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    POLYETHER GLYCOLS AND ALCOHOLS DERIVED FROM 3,4-EPOXY-1-BUTENE
    1.
    发明申请
    POLYETHER GLYCOLS AND ALCOHOLS DERIVED FROM 3,4-EPOXY-1-BUTENE 审中-公开
    来自3,4-环氧-1-丁烯的聚乙二醇和醇

    公开(公告)号：WO1995019383A1

    公开(公告)日：1995-07-20

    申请号：PCT/US1995000738

    申请日：1995-01-17

    Applicant: EASTMAN CHEMICAL COMPANY

    Inventor： EASTMAN CHEMICAL COMPANY ,  MATAYABAS, James, C., Jr. ,  FALLING, Stephen, N.

    IPC: C08G65/20

    CPC classification number: C08G65/14 ,  C08G65/322

    Abstract: Disclosed are novel saturated polyether compounds comprised of n units of residue (1) and m units of residue (2), wherein (i) residues (1) and (2) have the structures (1) and (2); (ii) the total value of n + m is 2 to 70 and m/(n + m) is 0.05 to 0.98; (ii) at least 98 percent of the terminal hydroxyl groups of the polyether have the structure (3) or (4). The polyethers are obtained by first polymerizing 3,4-epoxy-1-butene to produce unsaturated polyether precursors comprising residues (1A) and (2A) having the structures (1A) and (2A), and then hydrogenating the unsaturated polyether precursors. The hydrogenation advantageously is performed in the presence of a nickel hydrogenation catalyst.

    Abstract translation: 公开了由n个残基（1）单元和m个残基（2）组成的新型饱和聚醚化合物，其中（i）残基（1）和（2）具有结构（1）和（2）; （ii）n + m的总值为2〜70，m /（n + m）为0.05〜0.98; （ii）聚醚的至少98％的末端羟基具有结构（3）或（4）。 通过首先聚合3,4-环氧-1-丁烯以制备包含具有结构（1A）和（2A）的残基（1A）和（2A））的不饱和聚醚前体，然后氢化不饱和聚醚前体而获得聚醚。 氢化有利地在镍加氢催化剂的存在下进行。

    POLYETHER GLYCOLS AND ALCOHOLS DERIVED FROM 3,4-EPOXY-1-BUTENE
    2.
    发明申请
    POLYETHER GLYCOLS AND ALCOHOLS DERIVED FROM 3,4-EPOXY-1-BUTENE 审中-公开
    来自3,4-环氧-1-丁烯的聚乙二醇和醇

    公开(公告)号：WO1995019381A1

    公开(公告)日：1995-07-20

    申请号：PCT/US1995000594

    申请日：1995-01-17

    Applicant: EASTMAN CHEMICAL COMPANY

    Inventor： EASTMAN CHEMICAL COMPANY ,  MATAYABAS, James, C., Jr. ,  FALLING, Stephen, N.

    IPC: C08G65/14

    CPC classification number: C07C43/178 ,  C08G65/14 ,  C08G65/26

    Abstract: Disclosed are novel polyether compounds obtained by the reaction or polymerization of 3,4-epoxy-1-butene in the presence of an acidic catalyst and a nucleophilic initiator compound. The polyether compounds comprise n units of residue (1) and m units of residue (2), wherein the total value of n + m is 2 to 70, n/(n + m) is a value in the range of 0.70 to 0.95, and residues (1) and (2) have the structures (1 and 2).

    Abstract translation: 公开了在酸性催化剂和亲核引发剂化合物的存在下通过3,4-环氧-1-丁烯的反应或聚合获得的新型聚醚化合物。 聚醚化合物包含n个残基（1）单元和m个残基（2），其中n + m的总值为2〜70，n /（n + m）为0.70〜0.95的范围内的值 残基（1）和（2）具有结构（1和2）。

    POLYETHER GLYCOLS AND ALCOHOLS DERIVED FROM 3,4-EPOXY-1-BUTENE
    3.
    发明公开
    POLYETHER GLYCOLS AND ALCOHOLS DERIVED FROM 3,4-EPOXY-1-BUTENE 失效
    POLYETHERGLYOLE和酒精由3,4-环氧-1-丁烯

    公开(公告)号：EP0740678A1

    公开(公告)日：1996-11-06

    申请号：EP95908575.0

    申请日：1995-01-17

    Applicant: EASTMAN CHEMICAL COMPANY

    Inventor： MATAYABAS, James, C., Jr. ,  FALLING, Stephen, N.

    IPC: C08G65

    CPC classification number: C08G65/14 ,  C08G65/322

    Abstract: Disclosed are novel saturated polyether compounds comprised of n units of residue (1) and m units of residue (2), wherein (i) residues (1) and (2) have the structures (1) and (2); (ii) the total value of n + m is 2 to 70 and m/(n + m) is 0.05 to 0.98; (ii) at least 98 percent of the terminal hydroxyl groups of the polyether have the structure (3) or (4). The polyethers are obtained by first polymerizing 3,4-epoxy-1-butene to produce unsaturated polyether precursors comprising residues (1A) and (2A) having the structures (1A) and (2A), and then hydrogenating the unsaturated polyether precursors. The hydrogenation advantageously is performed in the presence of a nickel hydrogenation catalyst.

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