ORGANOSILANE POLYSULFANE COMPOUNDS AND METHOD OF PRODUCING RUBBER MIXTURES CONTAINING SAID COMPOUNDS

    公开(公告)号:SK96797A3

    公开(公告)日:1998-02-04

    申请号:SK96797

    申请日:1997-07-16

    Applicant: DEGUSSA

    Abstract: A mixture (I) of organosilane polysulphides (II) of formula (RO)3Si(CH2)xS-Sz-S(CH2)xSi(OR)3 (1) is new. The mixture contains 20 wt.% or less (1) when z = 2-6 and less than 80 wt.% (1) when z = 0. In (1), R = 1-8C alkyl, preferably 1-3C alkyl; x = 1-8; and z = 0-6. Also claimed are (i) preparation of sulphur, sulphur donor and accelerator vulcanised rubber mixtures containing one or more natural or man-made rubber, silicate, fillers, optionally carbon black and other components, the rubber, fillers, carbon black, optionally plasticiser, anti-oxidants, activators and (I) being mixed at 160-200 degrees C for 3-15 minutes followed by the addition of vulcanisation agents at 60-120 degrees C and mixing for a further 2-10 minutes to yield sheet or strips; (ii) tyre tread compounds with a high silicic acid content containing 4-10 parts weight (pts. wt.) (I) to 100 pts. wt. filler.

    8.
    发明专利
    未知

    公开(公告)号:MX173875B

    公开(公告)日:1994-04-07

    申请号:MX2448591

    申请日:1991-02-11

    Applicant: DEGUSSA

    Abstract: Surface modification of natural or synthetic oxidic or silicate fillers (I) comprises using one or more organosilicon cpds. of formula: (R'n(RO)3-nSi-(Alc)m-(Ar)p)q(B) (I). In (I), B = -SCN (when q = 1) or -Sx- (when q = 2); R and R' = 1-4C alkyl, phenyl in which every R and R' is identical or different, R = 1-4C-alkyl-1-4C-alkoxy gp.; n = 0, 1 or 2; alc = bivalent, linear or branched 1-6C hydrocarbon; m = 0 or 1; Ar = 6-12C arylene gp.; p = 0 or 1 (p+m does not equal 0); x = 2-8. The novelty is that: (a) at least one organosilicon cpd. is intensively mixed with the filler at temps. less than 60 deg.C in a concn. of up to 3.5 x 10 power (-6) mol. trialkoxysilyl gps. on a square meter of filler surface; (b) followed by hydrophobising the homogenised mixt. in a preheated mixer, tempered bed or another suitable heated reaction vessel at temps. larger than 60 deg.C.

    MIXTURE OF ORGANOSILANEPOLYSULPHANES AND A PROCESS FOR THE PRODUCTION OF RUBBER COMPOUNDS CONTAINING THESE MIXTURES

    公开(公告)号:MY141462A

    公开(公告)日:2010-04-30

    申请号:MYPI9703220

    申请日:1997-07-16

    Applicant: DEGUSSA

    Abstract: THIS INVENTION RELATES TO MIXTURES OF ORGANOSILANEPOLYSULPHANES OF THE GENERAL FORMULA (RO)3SI(CHZ)X S-SZ - S (CHZ)X SI(OR)3 (I) IN WHICH R MEANS ALKYL; LINEAR OR BRANCHED, HAVING 1-8 C ATOMS, IN PARTICULAR 1-3 C ATOMS X MEANS AN INTEGER FROM 1-8 Z MEANS 0 TO 6, WHEREIN SUM OF THE PROPORTIONS OF POLYSULPHANES IN WHICH Z = 0 AND Z = 1 AMOUNTS TO  80% (BY WEIGHT), PROVIDING THAT THE PROPORTION OF COMPOUNDS IN WHICH Z = 0 REMAINS BELOW 80% AND THE PROPORTION OF ORGANOSILANEPOLYSULPHANES IN WHICH Z MEANS AN INTEGER FROM 2 TO 6 DOES NOT EXCEED A PROPORTION OF 20 WT.% IN THE MIXTURES, AND TO THE RUBBER COMPOUNDS PRODUCED USING THESE MIXTURES, IN PARTICULAR FOR TYRE TREADS.

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