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公开(公告)号:US3879457A
公开(公告)日:1975-04-22
申请号:US28454572
申请日:1972-08-29
Applicant: DEGUSSA
Inventor: HENSEL JORG , SCHAEFER GERD , SCHREYER GERD
IPC: C07C231/06 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/10 , C07C233/03 , C07C103/30
CPC classification number: C07C233/00
Abstract: N-alkyl formamides or the corresponding N-cycloalkyl or Naralkyl formamaides are prepared by reacting olefins, cycloolefins or aralkenes with hydrogen cyanide in the Ritter reaction using about 2.5 moles of acid per mole of olefin at a temperature of 30* to 70* C. and the unneutralized acid reaction mixture is extracted with acid stable polar solvents and the extract is worked up in conventional manner.
Abstract translation: N-烷基甲酰胺或相应的N-环烷基或N-芳烷基甲酰胺通过在Ritter反应中使烯烃,环烯烃或芳烯烃与氰化氢反应,使用约2.5摩尔酸/摩尔烯烃在30至70℃的温度下反应制备。 并用酸稳定的极性溶剂萃取未中和的酸反应混合物,并以常规方式处理提取物。