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    METHOD FOR CATALYTICALLY HYDRATING ORGANIC COMPOUNDS AND SUPPORTED CATALYST USED IN SAID METHOD
    1.
    发明申请
    METHOD FOR CATALYTICALLY HYDRATING ORGANIC COMPOUNDS AND SUPPORTED CATALYST USED IN SAID METHOD 审中-公开
    PROCESS FOR有机化合物和载体催化剂THEREFOR催化加氢

    公开(公告)号：WO0236260A8

    公开(公告)日：2002-09-19

    申请号：PCT/EP0112043

    申请日：2001-10-12

    Applicant: DEGUSSA

    Inventor： HAAS THOMAS ,  JAEGER BERND ,  SAUER JOERG ,  VANHEERTUM RUDOLF

    IPC: B01J23/46 ,  B01J35/10 ,  C07B61/00 ,  C07C29/141 ,  C07C31/20 ,  C07C209/72 ,  C07C211/17 ,  C07C211/36

    CPC classification number: B01J23/462 ,  B01J35/1009 ,  C07C29/141 ,  C07C209/72 ,  C07C2601/14 ,  C07C211/17 ,  C07C31/10 ,  C07C31/205

    Abstract: The invention relates to a method for catalytically hydrating an organic compound, especially an unstable organic compound, in the presence of a supported catalyst that is provided with a coating that contains ruthenium as the active metal and a total of 0.01 to 30 % by weight of active metals. The aim of the invention is to increase stereoselectivity and catalyst service life. To this end, a supported catalyst is used whose oxide-, carbide-, nitride- or silicate-containing support material, prior to being charged with at least one active metal, has a BET(N2) surface of less than 10 m /g, preferably 0.1 to 5 m /g, with the exception of diatomaceous earth with a BET(N2) surface of greater 2 m /g, and whose ruthenium content constitutes at least 50 % by weight, preferably at least 99 % by weight, of the active metals. The invention further relates to the aforementioned supported catalysts. The method and catalysts according to the invention are especially suitable for hydrating polyfunctional compounds such as hydroxycarbonyl compounds and aromatic amines.

    Abstract translation: 本发明涉及一种用于有机化合物的催化氢化，特别是在含有钌作为活性金属和共活性金属涂层的0.01至30重量％的负载型催化剂的存在下不稳定有机化合物的方法。 根据本发明，可与至少一种活性金属装载之前，使用负载的催化剂，该氧化物carbidisches，氮化的或硅酸盐载体材料时，具有BET的小于10μm<2> /克（N 2）的表面区域中获得更高的立体选择性和更高的催化剂寿命 ，特别优选为0.1〜5μm的<2> / g和具有BET硅藻土（N2）表面积大于2m <2> /克被排除，并且其钌中的至少50重量％含量，优选至少99 ％的.-％的活性金属。 本发明还涉及上文所述的负载型催化剂。 具体地说，该方法和用于多官能化合物，如羟基羰基化合物和芳香胺的氢化的催化剂。

    2.
    发明专利
    未知

    公开(公告)号：BRPI0721191A2

    公开(公告)日：2014-03-18

    申请号：BRPI0721191

    申请日：2007-12-20

    Applicant: EVONIK DEGUSSA GMBH

    Inventor： BADE STEFAN ,  SCHLADERBECK NORBERT ,  SELIGER BEATE ,  SAUER JOERG

    IPC: C07F7/18 ,  C07F7/08

    Abstract: The present invention relates to a process for preparing glycidyloxy-alkylalkoxysilanes of the general formula (I) (R″)O—CnH2nSi(R′)m(OR)3-m(I) in which R and R′ groups are each independently linear or branched alkyl groups having from 1 to 4 carbon atoms, n is 1, 2, 3, 4, 5, 6, 7 or 8 and m is 0, 1, 2 or 3, and R″ is an H2C(O)CH— or H2C(O)CHCH2— group, by reacting (i) a functionalized alkene of the general formula (II) (R″)O—CnH2n-1(II) in which R″ is an H2C(O)CH— or H2C(O)CHCH2— group and n is 1, 2, 3, 4, 5, 6, 7 or 8 with (ii) at least one hydroalkoxy-silane of the general formula (III) HSi(R′)m(OR)3-m (III) in which R and R′ groups are each independently linear or branched alkyl groups having from 1 to 4 carbon atoms and m is 0, 1, 2 or 3, in the presence (iii) of at least one homogeneous catalyst, (iv) of at least one solvent and/or of a diluent and (v) of at least one promoter.

    Process for the epoxidation of olefins.
    5.
    发明专利
    Process for the epoxidation of olefins. 未知

    公开(公告)号：ZA200306925B

    公开(公告)日：2004-09-02

    申请号：ZA200306925

    申请日：2003-09-04

    Applicant: DEGUSSA ,  UHDE GMBH

    Inventor： HAAS THOMAS ,  SAUER JOERG ,  HOFEN WILLI ,  THIELE GEORG

    IPC: C07D301/12 ,  C07D303/04 ,  C07D

    Abstract: Catalytic epoxidation of olefins with hydrogen peroxide uses a continuous flow reaction system. The reaction mixture is passed through a fixed catalyst bed within a reactor equipped with cooling device, while maintaining a temperature profile within the reactor so that the cooling medium temperature of the cooling device is at least 40[deg]C and the maximum temperature within the catalyst bed is 60[deg]C.

    6.
    发明专利
    未知

    公开(公告)号：BR0015363A

    公开(公告)日：2002-06-18

    申请号：BR0015363

    申请日：2000-10-26

    Applicant: DEGUSSA

    Inventor： HAAS THOMAS ,  GLENNEBERG JUERGEN ,  WAGNER RUDOLF ,  CREUTZ MATTHIAS ,  SAUER JOERG ,  VANHEERTUM RUDOLF

    IPC: B01J8/02 ,  B01J10/00 ,  B01J23/44 ,  B01J35/02 ,  C01B15/023

    Abstract: In carrying out the hydrogenation stage of the anthraquinone process for the preparation of hydrogen peroxide in a hydrogenation reactor on a fixed bed catalyst of a particulate catalyst, the service life of the catalyst is increased in that the working solution comprising the reaction carrier and a gas phase comprising hydrogen, are passed through the hydrogenation reactor from the bottom upwards. The empty tube speed of the working solution is 0.05 to 100 m/h, preferably 10 to 50 m/h.

    10.
    发明专利
    未知

    公开(公告)号：DE60204761D1

    公开(公告)日：2005-07-28

    申请号：DE60204761

    申请日：2002-03-04

    Applicant: DEGUSSA ,  UHDE GMBH

    Inventor： HAAS THOMAS ,  HOFEN WILLI ,  SAUER JOERG ,  THIELE GEORG

    IPC: C07D301/12 ,  C07D303/04

    Abstract: A process for the catalytic epoxidation of olefins with hydrogen peroxide in a continuous flow reaction system, involves passing the reaction mixture through a fixed catalyst bed in down-flow operation mode and partially removing the heat during the course of the reaction.

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