2.
    发明专利
    未知

    公开(公告)号:DE59100102D1

    公开(公告)日:1993-06-09

    申请号:DE59100102

    申请日:1991-10-29

    Applicant: DEGUSSA

    Abstract: Novel gold(I) mercaptocarboxylic acid esters of the formula (I) in which X is a C1- to C3 alkylene group and Z is a group from the series tricyclo(5,2,1,02.6)decane-8- or -9-yl or tricyclo(5,2,1,02.6)decyl-3- or -4-methyl. These esters can be prepared from mercaptocarboxylic acid esters of the formula (II) and from a gold(I) chloride-dialkylsulfide complex. The novel esters can be used in gold preparations for gilding solid bases, especially ceramic materials. Compared to known gold(I) mercaptocarboxylic acid esters, the novel esters result in considerably shorter drying times for gold preparations.

    5.
    发明专利
    未知

    公开(公告)号:DE3872351D1

    公开(公告)日:1992-07-30

    申请号:DE3872351

    申请日:1988-10-05

    Applicant: DEGUSSA

    Abstract: Micro-wave-resistant designs on crockery parts comprise silicatic materials, burnished noble metal prepns. (I). (I) comprise an organo-gold cpd., opt. mixed with organosilver-, organopalladium- and/or organoplatinum cpds.; an organic support; and a flux of organic metal cpds. contg. an organic silicon cpd. (II) having three hydrolysable gps. on the Si-atom, in amts. of 0.1-2 mols. Si per mol. of noble metal. Pref. cpd. (II) is a cpd. of formula Y3SiX in which Y is alkoxy, aryloxy, aralkoxy, acyloxy, ketoximyl, mercaptan, halogen and/or pseudohalogen and X is alkyl, aryl, aralkyl, (cyclo)alkenyl, vinyl and/or heteroatom-substd. analogues.

    7.
    发明专利
    未知

    公开(公告)号:DK0491143T3

    公开(公告)日:1993-07-12

    申请号:DK91118368

    申请日:1991-10-29

    Applicant: DEGUSSA

    Abstract: Novel gold(I) mercaptocarboxylic acid esters of the formula (I) in which X is a C1- to C3 alkylene group and Z is a group from the series tricyclo(5,2,1,02.6)decane-8- or -9-yl or tricyclo(5,2,1,02.6)decyl-3- or -4-methyl. These esters can be prepared from mercaptocarboxylic acid esters of the formula (II) and from a gold(I) chloride-dialkylsulfide complex. The novel esters can be used in gold preparations for gilding solid bases, especially ceramic materials. Compared to known gold(I) mercaptocarboxylic acid esters, the novel esters result in considerably shorter drying times for gold preparations.

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