Abstract:
A catalytic hydrocarbon reformer comprising a catalyst concentrically disposed within a reformer tube surrounded by an annular flow space for air entering a fuel-air mixing zone ahead of the catalyst. The catalyst is sustained by minimal insulative mounting material so that most of the side of the catalyst is exposed for radial radiative heat transfer to the reformer tube for cooling by air in the annular flow space. The forward portion of the mounting material preferably is formed of a thermally-conductive material to provide radial conductive cooling of the entry of the catalyst to prevent overheating during catalysis. The incoming air flow is protected from heat exchange with hot reformate exiting the catalyst, allowing for convective cooling of the catalyst side and greater cooling of the catalyst face, thus increasing the working life of the catalyst while providing for rapid startup of the reformer and associated fuel cell system.
Abstract:
In one embodiment, a fuel reformer 100 can comprise: a mixing zone 26 capable of mixing a fuel and an oxidant to form a fuel mixture 32 and a reforming zone 28 disposed downstream of the mixing zone 26. The reforming zone 28 comprises a primary substrate 18 and a secondary substrate 20. The primary substrate 18 is disposed upstream of the secondary substrate 20 and has a primary thermal mass that is greater than a secondary thermal mass of the secondary substrate 20. One embodiment of a method for operating a fuel reformer 100 can comprise: mixing an oxidant and a fuel to form a fuel mixture 32, combusting the fuel mixture 32, heating the secondary substrate 20 above its light-off temperature, changing an air to fuel ratio of the fuel mixture 32 to a reforming mixture, producing an exotherm and a reformate at the secondary substrate 20, heating a primary substrate 18 with the exotherm to above its light-off temperature, and producing a reformate.
Abstract:
A catalytic hydrocarbon reformer comprising a catalyst concentrically disposed within a reformer tube surrounded by an annular flow space for air entering a fuel-air mixing zone ahead of the catalyst. The catalyst is sustained by minimal insulative mounting material so that most of the side of the catalyst is exposed for radial radiative heat transfer to the reformer tube for cooling by air in the annular flow space. The forward portion of the mounting material preferably is formed of a thermally-conductive material to provide radial conductive cooling of the entry of the catalyst to prevent overheating during catalysis. The incoming air flow is protected from heat exchange with hot reformate exiting the catalyst, allowing for convective cooling of the catalyst side and greater cooling of the catalyst face, thus increasing the working life of the catalyst while providing for rapid startup of the reformer and associated fuel cell system.
Abstract:
In one embodiment, a fuel reformer 100 can comprise: a mixing zone 26 capable of mixing a fuel and an oxidant to form a fuel mixture 32 and a reforming zone 28 disposed downstream of the mixing zone 26. The reforming zone 28 comprises a primary substrate 18 and a secondary substrate 20. The primary substrate 18 is disposed upstream of the secondary substrate 20 and has a primary thermal mass that is greater than a secondary thermal mass of the secondary substrate 20. One embodiment of a method for operating a fuel reformer 100 can comprise: mixing an oxidant and a fuel to form a fuel mixture 32, combusting the fuel mixture 32, heating the secondary substrate 20 above its light-off temperature, changing an air to fuel ratio of the fuel mixture 32 to a reforming mixture, producing an exotherm and a reformate at the secondary substrate 20, heating a primary substrate 18 with the exotherm to above its light-off temperature, and producing a reformate.