公开(公告)号：WO2006134103A8

公开(公告)日：2007-03-15

申请号：PCT/EP2006063141

申请日：2006-06-13

Applicant: FORSCHUNGSVERBUND BERLIN EV ,  KLEHR ANDREAS ,  SUMPF BERND ,  MAIWALD MARTIN ,  SCHMIDT HEINAR

Inventor： KLEHR ANDREAS ,  SUMPF BERND ,  MAIWALD MARTIN ,  SCHMIDT HEINAR

IPC: G01J3/44 ,  G01J3/10 ,  G01N21/65 ,  H01S5/0625

CPC classification number: G01N21/65 ,  G01J3/10 ,  G01J3/44 ,  G01J2003/4424 ,  G01N2021/656

Abstract: The invention relates to a method and a device for producing and detecting a Raman spectrum. The problem addressed by the present invention is that of devising a method and a device for producing and detecting a Raman spectrum of a medium under investigation, whereby the Raman spectrum of a medium that is under investigation can be examined with a high degree of sensitivity while requiring relatively little equipment. The method is characterised by the coupling of excitation radiation into a medium (8) under investigation and the coupling of the electromagnetic radiation scattered by the medium (8) under investigation into a spectral optic system (10), a laser diode (1) for generating excitation radiation with at least two different wavelengths (? 1 , ? 2 ) being controlled with at least two different excitation conditions and at least one Raman spectrum (16, 17) being detected in each case from the scattered radiation at the different excitation wavelengths (? 1 , ? 2 ), and the Raman spectrum (20) of the medium (8) under investigation being determined from the at least two detected Raman spectra (16, 17), the two different excitation conditions for the laser diode (1) being adjusted by means of the electric current supplied to the laser diode (1).

Abstract translation: 本发明涉及一种用于产生和检测的拉曼光谱的方法和装置。 本发明的目的是提供一种用于产生和检测的被检查介质，利用该具有高灵敏度的被检查介质的拉曼光谱可以在上装置相对低的支出来确定的拉曼光谱的方法和装置。 该方法的特征在于，耦合激发辐射到被检体内待检查介质（8），待检查的耦合介质（8）散射的电磁辐射的光谱光学系统（10），用于产生激发辐射的激光二极管（1）至少 两种不同波长的被驱动与至少两个不同的激发条件（2？1，？）和出散射辐射的在每种情况下的不同的激发波长（λ1，？2）至少一种拉曼光谱（16，17）被检测并从该至少 两个检测到的拉曼光谱（16，17）时，要被检查介质（8）被确定的拉曼光谱（20），其特征在于，被设置施加由所述激光二极管（1）的电流的激光二极管（1）的两个不同的激励条件 是。

公开(公告)号：DE102009029648B3

公开(公告)日：2011-03-24

申请号：DE102009029648

申请日：2009-09-21

Applicant: FORSCHUNGSVERBUND BERLIN EV

Inventor： MAIWALD MARTIN ,  SCHMIDT HEINAR ,  KAISER DANIEL PEREZ

IPC: G01J3/44

Abstract: Die vorliegende Erfindung betrifft ein Verfahren und eine Vorrichtung zur Erzeugung und zur Detektion eines Raman-Spektrums. Es ist Aufgabe der vorliegenden Erfindung, ein Verfahren und eine Vorrichtung zur Erzeugung und zur Detektion eines Raman-Spektrums anzugeben, die eine automatisierte bzw. automatisierbare und gleichzeitig quantitative SERD-Spektroskopie (z.B. Konzentrationsmessreihen) ermöglichen. Dazu werden bei der SERD-Spektroskopie ein erstes Spektrum (16) und ein zweites Spektrum (17) in Bezug auf ihre Intensitätswerte zueinander normiert, und nachfolgend ein erstes Differenzspektrum (D1) berechnet, ein zweites Differenzspektrum (D2) berechnet, das erste Differenzspektrum (D1) in ein erstes Transformationsspektrum (K1) überführt, das zweite Differenzspektrum (D2) in ein zweites Transformationsspektrum (K2) überführt und das Raman-Spektrum (R1) durch Addition des ersten Transformationsspektrums (K1) und des zweiten Transformationsspektrums (K2) berechnet.

公开(公告)号：DE102005028268A1

公开(公告)日：2006-12-28

申请号：DE102005028268

申请日：2005-06-14

Applicant: FORSCHUNGSVERBUND BERLIN EV ,  UNIV BERLIN TECH

Inventor： KLEHR ANDREAS ,  SUMPF BERND ,  MAIWALD MARTIN ,  SCHMIDT HEINAR

IPC: G01N21/65

Abstract: The invention relates to a method and a device for producing and detecting a Raman spectrum. The problem addressed by the present invention is that of devising a method and a device for producing and detecting a Raman spectrum of a medium under investigation, whereby the Raman spectrum of a medium that is under investigation can be examined with a high degree of sensitivity while requiring relatively little equipment. The method is characterized by the coupling of excitation radiation into a medium (8) under investigation and the coupling of the electromagnetic radiation scattered by the medium (8) under investigation into a spectral optic system (10), a laser diode (1) for generating excitation radiation with at least two different wavelengths (λ1, λ2) being controlled with at least two different excitation conditions and at least one Raman spectrum (16, 17) being detected in each case from the scattered radiation at the different excitation wavelengths (λ1, λ2), and the Raman spectrum (20) of the medium (8) under investigation being determined from the at least two detected Raman spectra (16, 17), the two different excitation conditions for the laser diode (1) being adjusted by means of the electric current supplied to the laser diode (1).

公开(公告)号：DK2480868T3

公开(公告)日：2014-03-31

申请号：DK10763149

申请日：2010-09-16

Applicant: FORSCHUNGSVERBUND BERLIN EV

Inventor： SCHMIDT HEINAR ,  PEREZ KAISER DANIEL ,  MAIWALD MARTIN

IPC: G01J3/28 ,  G01J3/44 ,  G01J3/457 ,  G01N21/27 ,  G01N21/65