公开(公告)号：BG25805A3

公开(公告)日：1978-12-12

申请号：BG2488773

申请日：1973-10-30

Applicant: DEGUSSA

Inventor： THURN ,  BURMESTER ,  POCHERT ,  WOLFF

IPC: C08L7/00 ,  C07F7/02 ,  C08K3/00 ,  C08K3/36 ,  C08K5/00 ,  C08K5/548 ,  C08L1/00 ,  C08L19/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C09C1/30 ,  C08L9/02

公开(公告)号：FI47580C

公开(公告)日：1974-01-10

申请号：FI305365

申请日：1965-12-21

Applicant: DEGUSSA

Inventor： WESTLINNING ,  WOLFF ,  SCHWARZE

IPC: C08K5/378 ,  C08K5/43 ,  C08K5/46 ,  C08L21/00 ,  C08C11/54 ,  C08D13/28

公开(公告)号：DD153885A5

公开(公告)日：1982-02-10

申请号：DD22382479

申请日：1979-12-07

Applicant: DEGUSSA

Inventor： SCHWARZ ,  KLEINSCHMIT ,  LIEDTKE ,  WOLFF

IPC: C08L7/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C08G75/02 ,  C08G75/14 ,  C08K5/5425 ,  C08K5/548 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08K5/54 ,  C08L9/06

Abstract: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH2=CH)m-SiRn1R4-(m+n) in which R represents chlorine, bromine, iodine, C1-C3-alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R1 represents C1-C3-alkyl, phenyl or C5-C7-cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100 DEG and 200 DEG C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

公开(公告)号：FI47581C

公开(公告)日：1974-01-10

申请号：FI69768

申请日：1968-03-14

Applicant: DEGUSSA

Inventor： WESTLINNING ,  WOLFF ,  SCHWARZE

IPC: C08K5/36 ,  C08K5/378 ,  C08C11/54

公开(公告)号：BG25235A3

公开(公告)日：1978-08-10

申请号：BG2863574

申请日：1974-12-31

Applicant: DEGUSSA

Inventor： POCHERT ,  WOLFF ,  THURN

IPC: C08L7/00 ,  B29C35/00 ,  B29C55/00 ,  B29C65/00 ,  B29C65/70 ,  C08J5/10 ,  C08K3/00 ,  C08K5/00 ,  C08K5/548 ,  C08K7/00 ,  C08L21/00 ,  C08L61/10 ,  C08L67/00 ,  C08L77/00 ,  C08L9/06

Abstract: Silica containing mixtures for the improvement of the adhesion of vulcanizable mixtures of natural and/or synthetic rubber to reinforcing fillers or supports of textile and/or metallic fabrics after the vulcanization are prepared that substantially consist of (A) active synthetically produced silica or silicates having a specific surface area according to the BET procedure of about 50 to 500 m2/g and an average primary particle size of from about 5 to 100 and at least one of (B) phenolic resin or aminoplast forming components, namely on the one hand phenols and/or amines and on the other hand aldehydes or aldehyde donors, and/or at least (C) one organosilane which can be a bisalkoxysilylalkyl-oligosulfide of the formula I. Z-Alk-Sn-Alk-Z, in which Z stands for the group R1 R1 R2 ¦ ¦ ¦ (a)-Si-R1, (b)-Si-R2 or (c)-Si-R2 ¦ ¦ ¦ R