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    4.
    发明专利
    未知

    公开(公告)号：SE8204785L

    公开(公告)日：1983-02-22

    申请号：SE8204785

    申请日：1982-08-20

    Applicant: EXXON RESEARCH ENGINEERING CO

    Inventor： OSWALD A A ,  JERMANSEN T G ,  WESTNER A A ,  HUANG I-D

    IPC: B01J31/24 ,  C07C29/16 ,  C07C31/125 ,  C07C45/49 ,  C07C45/50 ,  C07F9/50 ,  C07F15/00 ,  B01J31/18

    Abstract: Described is a carbonylation process using novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula: [(Ar2PQ)ySiR4-y]g(MXn)s wherein Ar is a C6 to C10 aromatic hydrocarbyl radical, Q is a C1 to C30 saturated straight chain divalent radical, R is a C1 to C10 hydrocarbyl, wherein Ar, Q and R, can be substituted or unsubstituted, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the valence and coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials exhibit high thermal stability and are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of ligand of the formula: (Ar2PQ)ySiR4-y wherein Ar, Q, R, and y are as previously defined. Specifically, tris-(trimethyl silyl-ethyl diphenyl phosphine) rhodium carbonyl hydride, [(CH3)3Si-CH2CH2-PPh2]3Rh(CO)H and tris [bis-(diphenylphosphinoethyl) dimethyl silane] rhodium carbonyl hydride, [(CH3)2Si-CH2CH2-PPh2]3Rh(CO)H, are selective olefin hydroformylation catalysts, particularly in the presence of excess trihydrocarbyl silyl-substituted alkyl diaryl phosphine ligand.

    5.
    发明专利
    未知

    公开(公告)号：SE8204785D0

    公开(公告)日：1982-08-20

    申请号：SE8204785

    申请日：1982-08-20

    Applicant: EXXON RESEARCH ENGINEERING CO

    Inventor： OSWALD A A ,  JERMANSEN T G ,  WESTNER A A ,  HUANG I-D

    IPC: B01J31/24 ,  C07C29/16 ,  C07C31/125 ,  C07C45/49 ,  C07C45/50 ,  C07F9/50 ,  C07F15/00

    Abstract: Described is a carbonylation process using novel homogeneous trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes of the general formula: [(Ar2PQ)ySiR4-y]g(MXn)s wherein Ar is a C6 to C10 aromatic hydrocarbyl radical, Q is a C1 to C30 saturated straight chain divalent radical, R is a C1 to C10 hydrocarbyl, wherein Ar, Q and R, can be substituted or unsubstituted, y is 1 to 4, g times y is 1 to 6, M is a transition metal selected from the group consisting of Group VIII transition metals, X is an anion or organic ligand excluding halogen satisfying the valence and coordination sites of the metal, n is 2 to 6 and s is 1 to 3, are disclosed. These materials exhibit high thermal stability and are superior catalysts for the selective hydroformylation of olefins, particularly in the presence of excess quantities of ligand of the formula: (Ar2PQ)ySiR4-y wherein Ar, Q, R, and y are as previously defined. Specifically, tris-(trimethyl silyl-ethyl diphenyl phosphine) rhodium carbonyl hydride, [(CH3)3Si-CH2CH2-PPh2]3Rh(CO)H and tris [bis-(diphenylphosphinoethyl) dimethyl silane] rhodium carbonyl hydride, [(CH3)2Si-CH2CH2-PPh2]3Rh(CO)H, are selective olefin hydroformylation catalysts, particularly in the presence of excess trihydrocarbyl silyl-substituted alkyl diaryl phosphine ligand.

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