公开(公告)号：US3873595A

公开(公告)日：1975-03-25

申请号：US37210473

申请日：1973-06-21

Applicant: DEGUSSA

Inventor： LUSSLING THEODOR ,  SCHAEFER HANS ,  WEIGERT WOLFGANG

IPC: B01J23/18 ,  B01J23/22 ,  C07C255/51 ,  C07C121/02 ,  C07C121/56

CPC classification number: C07C253/28 ,  B01J23/22 ,  C07C255/51 ,  C07C255/50

Abstract: A catalyst useful in preparing o-phthalodinitrile from o-xylene comprises antimony oxide and vanadium oxide and/or antimony vanadate. The antimony oxide is present as Beta -antimony tetroxide.

Abstract translation: 用于从邻二甲苯制备邻酞二腈的催化剂包括氧化锑和氧化钒和/或钒酸锑。 氧化锑以四氧化锑为主。

公开(公告)号：US3899495A

公开(公告)日：1975-08-12

申请号：US32583473

申请日：1973-01-22

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  SCHAEFER HANS ,  SCHULER WILHELM ALFONS

IPC: C07D213/61 ,  C07D31/26

CPC classification number: C07D213/61

Abstract: 2,6-DICHLOROPYRIDINE IS PREPARED FROM CHLORINE AND PYRIDINE AT ELEVATED TEMPERATURES IN THE PRESENCE OF STEAM.

Abstract translation: 2,6-二氯吡啶在蒸汽存在下在高温下由氯和吡啶制备。

公开(公告)号：US3893895A

公开(公告)日：1975-07-08

申请号：US38066473

申请日：1973-07-19

Applicant: DEGUSSA

Inventor： DEHNERT JURGEN ,  KLEEMANN AXEL ,  LUSSLING THEODOR ,  NOLL EWALD ,  SCHAEFER HANS ,  SCHREYER GERD

IPC: C07C51/00 ,  C07C51/44 ,  C07C51/487 ,  C07C57/07 ,  C07C67/00 ,  B01D3/34

CPC classification number: C07C51/44 ,  C07C51/487 ,  Y10S203/22 ,  C07C57/04

Abstract: 1,2-Unsaturated carboxylic acids having carbonyl compound impurities are separated by binding the carbonyl compounds with inorganic, aliphatic or aromatic amines and then distilling the acids.

Abstract translation: 具有羰基化合物杂质的1,2-不饱和羧酸通过将羰基化合物与无机，脂族或芳族胺结合，然后蒸馏出酸来分离。

公开(公告)号：US3926856A

公开(公告)日：1975-12-16

申请号：US37267473

申请日：1973-06-22

Applicant: DEGUSSA

Inventor： LUSSLING THEODOR ,  SCHAEFER HANS ,  WEIGERT WOLFGANG

IPC: B01J23/16 ,  B01J23/30 ,  B01J23/34 ,  B01J23/84 ,  B01J23/888 ,  B01J37/04 ,  C07D213/84

CPC classification number: C07D213/84 ,  B01J23/16 ,  B01J23/30 ,  B01J23/34 ,  B01J23/84 ,  B01J23/888 ,  B01J37/04 ,  C07C253/28 ,  C07C255/51 ,  C07C255/50

Abstract: A catalyst useful in preparing nitriles from alkyl substituted aromatic and heteroaromatic hydrocarbons comprises a mixture of antimony oxide and tungsten oxide which have been pretreated by heating from 650* to 1100* C. Compounds of manganese, chromium, iron, cobalt, nickel, copper or, preferably, vanadium can also be present.

公开(公告)号：US3923819A

公开(公告)日：1975-12-02

申请号：US37267373

申请日：1973-06-22

Applicant: DEGUSSA

Inventor： LUSSLING THEODOR ,  SCHAEFER HANS ,  WEIGERT WOLFGANG

IPC: B01J23/16 ,  B01J23/30 ,  B01J23/34 ,  B01J23/888 ,  B01J37/04 ,  C07D209/48 ,  C07D213/84 ,  C07D213/85 ,  C07D213/57

CPC classification number: C07D213/84 ,  B01J23/16 ,  B01J23/30 ,  B01J23/34 ,  B01J23/888 ,  B01J37/04 ,  C07C253/28 ,  C07C255/51 ,  C07C255/50 ,  C07C255/52

Abstract: A catalyst useful in preparing nitriles from alkyl substituted aromatic and heteroaromatic hydrocarbons comprises a mixture of antimony oxide and tungsten oxide which have been pretreated by heating from 650* to 1100* C. Compounds of manganese, chromium, iron, cobalt, nickel, copper or, preferably, vanadium can also be present.

Abstract translation: 用于从烷基取代的芳族和杂芳族烃制备腈的催化剂包括通过加热至650℃至1100℃预处理的氧化锑和氧化钨的混合物。锰，铬，铁，钴，镍，铜或 ，优选地也可以存在钒。

公开(公告)号：US3898177A

公开(公告)日：1975-08-05

申请号：US29613572

申请日：1972-10-10

Applicant: DEGUSSA

Inventor： BESCHKE HELMUT ,  SCHAEFER HANS ,  SCHREYER GERD ,  SCHULER WILHELM ALFONS ,  WEIGERT WOLFGANG

IPC: B01J21/02 ,  B01J21/04 ,  B01J21/06 ,  B01J21/12 ,  B01J21/14 ,  B01J27/125 ,  B01J27/135 ,  B01J27/138 ,  C07D213/12 ,  B01J27/12

CPC classification number: B01J21/066 ,  B01J21/02 ,  B01J21/04 ,  B01J21/12 ,  B01J21/14 ,  C07D213/12

Abstract: Catalysts for the reaction of acrolein with ammonia to form pyridine and 3-methylpyridine are prepared by treating a compound of the elements Al, F and O and at least one element of the second, third or fourth group of the periodic system with oxygen at 550* to 1,200*C.

Abstract translation: 丙烯醛与氨反应形成吡啶和3-甲基吡啶的催化剂是通过将元素Al，F和O的化合物和周期系统的第二，第三或第四组的至少一种元素与氧在550 DEG至1200℃

公开(公告)号：US3926744A

公开(公告)日：1975-12-16

申请号：US42830473

申请日：1973-12-26

Applicant: DEGUSSA

Inventor： NOLL EWALD ,  SCHAEFER HANS ,  SCHMID HORST ,  WEIGERT WOLFGANG

IPC: B01D53/72 ,  B01D53/77 ,  C07C27/00 ,  C07C27/14 ,  C07C27/26 ,  C07C45/00 ,  C07C45/78 ,  C07C47/22 ,  C07C51/00 ,  C07C51/25 ,  C07C51/42 ,  C07C51/48 ,  C07C57/07 ,  C07C67/00 ,  B01D3/34 ,  B01D3/00

CPC classification number: C07C51/252 ,  C07C45/783 ,  C07C51/43 ,  C07C51/48 ,  Y10S203/22 ,  C07C47/22 ,  C07C57/04

Abstract: There is provided a process for the recovery of acrylic acid and acrolein from the gas mixture resulting from the catalytic gas phase oxidation of propylene or acrolein by washing the gas mixture with liquids in which at first the acrylic acid is dissolved at higher temperature and then the acrolein is dissolved at lower temperature. The improvement comprises washing the gas mixture for the separation of the acrylic acid at temperatures from about 60* to 120* C. with a washing liquid which is a mixture of water and organic liquid and then washing the gas mixture with a washing liquid which is water or a mixture of water and organic liquid at temperatures between 0* and 30* C. The organic liquid used has a higher boiling point than acrylic acid, does form an azeotrope with water alone, but does not form an azeotrope with acrolein or a mixture of water and acrolein, has slight miscibility with water and forms a solution with acrylic acid in which the acrylic acid has an activity coefficient of less than about 1.5.

公开(公告)号：US3867438A

公开(公告)日：1975-02-18

申请号：US38323273

申请日：1973-07-27

Applicant: DEGUSSA

Inventor： HENSEL JORG ,  LUSSLING THEODOR ,  NOLL EWALD ,  SCHAEFER HANS ,  WEIGERT WOLFGANG

IPC: B01J23/30 ,  B01J23/68 ,  B01J23/88 ,  B01J23/888 ,  B01J37/02 ,  C07C51/25 ,  C07C57/055 ,  C07C57/04 ,  C07C51/26

CPC classification number: B01J23/8885 ,  B01J23/30 ,  B01J23/687 ,  B01J37/0236 ,  C07C51/252 ,  C07C57/04

Abstract: Catalyst for the oxidation of an Alpha , Beta -unsaturated aldehyde to an Alpha , Beta -unsaturated carboxylic acid, said catalyst comprising (A) a mixture of oxides of the elements antimony, molybdenum, vanadium and tungsten and/or compounds of said elements and oxygen, and (B) at least one oxide or oxygen containing compound of the elements lead, silver, copper, tin, titanium or bismuth, said catalyst having an atomic ratio of antimony to molybdenum to vanadium to tungsten to Group (B) elements of about 1 - 60 : 12 : 0.5 - 25 : 0.1 - 12 : 0.1 - 12. Processes for the use and preparation of the catalysts are provided.

Abstract translation: 用于将α，β-不饱和醛氧化成α，β-不饱和羧酸的催化剂，所述催化剂包含（A）元素锑，钼，钒和钨的氧化物和/或所述元素的化合物的混合物，和 氧，和（B）元素铅，银，铜，锡，钛或铋的至少一种氧化物或氧化物，所述催化剂具有锑与钼与钒的原子比与钒与钨的原子比与钨（B）元素的 约1：60：12：0.5 - 25：0.1 - 12：0.1 - 12。提供了使用和制备催化剂的方法。

公开(公告)号：US3867345A

公开(公告)日：1975-02-18

申请号：US29262872

申请日：1972-09-27

Applicant: DEGUSSA

Inventor： KOBERSTEIN EDGAR ,  LUESSLING THEODOR ,  NOLL EWALD ,  SCHAEFER HANS ,  WEIGERT WOLFGANG

IPC: B01J23/28 ,  B01J23/30 ,  C07C51/25 ,  C07C57/055 ,  C07C51/26 ,  C07C57/04

CPC classification number: B01J23/30 ,  B01J23/28 ,  C07C51/252 ,  C07C57/04

Abstract: Alpha , Beta -unsaturated aldehydes are oxidized to Alpha , Beta -unsaturated carboxylic acids by contacting the Alpha , Beta -unsaturated aldehyde with air or oxygen and steam at 200*350*C and at atmospheric or elevated pressure in the presence of a catalyst so as to convert the aldehyde to the corresponding carboxylic acid. The catalyst comprises a mixture of oxides of the elements antimony, molybdenum, vanadium and tungsten and/or compounds of said elements and oxygen wherein the atomic ratio of the elements is as follows: 1 to 60 : 12 : 0.5 to 25 : 0.1 to 12. The catalyst is made by intimately mixing under agitation aqueous solutions or suspensions of the oxides or other compounds, for instance antimony oxide, ammonium molybdate, ammonium vanadate and ammonium tungstate, and possibly a carrier material and preferably bringing the mixture to boiling point, then separating the catalyst mass from the aqueous phase, drying it and calcining it at 225*-275*C, followed by heating in air for 15-60 minutes at 350*-475*C.

Abstract translation: α，β-不饱和醛被氧化成α，β-不饱和羧酸，通过使α，β-不饱和醛与空气或氧气和蒸汽在200-350℃和大气压或高压下在催化剂存在下接触 以将醛转化成相应的羧酸。 催化剂包括元素锑，钼，钒和钨的氧化物和/或所述元素和氧的化合物的混合物，其中元素的原子比如下：1至60：12：0.5至25：0.1至12 。

公开(公告)号：LT2110B

公开(公告)日：1993-07-15

申请号：LTRP522

申请日：1993-05-06

Applicant: DEGUSSA

Inventor： MANNER REINHARD ,  SCHAEFER HANS ,  VOIGT CARL ,  PFEIFER WOLF DIETER

IPC: B01J19/24