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公开(公告)号:DE68924302D1
公开(公告)日:1995-10-26
申请号:DE68924302
申请日:1989-05-23
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
IPC: C07F7/02 , C03C17/30 , C03C25/40 , C08J5/12 , C08K5/54 , C08K5/5419 , C09C3/10 , C09C3/12 , C09D5/00 , C09D125/00 , C09D125/10 , C09D133/02
Abstract: A novel ionomeric silane coupling agent is disclosed and its use in bonding a matrix polymer to a mineral substrate is described. The coupling agent is prepared by partially neutralizing the combined acid functionality present in a mixture of an acid-functional silane (or metal salt thereof) and an acid-functional film former with a metal ion. The coupling agent greatly improves bond strength in moist environments and is particularly suitable for use in formulating filled injection molding compositions.
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公开(公告)号:DE68921781T2
公开(公告)日:1995-08-24
申请号:DE68921781
申请日:1989-04-17
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL , REVIS ANTHONY
Abstract: Organosilicon quaternary ammonium antimicrobial compounds are described, particularly, ammonium chloride derivatives of multifunctional diamino quaternary salts and salts containing a combination of amino, ester and fluoroalkyl functionality.
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公开(公告)号:DE68921781D1
公开(公告)日:1995-04-27
申请号:DE68921781
申请日:1989-04-17
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL , REVIS ANTHONY
Abstract: Organosilicon quaternary ammonium antimicrobial compounds are described, particularly, ammonium chloride derivatives of multifunctional diamino quaternary salts and salts containing a combination of amino, ester and fluoroalkyl functionality.
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公开(公告)号:DE69010098T2
公开(公告)日:1994-11-17
申请号:DE69010098
申请日:1990-07-18
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
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公开(公告)号:AU602614B2
公开(公告)日:1990-10-18
申请号:AU2503388
申请日:1988-11-11
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL , BANK HOWARD MARVIN
IPC: C08L83/07 , C07F7/18 , C08F2/38 , C08F2/40 , C08F30/08 , C08K5/17 , C08L83/04 , C08K5/32 , C08K5/34
Abstract: A method for stabilizing an unsaturated organosilicone is disclosed wherein a stabilizing amount of a hydroxylamine compound is added to the organosilicone to prevent thermal polymerization of the latter. The organosilicone may be an alkoxysilane or an organopolysiloxane having in its molecule a reactive organic group-bearing at least one radical selected from acryloxy, methacryloxy, acrylamide, methacrylamide, styryl or vinylbenzyl radicals. The hydroxylamine compound may be added either to the organosilicone or during the preparation of the alkoxysilane from its respective reactants.
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公开(公告)号:DE3004337A1
公开(公告)日:1980-08-14
申请号:DE3004337
申请日:1980-02-06
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
IPC: B29C45/00 , B05D7/24 , B29B15/00 , B29C55/00 , B29C65/00 , B29C65/48 , C08J5/12 , C09D5/00 , C09D161/32 , C09J5/00 , C09J5/02 , C09D3/82
Abstract: A primer composition consisting essentially of 75 to 99 percent alkoxymethyltriazine and 1 to 25 percent 3-glycidoxypropyltrimethoxysilane, 2-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 2-mercaptoethyltrimethoxysilane or a partial hydrolyzate of the silanes is employed to improve wet and dry adhesion of thermoplastics to solid substrates.
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公开(公告)号:CH609351A5
公开(公告)日:1979-02-28
申请号:CH1588574
申请日:1974-11-29
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
IPC: C08K5/00 , C07F7/18 , C08G77/26 , C08K5/54 , C08K5/544 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L67/00 , C09J11/00 , C07F7/10
Abstract: Anionic silanes of the formula HOOCR'' O=C ¦ (RO)3SiR'(NCH2CH2)nNHCH2CH=CH2 are made by reacting silanes of the formula (RO)3SiR'(NHCH2CH2)nNHCH2 CH=CH2 with 1 or 2 moles of an anhydride of a 1,2-dicarboxylic acid. A typical compound is (MeO)3Si(CH2)3NCH2CH2NHCH2CH=CH2. ¦ C=O ¦ CH=CHCOOH these compounds are used as coupling agents between inorganic substrates and organic resins such as epoxides, phenolic and polyester.
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公开(公告)号:DE2424692A1
公开(公告)日:1974-12-05
申请号:DE2424692
申请日:1974-05-21
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
IPC: C08K5/00 , C08J3/02 , C08K5/45 , C08K5/54 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L57/00 , C08L67/00 , C08L101/00 , C09D5/00 , C09D5/02 , C09J201/00 , C08F45/46 , C08F45/50 , C09D3/74
Abstract: Small amounts of organosilanes having epoxy, amine, imino, carboxyl, or mercapto functionality are added to soluble poly(hydroxyarylpolymethylenesulfonium) zwitterionic monomer to give a material which can be added to flexible polymer latexes to increase adhesion of films deposited from such latexes.
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公开(公告)号:GB1279213A
公开(公告)日:1972-06-28
申请号:GB6200370
申请日:1970-12-31
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
Abstract: 1279213 Silylation of hydroxyl compounds DOW CORNING CORP 31 Dec 1970 [9 April 1970] 62003/70 Heading C3S Organic compounds containing hydroxyl groups are silylated at the hydroxyl groups by reaction with silanes of the formula R n SiX 4-n in the presence of formamide, wherein R denotes a C 1-18 monovalent hydrocarbon or halogenated hydrocarbon radical, or a C 1-18 alkoxy radical, X denotes chlorine or C 1-2 acyloxy and n is 1, 2 or 3. The reactive hydroxy group may be provided an alcohol, phenol, silanol, carboxylic acid, hydroxylamine, oxime or hydroperoxide. Examples describe the preparation of 2-(trimethylsiloxy)ethyl methacrylate, tris-trimethylsiloxy propane, hexakis-trimethylsilylated sucrose, 3-chloropropyltriethoxysilane, dimethyldi - n - butoxysilane, trimethylsilyl methacrylate, 4 - (methylthio)phenoxytrimethylsilane, trimethylsilyl - tert. - butyl peroxide, 2 - (trimethylsiloxy)ethyl methacrylate and 1,1 - diphenyl - 1,3,3,3 - tretamethyl - disiloxane.
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公开(公告)号:AU2256170A
公开(公告)日:1972-05-25
申请号:AU2256170
申请日:1970-11-23
Applicant: DOW CORNING
Inventor: PLUEDDEMANN EDWIN PAUL
Abstract: 1279213 Silylation of hydroxyl compounds DOW CORNING CORP 31 Dec 1970 [9 April 1970] 62003/70 Heading C3S Organic compounds containing hydroxyl groups are silylated at the hydroxyl groups by reaction with silanes of the formula R n SiX 4-n in the presence of formamide, wherein R denotes a C 1-18 monovalent hydrocarbon or halogenated hydrocarbon radical, or a C 1-18 alkoxy radical, X denotes chlorine or C 1-2 acyloxy and n is 1, 2 or 3. The reactive hydroxy group may be provided an alcohol, phenol, silanol, carboxylic acid, hydroxylamine, oxime or hydroperoxide. Examples describe the preparation of 2-(trimethylsiloxy)ethyl methacrylate, tris-trimethylsiloxy propane, hexakis-trimethylsilylated sucrose, 3-chloropropyltriethoxysilane, dimethyldi - n - butoxysilane, trimethylsilyl methacrylate, 4 - (methylthio)phenoxytrimethylsilane, trimethylsilyl - tert. - butyl peroxide, 2 - (trimethylsiloxy)ethyl methacrylate and 1,1 - diphenyl - 1,3,3,3 - tretamethyl - disiloxane.
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