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1.发明申请CATALYST COMPOSITIONS AND THE USE THEREOF IN THE HYDROGENATION OF CARBOXYLIC ACID ESTERS 审中-公开催化剂组合物及其在羧酸酯加氢反应中的应用
公开(公告)号：WO1994027721A1
公开(公告)日：1994-12-08
申请号：PCT/US1994005663
申请日：1994-05-20
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： EASTMAN CHEMICAL COMPANY , KUO, Yeong-Jen
IPC: B01J23/80
CPC classification number: C07C29/149 , B01J23/80 , C07C29/141 , C07C29/145 , Y02P20/52 , C07C31/08 , C07C31/205 , C07C31/10 , C07C31/276 , C07C31/202 , C07C31/125 , C07C33/22 , C07C31/207 , C07C31/20 , C07C31/04 , C07C31/12
Abstract: Disclosed are catalyst compositions comprised of the oxides of copper, zinc, and a third element selected from the group consisting of aluminum, magnesium, zirconium, and mixtures thereof, and the use of such catalyst compositions in the hydrogenation of carbonyl compounds such as carboxylate esters to obtain the alcohol corresponding to the acid residue of the ester.
Abstract translation: 公开了由铜，锌的氧化物和选自铝，镁，锆及其混合物的第三元素组成的催化剂组合物，以及这些催化剂组合物在羰基化合物如羧酸酯的氢化中的用途 以获得对应于酯的酸残基的醇。
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公开(公告)号：WO1994029259A1
公开(公告)日：1994-12-22
申请号：PCT/US1994006265
申请日：1994-06-03
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： EASTMAN CHEMICAL COMPANY , GUSTAFSON, Bruce, LeRoy , KUO, Yeong-Jen , TENNANT, Brent, Alan
IPC: C07C67/303
CPC classification number: C07C67/303 , C07C2601/14 , C07C69/75
Abstract: Disclosed is a process for the preparation of a dimethyl cyclohexanedicarboxylate by the hydrogenation of the analogous dimethyl benzenedicarboxylate ester in the presence of a class of palladium on alumina catalysts which have a unique combination of characteristics. The use of the catalysts permits the process to be carried out at significantly lower process pressures.
Abstract translation: 公开了一种通过类似的二苯基二羧酸酯在一类具有独特特征组合的氧化铝催化剂存在下氢化制备二甲基环己烷二羧酸酯的方法。 催化剂的使用允许以显着更低的工艺压力进行该方法。
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公开(公告)号：WO1997007113A1
公开(公告)日：1997-02-27
申请号：PCT/US1996013343
申请日：1996-08-14
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： EASTMAN CHEMICAL COMPANY , KUO, Yeong-Jen , HARTLEY, Gary, Wayne , GUSTAFSON, Bruce, LeRoy , ALLEN, David, John
IPC: C07D311/72
CPC classification number: C07D311/72 , Y02P20/582
Abstract: Disclosed is an improved process for the preparation of alpha-tocopherol by the hydroxymethylation followed by the hydrogenation of non- alpha -tocopherols comprising beta -, gamma -, and delta -tocopherols using a particular palladium on alumina catalyst wherein (1) the dispersion and depth of deposition of the palladium metal are within certain ranges, and (2) the alumina is of a particular crystalline phase.
Abstract translation: 公开了一种通过羟甲基化制备α-生育酚的改进方法，随后使用特定的氧化铝催化剂氢化包含β - ，γ - 和δ-生育酚的非α-生育酚，其中（1）分散体和 钯金属的沉积深度在一定范围内，（2）氧化铝具有特定的结晶相。
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4.发明申请LOW PRESSURE PROCESS FOR THE HYDROGENATION OF DIMETHYL BENZENEDICARBOXYLATES TO THE CORRESPONDING DIMETHYL CYCLOHEXANEDICARBOXYLATES 审中-公开二甲基苯二甲酸二异氰酸酯加成二甲基环己烷二羧酸的低压法
公开(公告)号：WO1994029260A1
公开(公告)日：1994-12-22
申请号：PCT/US1994006266
申请日：1994-06-03
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： EASTMAN CHEMICAL COMPANY , GUSTAFSON, Bruce, LeRoy , TENNANT, Brent, Alan , KUO, Yeong-Jen , PRICE, Timothy, Warren
IPC: C07C67/303
CPC classification number: C07C67/303 , B01J23/44 , B01J23/462 , B01J23/892 , B01J35/0066 , B01J35/1042 , B01J35/1061 , C07C69/75
Abstract: Disclosed is a process for the preparation of a dimethyl cyclohexanedicarboxylate by the hydrogenation of the corresponding dimethyl benzenedicarboxylate ester in the presence of a class of supported catalysts comprising palladium and a second Group VIII metal selected from nickel, platinum, ruthenium or a mixture thereof deposited on an alumina support which have a unique combination of characteristics. The use of the catalysts permits the process to be carried out at significantly lower process pressures.
Abstract translation: 公开了一种通过在相应的二苯基二羧酸酯的氢化下，在一类负载型催化剂的存在下制备二甲基环己烷二羧酸酯的方法，该催化剂包含钯和选自镍，铂，钌或其沉积在 具有特征组合的氧化铝载体。 催化剂的使用允许以显着更低的工艺压力进行该方法。
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5.发明授权LOW PRESSURE PROCESS FOR THE HYDROGENATION OF DIMETHYL BENZENEDICARBOXYLATES TO THE CORRESPONDING DIMETHYL CYCLOHEXANEDICARBOXYLATES 失效低压流程FOR DIMETHYLBENZOLDICARBOXYLATEN加氢适当DIMETHYLCYCLOHEXANCARBOXYLATEN
公开(公告)号：EP0703894B1
公开(公告)日：1998-08-26
申请号：EP94919348.6
申请日：1994-06-03
Applicant: EASTMAN CHEMICAL COMPANY
IPC: C07C67/303 , C07C69/75
CPC classification number: C07C67/303 , B01J23/44 , B01J23/462 , B01J23/892 , B01J35/0066 , B01J35/1042 , B01J35/1061 , C07C69/75
Abstract: Disclosed is a process for the preparation of a dimethyl cyclohexanedicarboxylate by the hydrogenation of the corresponding dimethyl benzenedicarboxylate ester in the presence of a class of supported catalysts comprising palladium and a second Group VIII metal selected from nickel, platinum, ruthenium or a mixture thereof deposited on an alumina support which have a unique combination of characteristics. The use of the catalysts permits the process to be carried out at significantly lower process pressures.
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Patent Agency Ranking
公开(公告)号：EP0844995B1
公开(公告)日：1999-11-17
申请号：EP96928908.1
申请日：1996-08-14
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： KUO, Yeong-Jen , HARTLEY, Gary, Wayne , GUSTAFSON, Bruce, LeRoy , ALLEN, David, John
IPC: C07D311/72
CPC classification number: C07D311/72 , Y02P20/582
Abstract: Disclosed is an improved process for the preparation of alpha-tocopherol by the hydroxymethylation followed by the hydrogenation of non-α-tocopherols comprising β-, η-, and δ-tocopherols using a particular palladium on alumina catalyst wherein (1) the dispersion and depth of deposition of the palladium metal are within certain ranges, and (2) the alumina is of a particular crystalline phase.
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公开(公告)号：EP0703895B1
公开(公告)日：1998-05-13
申请号：EP94920074.5
申请日：1994-06-03
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： GUSTAFSON, Bruce, LeRoy , KUO, Yeong-Jen , TENNANT, Brent, Alan
IPC: C07C67/303 , C07C69/75
CPC classification number: C07C67/303 , C07C2601/14 , C07C69/75
Abstract: Disclosed is a process for the preparation of a dimethyl cyclohexanedicarboxylate by the hydrogenation of the analogous dimethyl benzenedicarboxylate ester in the presence of a class of palladium on alumina catalysts which have a unique combination of characteristics. The use of the catalysts permits the process to be carried out at significantly lower process pressures.
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8.发明公开LOW PRESSURE PROCESS FOR THE HYDROGENATION OF DIMETHYL BENZENEDICARBOXYLATES TO THE CORRESPONDING DIMETHYL CYCLOHEXANEDICARBOXYLATES 失效二甲基苯甲酸甲酯氢化生成相应的二甲基环己烷二甲酸酯的低压方法
公开(公告)号：EP0703894A1
公开(公告)日：1996-04-03
申请号：EP94919348.0
申请日：1994-06-03
Applicant: EASTMAN CHEMICAL COMPANY
CPC classification number: C07C67/303 , B01J23/44 , B01J23/462 , B01J23/892 , B01J35/0066 , B01J35/1042 , B01J35/1061 , C07C69/75
Abstract: Disclosed is a process for the preparation of a dimethyl cyclohexanedicarboxylate by the hydrogenation of the corresponding dimethyl benzenedicarboxylate ester in the presence of a class of supported catalysts comprising palladium and a second Group VIII metal selected from nickel, platinum, ruthenium or a mixture thereof deposited on an alumina support which have a unique combination of characteristics. The use of the catalysts permits the process to be carried out at significantly lower process pressures.
Abstract translation: 本发明公开了一种制备环己烷二羧酸二甲酯的方法，该方法是在一类负载型催化剂的存在下，通过氢化相应的苯二甲酸二甲酯来制备环己烷二羧酸二甲酯，所述负载型催化剂包含钯和选自镍，铂，钌或其混合物的第二第VIII族金属 具有独特组合特征的氧化铝载体。 催化剂的使用允许该过程在显着较低的过程压力下进行。
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9.发明公开CATALYST COMPOSITIONS AND THE USE THEREOF IN THE HYDROGENATION OF CARBOXYLIC ACID ESTERS 失效催化剂组合物及它们在CARBONSAEUREESTERN加氢
公开(公告)号：EP0701479A1
公开(公告)日：1996-03-20
申请号：EP94917450.0
申请日：1994-05-20
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： KUO, Yeong-Jen
CPC classification number: C07C29/149 , B01J23/80 , C07C29/141 , C07C29/145 , Y02P20/52 , C07C31/08 , C07C31/205 , C07C31/10 , C07C31/276 , C07C31/202 , C07C31/125 , C07C33/22 , C07C31/207 , C07C31/20 , C07C31/04 , C07C31/12
Abstract: Disclosed are catalyst compositions comprised of the oxides of copper, zinc, and a third element selected from the group consisting of aluminum, magnesium, zirconium, and mixtures thereof, and the use of such catalyst compositions in the hydrogenation of carbonyl compounds such as carboxylate esters to obtain the alcohol corresponding to the acid residue of the ester.
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公开(公告)号：EP0844995A1
公开(公告)日：1998-06-03
申请号：EP96928908.0
申请日：1996-08-14
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： KUO, Yeong-Jen , HARTLEY, Gary, Wayne , GUSTAFSON, Bruce, LeRoy , ALLEN, David, John
CPC classification number: C07D311/72 , Y02P20/582
Abstract: Disclosed is an improved process for the preparation of alpha-tocopherol by the hydroxymethylation followed by the hydrogenation of non-α-tocopherols comprising β-, η-, and δ-tocopherols using a particular palladium on alumina catalyst wherein (1) the dispersion and depth of deposition of the palladium metal are within certain ranges, and (2) the alumina is of a particular crystalline phase.
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