7/08 , C07F7/18 , C08G77/48 , C08K5/548 , C08L7/00 , C08L21/00 , C08L83/08 , C08G77/04 , C08G77/28 , C08K3/36 , C08J3/24 , C08L83/04
Abstract: A mixture (I) of organosilane polysulphides (II) of formula (RO)3Si(CH2)xS-Sz-S(CH2)xSi(OR)3 (1) is new. The mixture contains 20 wt.% or less (1) when z = 2-6 and less than 80 wt.% (1) when z = 0. In (1), R = 1-8C alkyl, preferably 1-3C alkyl; x = 1-8; and z = 0-6. Also claimed are (i) preparation of sulphur, sulphur donor and accelerator vulcanised rubber mixtures containing one or more natural or man-made rubber, silicate, fillers, optionally carbon black and other components, the rubber, fillers, carbon black, optionally plasticiser, anti-oxidants, activators and (I) being mixed at 160-200 degrees C for 3-15 minutes followed by the addition of vulcanisation agents at 60-120 degrees C and mixing for a further 2-10 minutes to yield sheet or strips; (ii) tyre tread compounds with a high silicic acid content containing 4-10 parts weight (pts. wt.) (I) to 100 pts. wt. filler.
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3.
公开(公告)号:SK96797A3
公开(公告)日:1998-02-04
申请号:SK96797
申请日:1997-07-16
Applicant: DEGUSSA
Inventor: GORL UDO , LAMBERTZ HORST
IPC: C08L19/00 , B60C1/00 , C07F7/08 , C07F7/18 , C08G77/48 , C08K5/548 , C08L7/00 , C08L21/00 , C08L83/08 , C08K5/54
Abstract: A mixture (I) of organosilane polysulphides (II) of formula (RO)3Si(CH2)xS-Sz-S(CH2)xSi(OR)3 (1) is new. The mixture contains 20 wt.% or less (1) when z = 2-6 and less than 80 wt.% (1) when z = 0. In (1), R = 1-8C alkyl, preferably 1-3C alkyl; x = 1-8; and z = 0-6. Also claimed are (i) preparation of sulphur, sulphur donor and accelerator vulcanised rubber mixtures containing one or more natural or man-made rubber, silicate, fillers, optionally carbon black and other components, the rubber, fillers, carbon black, optionally plasticiser, anti-oxidants, activators and (I) being mixed at 160-200 degrees C for 3-15 minutes followed by the addition of vulcanisation agents at 60-120 degrees C and mixing for a further 2-10 minutes to yield sheet or strips; (ii) tyre tread compounds with a high silicic acid content containing 4-10 parts weight (pts. wt.) (I) to 100 pts. wt. filler.
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公开(公告)号:GB2259303B
公开(公告)日:1994-07-20
申请号:GB9217649
申请日:1992-08-19
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , GORL UDO
IPC: C08J3/24 , C08K5/00 , C08K5/36 , C08K5/39 , C08K5/40 , C08K5/548 , C08K5/58 , C08L21/00 , C08K5/54
Abstract: In a process for the production of vulcanizable moulding compounds consisting of one or more natural or synthetic rubbers or polymers the quantity of accelerators from the class of thiurams and/or dithiocarbamates is reduced to half the quantity originally required through the use of 3-thiocyanatopropyl trialkoxy silanes.
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公开(公告)号:ZA9107339B
公开(公告)日:1992-06-24
申请号:ZA9107339
申请日:1991-09-13
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , SIEGFRIED WOLFF , GORL UDO , UDO GORL , MEIER KARL , KARL MEIER
IPC: C01B33/12 , C08J3/22 , C08K3/00 , C08K3/18 , C08K3/22 , C08K3/34 , C08K3/36 , C08L21/00 , C09C1/04 , C09C1/28 , C09C1/30 , C09C , C08K , C08L
CPC classification number: C08K3/22 , C08J3/22 , C08J2321/00 , C08K3/36 , Y10S241/31 , C08L21/00
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公开(公告)号:FR2680795B1
公开(公告)日:2002-01-25
申请号:FR9208032
申请日:1992-06-30
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , GORL UDO
IPC: C08J3/24 , C08K5/00 , C08K5/36 , C08K5/39 , C08K5/40 , C08K5/548 , C08K5/58 , C08L21/00 , C08L23/16
Abstract: In a process for the production of vulcanizable moulding compounds consisting of one or more natural or synthetic rubbers or polymers the quantity of accelerators from the class of thiurams and/or dithiocarbamates is reduced to half the quantity originally required through the use of 3-thiocyanatopropyl trialkoxy silanes.
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公开(公告)号:SK67896A3
公开(公告)日:1996-12-04
申请号:SK67896
申请日:1996-05-27
Applicant: DEGUSSA
Inventor: DESCHLER ULRICH , GOBEL THOMAS , GORL UDO , LAMBERTZ HORST
Abstract: Mixts. of organosilane cpds. of formula (I) and (II) are claimed (M): Ä(RO)3Si(CH2)3SxÜ2 (I) and Ä(R'O)3Si(CH2)y-CH3 (II), where R, R' = 1-8C alkyl (same or different); x = 1-4; and y = 1-19; in amts. of 40-95 wt% (I) and 5-60 wt% (II). Also claimed are vulcanisable moulding materials and rubber mixts. contg. 10-250 pts. silicate filler and 0-150 pts. carbon black to 100 pts. rubber, plus 0.1-20 pts. mixt. (M) to 100 pts. silicate filler.
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公开(公告)号:MX173875B
公开(公告)日:1994-04-07
申请号:MX2448591
申请日:1991-02-11
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED , GORL UDO , DEUSSER HANS
Abstract: Surface modification of natural or synthetic oxidic or silicate fillers (I) comprises using one or more organosilicon cpds. of formula: (R'n(RO)3-nSi-(Alc)m-(Ar)p)q(B) (I). In (I), B = -SCN (when q = 1) or -Sx- (when q = 2); R and R' = 1-4C alkyl, phenyl in which every R and R' is identical or different, R = 1-4C-alkyl-1-4C-alkoxy gp.; n = 0, 1 or 2; alc = bivalent, linear or branched 1-6C hydrocarbon; m = 0 or 1; Ar = 6-12C arylene gp.; p = 0 or 1 (p+m does not equal 0); x = 2-8. The novelty is that: (a) at least one organosilicon cpd. is intensively mixed with the filler at temps. less than 60 deg.C in a concn. of up to 3.5 x 10 power (-6) mol. trialkoxysilyl gps. on a square meter of filler surface; (b) followed by hydrophobising the homogenised mixt. in a preheated mixer, tempered bed or another suitable heated reaction vessel at temps. larger than 60 deg.C.
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公开(公告)号:MY141462A
公开(公告)日:2010-04-30
申请号:MYPI9703220
申请日:1997-07-16
Applicant: DEGUSSA
Inventor: GORL UDO , LAMBERTZ HORST
Abstract: THIS INVENTION RELATES TO MIXTURES OF ORGANOSILANEPOLYSULPHANES OF THE GENERAL FORMULA (RO)3SI(CHZ)X S-SZ - S (CHZ)X SI(OR)3 (I) IN WHICH R MEANS ALKYL; LINEAR OR BRANCHED, HAVING 1-8 C ATOMS, IN PARTICULAR 1-3 C ATOMS X MEANS AN INTEGER FROM 1-8 Z MEANS 0 TO 6, WHEREIN SUM OF THE PROPORTIONS OF POLYSULPHANES IN WHICH Z = 0 AND Z = 1 AMOUNTS TO 80% (BY WEIGHT), PROVIDING THAT THE PROPORTION OF COMPOUNDS IN WHICH Z = 0 REMAINS BELOW 80% AND THE PROPORTION OF ORGANOSILANEPOLYSULPHANES IN WHICH Z MEANS AN INTEGER FROM 2 TO 6 DOES NOT EXCEED A PROPORTION OF 20 WT.% IN THE MIXTURES, AND TO THE RUBBER COMPOUNDS PRODUCED USING THESE MIXTURES, IN PARTICULAR FOR TYRE TREADS.
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公开(公告)号:CA2210780C
公开(公告)日:2005-01-25
申请号:CA2210780
申请日:1997-07-17
Applicant: DEGUSSA
Inventor: GORL UDO , LAMBERTZ HORST
IPC: C08L19/00 , B60C1/00 , C07F7/08 , C07F7/18 , C08G77/48 , C08K5/548 , C08L7/00 , C08L21/00 , C08L83/08 , C08C19/20 , C08C19/25 , C08K5/54
Abstract: This invention relates to mixtures of organosilanepolysulphanes of the general formula (RO)3Si(CH2)x S-S z - S (CH2)x Si(OR)3 (I) in which: R means alkyl, linear or branched, having 1-8 C atoms, in particular 1-3 C atoms; x is an integer from 1-8; z is 0 to 6; wherein the sum of the proportions of polysulphanes in which z = 0 and z = 1 amounts to .gtoreq. 80% (by weight), providing that the proportion of compounds in which z = 0 remains below 80%, and the proportion of organosilanepolysulphanes in which z is an integer from 2 to 6 does not exceed a proportion of 20 wt.% in the mixtures, and to rubber compounds produced using these mixtures, in particular for tyre treads. The invention also provides processes for the production of such rubber compounds.
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