公开(公告)号：WO2008036530A2

公开(公告)日：2008-03-27

申请号：PCT/US2007/078149

申请日：2007-09-11

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  MONTOYA-GONI, Amaia ,  LYSENKO, Zenon ,  SCHRADER, David ,  CHAMBARD, Gregory ,  SCHROCK, Alan, K.

Inventor： MONTOYA-GONI, Amaia ,  LYSENKO, Zenon ,  SCHRADER, David ,  CHAMBARD, Gregory ,  SCHROCK, Alan, K.

IPC: C08L25/00 ,  C08L9/00 ,  C08L51/04 ,  C08L55/02 ,  C08K5/00 ,  C08K5/103

CPC classification number: C08L53/02 ,  C08K5/103 ,  C08L51/04 ,  C08L55/02 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

Abstract: Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.

Abstract translation: 单亚乙烯基芳族聚合物，例如通用聚苯乙烯或高抗冲聚苯乙烯，用非官能化的非矿物油（例如植物油如卡诺拉油，棉籽油等）增塑。 单亚乙烯基芳族聚合物和油的混合物通常且优选不含任何显着量的官能化非矿物油，并且其通常包含至少0.1重量％的非官能化非矿物油，单独或与矿物油组合，基于 聚合物的重量。 非矿物油的碘值小于120，羟基数小于20。

公开(公告)号：WO2004048469A1

公开(公告)日：2004-06-10

申请号：PCT/US2002/038066

申请日：2002-11-26

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  SODERQUIST, Mark, E. ,  ELLEY-BRISTOW, Dale, M. ,  WAGNER, Phillip, A. ,  SCHRADER, David

Inventor： SODERQUIST, Mark, E. ,  ELLEY-BRISTOW, Dale, M. ,  WAGNER, Phillip, A. ,  SCHRADER, David

IPC: C08L51/04

CPC classification number: C08F279/02 ,  C08L23/20 ,  C08L51/04 ,  C08F212/08 ,  C08L2666/04

Abstract: The present invention is a use of polybutene for reducing the amount of dust generated in the trimming step of a thermoforming process of high impact monovinylidene aromatic polymer resins.

Abstract translation: 本发明是使用聚丁烯来减少高冲击性单亚乙烯基芳香族聚合物树脂的热成型工序的修整工序中产生的粉尘的量。

公开(公告)号：EP2066746A2

公开(公告)日：2009-06-10

申请号：EP07814801.2

申请日：2007-09-11

Applicant: DOW GLOBAL TECHNOLOGIES INC.

Inventor： MONTOYA-GONI, Amaia ,  LYSENKO, Zenon ,  SCHRADER, David ,  CHAMBARD, Gregory ,  SCHROCK, Alan K.

IPC: C08L25/00 ,  C08L9/00 ,  C08L51/04 ,  C08L55/02 ,  C08K5/00 ,  C08K5/103

CPC classification number: C08L53/02 ,  C08K5/103 ,  C08L51/04 ,  C08L55/02 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

Abstract: Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.

公开(公告)号：EP1159322B1

公开(公告)日：2009-04-29

申请号：EP99961809.3

申请日：1999-11-24

Applicant: DOW GLOBAL TECHNOLOGIES INC.

Inventor： SCHRADER, David ,  BLACK, Steven, M.

IPC: C08F279/02 ,  C08L25/02 ,  C08L51/04 ,  C08L9/00

CPC classification number: C08L25/06 ,  C08F257/02 ,  C08F279/02 ,  C08L9/00 ,  C08L51/003 ,  C08L51/04 ,  C08L2666/04 ,  C08L2666/02

Abstract: The present invention refers to a rubber modified monovinylidene aromatic polymer composition wherein the rubber is in the form of discrete, dispersed rubber particles and comprises: a) from 75 to 25 weight percent based on the total weight of rubber, of a star branched diene rubber, having a cis 1,4 structure content of less than 75 percent; and b) from 25 to 75 weight percent, based on the total weight of rubber, of a linear diene rubber, having a cis 1,4 structure content of less than 50 percent.

公开(公告)号：EP1299439A1

公开(公告)日：2003-04-09

申请号：EP01933242.8

申请日：2001-05-09

Applicant: Dow Global Technologies Inc.

Inventor： DEMIRORS, Mehmet ,  MAUGHON, Dianne, J., M. ,  REGO, Jose M. ,  SCHRADER, David

IPC: C08F279/02

CPC classification number: C08F279/02 ,  C08F257/02 ,  C08L51/003 ,  C08L51/04 ,  C08F212/08 ,  C08L2666/02

Abstract: Disclosed are rubber-modified monovinylidene aromatic polymers with improved toughness and rigidity as well as a process for the process thereof. The polymer comprises: a) a monovinylidene aromatic polymer matrix, b) rubber particles dispersed therein, characterized in that the rubber particles are produced from a dine rubber having I) from 20 to 80 percent, based on the total weight of said rubber particles, of a high solution viscosity component having a viscosity value ranging from 110 to 500 centipoise and II) from 80 to 20 percent, based on the total weight of said rubber particles, of a low solution viscosity component having a viscosity value ranging from 1 to 100 centipoise, further characterized in that the ratio of solution viscosity of high solution viscosity component to the solution viscosity of low solution viscosity ranges from 1.1 to 500, wherein both component I and II have a 1,4 cis content of greater than 30 percent, and III) the rubber is grafted with monovinylidene aromatic polymer to the extent that there is at least 30 percent monovinylidene aromatic polymer present as grafts on the rubber.

公开(公告)号：EP1244721A1

公开(公告)日：2002-10-02

申请号：EP00980429.5

申请日：2000-11-16

Applicant: DOW GLOBAL TECHNOLOGIES INC.

Inventor： DEMIRORS, Mehmet ,  SCHRADER, David ,  REGO, Jose M.

IPC: C08F279/02 ,  C08L51/04 ,  C08L25/02

CPC classification number: C08L51/04 ,  C08F279/02 ,  C08L25/06 ,  C08L2666/24 ,  C08L2666/02

Abstract: The present invention is a rubber modified monovinylidene aromatic polymer comprising: a) a monovinylidene aromatic polymer matrix, b) rubber particles dispersed therein, characterized in that the rubber particles are produced form a diene rubber having I) a high molecular weight component and II) a low molecular weight component; the high molecular weight component having a weight average molecular weight at least two and one half times greater than the weight average molecular weight of the low molecular weight component, wherein both components I and II have a 1,4 cis content of greater than 70 percent and III) the rubber is grafted with monovinylidene aromatic polymer to the extend that there is at least 30 percent monovinylidene aromatic polymer present as grafts on the rubber.