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公开(公告)号:BR8803516A
公开(公告)日:1989-02-08
申请号:BR8803516
申请日:1988-07-13
Applicant: DEGUSSA
Inventor: WITZEL MICHAEL , KLEINSCHMIT PETER , PFEIFER WOLF-DIETER , VOIGT CARL , ALBERS PETER
Abstract: A specific form of surface coating of Al2O3 catalysts, using additional amounts of aluminium ions and minimum amounts of platinum ions, made it possible to use Al2O3 as a catalyst for long-term operation (150 days and more) in the preparation of hydrogen cyanide from hydrocarbons and ammonia, preferably in the BMA process.
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公开(公告)号:CA1213123A
公开(公告)日:1986-10-28
申请号:CA449530
申请日:1984-03-14
Applicant: DEGUSSA
Inventor: MANNER REINHARD , SCHAEFER HANS , VOIGT CARL , PFEIFER WOLF D
Abstract: An increase in the throughput in the BMA-furnace or a BMA furnace chamber, respectively, without modification of the existing design and dimensions is achieved by converting the lower stage of the cooling head to a short-tube bundle-type heat exchanger whilst retaining the temperature profile needed for the process by the denser or less dense arrangement of the ceramic tubes in the furnace chamber and/or by using ceramic tubes having different inner and outer geometry and/or structure.
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公开(公告)号:IT1127975B
公开(公告)日:1986-05-28
申请号:IT6704780
申请日:1980-01-14
Applicant: DEGUSSA
Inventor: VOIGT CARL , KLEINSCHMIT PETER , WALTER EBERHARD
Abstract: The known hydrocyanic acid-methane-ammonia (BMA) process for the production of hydrogen cyanide can now be carried out with liquified gases namely through the presence of additional hydrogen at the beginning of the reaction. The atomic ratio of carbon to nitrogen and hydrogen is from 1:1:7.1 to 1:1.33:13. As additional hydrogen there is the portion of hydrogen present coming out of the reaction "hydrocarbon+NH3". Otherwise the reaction conditions are the same as in the known BMA process.
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公开(公告)号:CA1146719A
公开(公告)日:1983-05-24
申请号:CA359752
申请日:1980-09-03
Applicant: DEGUSSA
Inventor: BITTNER FRIEDRICH , VOIGT CARL , KLEINSCHMIT PETER
IPC: C01C3/02
Abstract: By introducing the reaction gas mixture of hydrocarbons and ammonia at increased speed through an inlet tube having one or several orifices into the reaction tube used in the BMA process the yield of HCN is increased substantially.
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公开(公告)号:CS211369B2
公开(公告)日:1982-02-26
申请号:CS218580
申请日:1980-03-08
Applicant: DEGUSSA
Inventor: VOIGT CARL , KLEINSCHMIT PETER , WALTER EBERHARD
IPC: C01C3/02
Abstract: The known hydrocyanic acid-methane-ammonia (BMA) process for the production of hydrogen cyanide can now be carried out with liquified gases namely through the presence of additional hydrogen at the beginning of the reaction. The atomic ratio of carbon to nitrogen and hydrogen is from 1:1:7.1 to 1:1.33:13. As additional hydrogen there is the portion of hydrogen present coming out of the reaction "hydrocarbon+NH3". Otherwise the reaction conditions are the same as in the known BMA process.
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公开(公告)号:DD149654A5
公开(公告)日:1981-07-22
申请号:DD21994780
申请日:1980-03-26
Applicant: DEGUSSA
Inventor: VOIGT CARL , KLEINSCHMIDT PETER , WALTER EBERHARD
IPC: C01C3/02
Abstract: The known hydrocyanic acid-methane-ammonia (BMA) process for the production of hydrogen cyanide can now be carried out with liquified gases namely through the presence of additional hydrogen at the beginning of the reaction. The atomic ratio of carbon to nitrogen and hydrogen is from 1:1:7.1 to 1:1.33:13. As additional hydrogen there is the portion of hydrogen present coming out of the reaction "hydrocarbon+NH3". Otherwise the reaction conditions are the same as in the known BMA process.
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公开(公告)号:IT1129890B
公开(公告)日:1986-06-11
申请号:IT6878780
申请日:1980-11-21
Applicant: DEGUSSA
Inventor: VOIGT CARL , STRACK HANS , KLEINSCHMIT PETER
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公开(公告)号:BR8401202A
公开(公告)日:1984-10-23
申请号:BR8401202
申请日:1984-03-15
Applicant: DEGUSSA
Inventor: MANNER REINHARD , SCHAEFER HANS , VOIGT CARL , PFEIFER WOLF DIETER
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公开(公告)号:ZA816404B
公开(公告)日:1982-09-29
申请号:ZA816404
申请日:1981-09-15
Applicant: DEGUSSA
Inventor: VOIGT CARL , KLEINSCHMIT PETER , MANNER REINHARD
Abstract: The previously carried out internal coating of contact tubes not only required very much manual labor and was very time consuming, but it was also unsatisfactory in regard to adhesion of the contact liquid to the surface and homogenity of the catalyst. By the simultaneous action of heat on the liquid interface in the tubes during the lowering of the liquid level as well as by a specially suited apparatus for this purpose which operates according to the principle of communicating tubes there is provided the possibility of a good adhesion to the surface as well as the formation of a homogeneous layer at very little operating expense.
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公开(公告)号:FR2470092A1
公开(公告)日:1981-05-29
申请号:FR8022858
申请日:1980-10-24
Applicant: DEGUSSA
Inventor: VOIGT CARL , STRACK HANS , KLEINSCHMIT PETER
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