公开(公告)号：AU534924B2

公开(公告)日：1984-02-23

申请号：AU6144680

申请日：1980-08-14

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： KABISCH GERHARD ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUBE RUDOLF ,  WITTMANN HANS

IPC: C07C27/00 ,  C07C29/03 ,  C07C29/09 ,  C07C31/20 ,  C07C31/27 ,  C07C35/00 ,  C07C51/00 ,  C07C51/367 ,  C07C59/10 ,  C07C59/105 ,  C07C67/00

公开(公告)号：DE3002861A1

公开(公告)日：1981-09-03

申请号：DE3002861

申请日：1980-01-26

Applicant: HENKEL KGAA ,  DEGUSSA

Inventor： LINDEMANN MANFRED DIPL CHEM DR ,  WEISS HERBERT DIPL CHEM DR ,  SCHWEIZER DIETER DIPL CHEM DR ,  KAEBISCH GERHARD DR ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUEBE RUDOLF ,  WITTMANN HANS

IPC: C07D301/16 ,  C07D303/04

公开(公告)号：CA909753A

公开(公告)日：1972-09-12

申请号：CA909753D

Applicant: DEGUSSA

Inventor： KABISCH GERHARD ,  RAUPACH SIEGFRIED

公开(公告)号：CA1177095A

公开(公告)日：1984-10-30

申请号：CA360467

申请日：1980-09-18

Applicant: DEGUSSA ,  HENKEL KGAA

Inventor： KAEBISCH GERHARD ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUEBE RUDOLF ,  WITTMANN HANS

IPC: C07C27/00 ,  C07C29/03 ,  C07C29/09 ,  C07C31/20 ,  C07C31/27 ,  C07C35/00 ,  C07C51/00 ,  C07C51/367 ,  C07C59/10 ,  C07C59/105 ,  C07C67/00

Abstract: Olefinically unsaturated compounds containing 4 to 36 carbon atoms and having boiling points above 40.degree.C are converted into the corresponding vicinal diols by reaction with formic acid and hydrogen peroxide at elevated temperature while intimately mixing and by subsequent saponification of the diol formates initially formed. The formic acid is used in amounts of 2 to 6 moles per mole of double bond and hydrogen peroxide is used in a concentration of 35 to 98 percent by weight. The reaction is carried out a temperature between 40 to 80.degree.C. The desired diols can usually be obtained in reaction times of less than seven hours and in yields of approximately 90%.

公开(公告)号：DE3002811A1

公开(公告)日：1981-08-06

申请号：DE3002811

申请日：1980-01-26

Applicant: DEGUSSA

Inventor： KAEBISCH GERHARD DR ,  TRUEBE RUDOLF ,  WITTMANN HANS ,  RAUPACH SIEGFRIED ,  MALITIUS HORST

IPC: C07D301/16 ,  C07D303/04 ,  C07D303/06

公开(公告)号：DE2937810A1

公开(公告)日：1981-04-02

申请号：DE2937810

申请日：1979-09-19

Applicant: DEGUSSA

Inventor： KAEBISCH GERHARD DR ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUEBE RUDOLF ,  WITTMANN HANS

IPC: B01J31/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/03 ,  C07C35/00 ,  C07C35/06 ,  C07C35/08 ,  C07C35/14 ,  C07C35/20 ,  C07C35/22 ,  C07C67/00 ,  C07C35/21

公开(公告)号：AU1964870A

公开(公告)日：1972-03-09

申请号：AU1964870

申请日：1970-09-08

Applicant: DEGUSSA

Inventor： KAEBISCH GERHARD ,  RAUPACH SIEGFRIED

IPC: C01B15/023 ,  C01B

Abstract: Hydrogen peroxide is extracted from the working solution of the alkyl anthraquinone process by solvents which are lighter than water and which produce the dispersed phase in the extraction step. The extraction is carried out in unfilled towers which at the bottom are fitted with known elements for dispersing organic liquids, e.g. perforated plates.

公开(公告)号：DE3169220D1

公开(公告)日：1985-04-18

申请号：DE3169220

申请日：1981-01-19

Applicant: HENKEL KGAA ,  DEGUSSA

Inventor： LINDEMANN MANFRED DR ,  WEISS HERBERT DR ,  SCHWEIZER DIETER DR ,  KABISCH GERHARD DR ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUBE RUDOLF ,  WITTMANN HANS

IPC: C07D301/16 ,  C07D303/04

公开(公告)号：AT12110T

公开(公告)日：1985-03-15

申请号：AT81100353

申请日：1981-01-19

Applicant: HENKEL KGAA ,  DEGUSSA

Inventor： LINDEMANN MANFRED DR ,  WEISS HERBERT DR ,  SCHWEIZER DIETER DR ,  KAEBISCH GERHARD DR ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUEBE RUDOLF ,  WITTMANN HANS

IPC: C07D301/16 ,  C07D303/04

公开(公告)号：CA1134867A

公开(公告)日：1982-11-02

申请号：CA360464

申请日：1980-09-18

Applicant: DEGUSSA

Inventor： KAEBISCH GERHARD ,  MALITIUS HORST ,  RAUPACH SIEGFRIED ,  TRUEBE RUDOLF ,  WITTMANN HANS

IPC: C07C29/48 ,  C07C27/00 ,  C07C29/03 ,  C07C33/26 ,  C07C67/00

Abstract: Styrene, its derivatives substituted in the aromatic nucleus or at the vinyl group by a methyl group or its derivatives substituted at the vinyl group by a hydroxy-methyl group are reacted at a temperature between 40 and 80.degree.C with less than 2 moles of formic acid and less than 2 moles of hydrogen peroxide per mole of double bond to be hydroxylated. Formic acid is applied in a concentration between 20 and 100 percent by weight and hydrogen peroxide in a concentration of less than 50 percent by weight. The concentration of the hydrogen peroxide in the aqueous phase of the reaction mixture is kept below 15 percent by weight during the entire reaction. The corresponding diols and triols are formed directly from the olefins applied within reasonable reaction times in high yields.