Abstract:
PROBLEM TO BE SOLVED: To provide an actinic ray-curable powder coating composition having higher glass-transition temperature (T g ), and giving a film having hydrophobic surface properties without injuring its excellent mechanical properties. SOLUTION: The actinic ray-curable powder coating composition containing a compound having functionalized polyhedral oligomer silicon-oxygen cluster units is produced. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract translation:要解决的问题:提供具有较高玻璃化转变温度(T SB> g SB)的光化学射线固化粉末涂料组合物,并提供具有疏水性表面性质的膜而不损害其优异的机械性能 。 解决方案:制备含有具有官能化多面体低聚物硅 - 氧簇单元的化合物的光化射线固化粉末涂料组合物。 版权所有(C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a new NCO-containing compound having improved properties and covalently bonded polyhedral oligomer silicon-oxygen cluster units. SOLUTION: The NCO-containing compound having covalently bonded polyhedral oligomer silicon-oxygen cluster units is formed by reaction of a starting material (A) at least one aromatic, aliphatic and/or alicyclic polyisocyanate having NCO-functionality of 2-6, (B) 0.001-20.0 mass% polyhedral oligomer silicon-oxygen cluster units having at least one functional group reacting with isocyanate, in the case, 1-20 mol% of free isocyanate existing at the beginning and of polyisocyanate is converted, and (C), if necessary, a blocking agent, in the case, 80-99 mol% of free isocyanate existing at the beginning and of polyisocyanate is converted and the molar ratio of the converted isocianate is 100% in total. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a thermally curable powder coating composition giving a film having hydrophobic surface properties without injuring its excellent mechanical properties. SOLUTION: The thermally curable powder coating composition containing a compound having functionalized polyhedral oligomer silicon-oxygen cluster units is produced. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
The invention relates to a transparent masterbatch for improving the surface properties of thermoplastics, said masterbatch containing from 10% to 60% by weight of polyhedral oligomeric silicon-oxygen cluster units in accordance with the formula [(RaXb,SiO1.5)m (RCXdSIO)n (ReXfSi2O2.5)o(RgXhSi2O2)p] where: a, b, c = 0-1; d = 1-2; e, f, g = 0-3; h = 1-4; m+n+o+p >= 4; a+b = 1; c+d = 2; e+f = 3 and g+h = 4; R = hydrogen atom, alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, cycloalkynyl group or polymer unit, each substituted or unsubstituted, or further functionalized polyhedral oligomeric silicon-oxygen cluster units attached via a polymer unit or a bridging unit, X = oxy, hydroxy, alkoxy, carboxy, silyl, alkylsilyl, alkoxysilyl, siloxy, alkylsiloxy, alkoxysiloxy, silylalkyl, alkoxysilylalkyl, alkylsilylalkyl, halogen, epoxy, ester, fluoroalkyl, isocyanate, blocked isocyanate, acrylate, methacrylate, nitrile, amino, phosphine or polyether group or substituents of type R containing at least one such group of type X the substituents of type R being identical or different and the substituents of type X being identical or different and from 40% to 9011/o by weight of a thermoplastic carrier material, and to a transparent thermoplastic and to its production process.
Abstract translation:本发明涉及一种用于改善热塑性塑料表面性能的透明母料,所述母料含有按重量计10%至60%重量的多面体低聚硅 - 氧簇簇单元,按照式[(RaXb,SiO1.5)m(RCXdSIO )n(ReXfSi2O2.5)o(RgXhSi2O2)p]其中:a,b,c = 0-1; d = 1-2; e,f,g = 0-3; h = 1-4; m + n + o + p> = 4; a + b = 1; c + d = 2; e + f = 3,g + h = 4; R =氢原子,烷基,环烷基,烯基,环烯基,炔基,环炔基或聚合物单元,每个取代或未取代的或通过聚合物单元或桥接单元连接的其它官能化多面体低聚硅 - 氧簇簇,X =氧, 羟基,烷氧基,羧基,甲硅烷基,烷基甲硅烷氧基,烷氧基甲硅烷氧基,甲硅烷基烷基,烷氧基甲硅烷基烷基,烷基甲硅烷基烷基,卤素,环氧基,酯,氟代烷基,异氰酸酯,封端异氰酸酯,丙烯酸酯,甲基丙烯酸酯,腈,氨基,膦或聚醚基团或 R型的取代基包含至少一个这种X型基团,R型取代基相同或不同,并且X型取代基相同或不同,为热塑性载体材料的重量百分比为40%至9011 / 透明的热塑性塑料及其生产工艺。
Abstract:
A process for the oxidation of organic compounds using a liquid multi-phase catalyst system comprising at least one ruthenium-containing compound and an oxygen atom donor, is characterized in that the oxidation is carried out using an aqueous phase pH of at least 7.0.
Abstract:
Un proceso para producir películas dieléctricas de k baja, que comprende utilizar silsesquioxanos oligómeros poliédricos incompletamente condensados de estructura 1 o 2 con R = átomo de hidrógeno o grupo alquilo, cicloalquilo, alquenilo, cicloalquenilo, alquinilo, cicloalquinilo, arilo o heteroarilo, sustituido o insustituido en todos los casos, siendo los sustituyentes R idénticos o diferentes, como material de partida para producir la película.
Abstract:
Procedimiento para la producción de alcoholes, cetonas, aldehídos y ácidos carboxílicos saturados, utilizándose como compuesto de partida un hidrocarburo insaturado, que en primer lugar se oxida con un gas que contiene oxígeno utilizando un catalizador y en presencia de un iniciador de radicales, y utilizando como catalizador un compuesto de fórmula I con R1, R2 = H, resto alcoxilo alifático o aromático, resto carboxilo, resto alcoxicarbonilo o resto hidrocarburo, en cada caso con de 1 a 20 átomos de carbono, SO3H, NH2, OH, F, Cl, Br, I y/o NO2, pudiendo denominar R1 y R2 restos idénticos o diferentes o estar unidos R1 y R2 entre sí a través de un enlace covalente, Q1, Q2 = iguales o distintos, C, CH o N, X, Z = C, S, o CH2, Y = O u OH, k = 0, 1 ó 2, l = 0, 1 ó 2 y m = de 1 a 100, caracterizado porque se reducen los productos de oxidación mediante una hidrogenación posterior y se forman alcoholes, cetonas, aldehídos y/o ácidos carboxílicos saturados.
Abstract:
The invention relates to a separator filled with an electrolyte composition, the separator having a ceramic surface and the electrolyte composition comprising an ionic liquid. The filling with the electrolyte composition can be effected for example by utilizing the separator in a battery, for example a lithium-ion battery, which has been filled with an appropriate electrolyte composition.