公开(公告)号：EP0494639A3

公开(公告)日：1993-04-14

申请号：EP92100147.5

申请日：1992-01-07

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Baron, Arthur Lawrence ,  Myers, Terry Ned

IPC: C08G18/38

CPC classification number: C08G18/285 ,  C08G18/3834

Abstract: Stabilized polyurethanes, polyureas and polyurethane-polyurea polymers having hindered amine light stabilizers (HALS) bonded thereto by means of a hydrazide functionality attached to the HALS are provided. The synergistic effect of a second amide functional group in the HALS-hydrazide provides improved photostabilization efficiency as compared to HALS-hydrazides of the prior art.

公开(公告)号：EP0368237A3

公开(公告)日：1991-09-04

申请号：EP89120588.2

申请日：1989-11-07

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Myers, Terry Ned ,  Macleay, Ronald Edward

IPC: C08F8/00

CPC classification number: C08F8/30

Abstract: Polymeric flame retardants comprise halogenated aromatic compounds having acylamino functional groups which are chemically bonded to cyclic imide-containing or imide-forming polymers or copolymers, which polymeric flame retardants have, e.g., the following Formula 1 or II:
in which the units occur, e.g., in the polymer backbone; R1 and R2 are, e.g., hydrogen; and G is a flame retardant group attached to the unit by an acylamino functional group having linked thereto a halogenated aromatic ring. The polymeric flame retardants are prepared by the reaction of halogenated aromatics containing a reactive hydrazido group with some or all of the anhydride groups of an cyclic alpha,beta-unsaturated dicarboxylic acid anhydride polymer or copolymer to form pendant halogenated-aromatic-substituted imide or amic acid groups. In addition, polymeric flame retardants are used to render thermoplastic resins less flammable under conditions which promote combustion. Novel flame retardant hydrazides are disclosed.

公开(公告)号：EP0494639A2

公开(公告)日：1992-07-15

申请号：EP92100147.5

申请日：1992-01-07

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Baron, Arthur Lawrence ,  Myers, Terry Ned

IPC: C08G18/38

CPC classification number: C08G18/285 ,  C08G18/3834

Abstract: Stabilized polyurethanes, polyureas and polyurethane-polyurea polymers having hindered amine light stabilizers (HALS) bonded thereto by means of a hydrazide functionality attached to the HALS are provided. The synergistic effect of a second amide functional group in the HALS-hydrazide provides improved photostabilization efficiency as compared to HALS-hydrazides of the prior art.

Abstract translation: 设置键合到其稳定的聚氨酯，聚脲和聚氨酯 - 聚脲聚合物具有受阻胺光稳定剂（HALS），通过酰肼功能上连接到HALS手段。 第二酰胺官能团在HALS酰肼的协同效应提供了改进的效率，因为光稳定相比于现有技术的HALS酰肼。

公开(公告)号：EP0368237B1

公开(公告)日：1995-04-12

申请号：EP89120588.2

申请日：1989-11-07

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Myers, Terry Ned ,  Macleay, Ronald Edward

IPC: C08F8/00

CPC classification number: C08F8/30

公开(公告)号：EP0368237A2

公开(公告)日：1990-05-16

申请号：EP89120588.2

申请日：1989-11-07

Applicant: ELF ATOCHEM NORTH AMERICA, INC.

Inventor： Myers, Terry Ned ,  Macleay, Ronald Edward

IPC: C08F8/00

CPC classification number: C08F8/30

Abstract: Polymeric flame retardants comprise halogenated aromatic compounds having acylamino functional groups which are chemically bonded to cyclic imide-containing or imide-forming polymers or copolymers, which polymeric flame retardants have, e.g., the following Formula 1 or II:
in which the units occur, e.g., in the polymer backbone; R1 and R2 are, e.g., hydrogen; and G is a flame retardant group attached to the unit by an acylamino functional group having linked thereto a halogenated aromatic ring. The polymeric flame retardants are prepared by the reaction of halogenated aromatics containing a reactive hydrazido group with some or all of the anhydride groups of an cyclic alpha,beta-unsaturated dicarboxylic acid anhydride polymer or copolymer to form pendant halogenated-aromatic-substituted imide or amic acid groups. In addition, polymeric flame retardants are used to render thermoplastic resins less flammable under conditions which promote combustion. Novel flame retardant hydrazides are disclosed.

Abstract translation: 聚合物阻燃剂包括具有酰基氨基官能团的卤代芳族化合物，该酰基氨基官能团与环状酰亚胺或形成酰亚胺的聚合物或共聚物化学键合，该聚合物阻燃剂具有例如以下通式1或II：，其中单元 发生在例如聚合物骨架中; R1和R2是例如氢; G是通过连接有卤代芳香环的酰基氨基官能团而与该单元连接的阻燃剂基团。 通过使含有反应性肼基的卤代芳族化合物与环状α，β-不饱和二羧酸酐聚合物或共聚物的一部分或全部酐基反应形成聚合物阻燃剂，以形成卤化芳族取代的酰亚胺或酰胺侧基 酸性基团。 此外，聚合物阻燃剂用于在促进燃烧的条件下使热塑性树脂更易燃。 公开了新的阻燃酰肼。