公开(公告)号：WO2008134131A1

公开(公告)日：2008-11-06

申请号：PCT/US2008/056820

申请日：2008-03-13

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  BOUQUET, Gilbert, C.E. ,  CHAMBARD, Gregory ,  DION, Robert, P. ,  LAKEMAN, Pascal, E.R.E.J. ,  MAES, Dominique

Inventor： BOUQUET, Gilbert, C.E. ,  CHAMBARD, Gregory ,  DION, Robert, P. ,  LAKEMAN, Pascal, E.R.E.J. ,  MAES, Dominique

IPC: C08F2/00 ,  C08F2/38

CPC classification number: C08F2/001 ,  C08F2/38 ,  C08F4/00

Abstract: The present invention is a multistage process for the preparation of a co)polymer composition. Said process comprises the steps of: i) polymerizing in a first stage a reaction mixture comprising one or more monomer with optionally a rubber, a comonomer, a polymerization initiator, a chain transfer agent, a decomposition catalyst and/or a solvent, in the presence of one or more stable free radical precursor which provides a stable free radical during the polymerization process and/or one or more stable free radical such that the polymerization proceeds via a mediated free radical polymerization mechanism until a partial conversion of monomer(s) to (co)polymer is obtained and ii) polymerizing in a second stage the partially converted reaction mixture under reaction conditions that proceed via a free radical polymerization mechanism to obtain a further degree of conversion of monomer(s) to (co)polymer.

Abstract translation: 本发明是制备共聚物组合物的多阶段方法。 所述方法包括以下步骤：i）在第一阶段中将包含一种或多种单体与任选的橡胶，共聚单体，聚合引发剂，链转移剂，分解催化剂和/或溶剂的反应混合物聚合在 存在一种或多种稳定的自由基前体，其在聚合过程中提供稳定的自由基和/或一种或多种稳定的自由基，使得聚合通过介导的自由基聚合机理进行直到单体的部分转化为 （共）聚合物，和ii）在第二阶段聚合部分转化的反应混合物在经由自由基聚合机理进行的反应条件下进一步获得单体向（共）聚合物的转化程度。

公开(公告)号：WO2008036530A2

公开(公告)日：2008-03-27

申请号：PCT/US2007/078149

申请日：2007-09-11

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  MONTOYA-GONI, Amaia ,  LYSENKO, Zenon ,  SCHRADER, David ,  CHAMBARD, Gregory ,  SCHROCK, Alan, K.

Inventor： MONTOYA-GONI, Amaia ,  LYSENKO, Zenon ,  SCHRADER, David ,  CHAMBARD, Gregory ,  SCHROCK, Alan, K.

IPC: C08L25/00 ,  C08L9/00 ,  C08L51/04 ,  C08L55/02 ,  C08K5/00 ,  C08K5/103

CPC classification number: C08L53/02 ,  C08K5/103 ,  C08L51/04 ,  C08L55/02 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

Abstract: Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.

Abstract translation: 单亚乙烯基芳族聚合物，例如通用聚苯乙烯或高抗冲聚苯乙烯，用非官能化的非矿物油（例如植物油如卡诺拉油，棉籽油等）增塑。 单亚乙烯基芳族聚合物和油的混合物通常且优选不含任何显着量的官能化非矿物油，并且其通常包含至少0.1重量％的非官能化非矿物油，单独或与矿物油组合，基于 聚合物的重量。 非矿物油的碘值小于120，羟基数小于20。

公开(公告)号：EP2142575A1

公开(公告)日：2010-01-13

申请号：EP08732111.3

申请日：2008-03-13

Applicant: DOW GLOBAL TECHNOLOGIES INC.

Inventor： BOUQUET, Gilbert, C.E. ,  CHAMBARD, Gregory ,  DION, Robert, P. ,  LAKEMAN, Pascal, E.R.E.J. ,  MAES, Dominique

IPC: C08F2/00 ,  C08F2/38

CPC classification number: C08F2/001 ,  C08F2/38 ,  C08F4/00

Abstract: The present invention is a multistage process for the preparation of a co)polymer composition. Said process comprises the steps of: i) polymerizing in a first stage a reaction mixture comprising one or more monomer with optionally a rubber, a comonomer, a polymerization initiator, a chain transfer agent, a decomposition catalyst and/or a solvent, in the presence of one or more stable free radical precursor which provides a stable free radical during the polymerization process and/or one or more stable free radical such that the polymerization proceeds via a mediated free radical polymerization mechanism until a partial conversion of monomer(s) to (co)polymer is obtained and ii) polymerizing in a second stage the partially converted reaction mixture under reaction conditions that proceed via a free radical polymerization mechanism to obtain a further degree of conversion of monomer(s) to (co)polymer.

公开(公告)号：EP2066746A2

公开(公告)日：2009-06-10

申请号：EP07814801.2

申请日：2007-09-11

Applicant: DOW GLOBAL TECHNOLOGIES INC.

Inventor： MONTOYA-GONI, Amaia ,  LYSENKO, Zenon ,  SCHRADER, David ,  CHAMBARD, Gregory ,  SCHROCK, Alan K.

IPC: C08L25/00 ,  C08L9/00 ,  C08L51/04 ,  C08L55/02 ,  C08K5/00 ,  C08K5/103

CPC classification number: C08L53/02 ,  C08K5/103 ,  C08L51/04 ,  C08L55/02 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

Abstract: Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.