Abstract:
Provided is a dispersion composition which has a high refractive index. The surface of a film coated from the dispersion has an excellent surface condition. Also provided is a curable composition comprising the dispersion, a transparent film, a microlens and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70; a polymer compound (B) having an acid value of less than 120 mgKOH/g and being represented by Formula (1); and a solvent (C): (A 1 -R 2 )5 n -R 1 (5P 1 ) m Formula (1) wherein: R 1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L 3 represents a trivalent group; T 3 represents a single bond or a divalent linking group; and the three T 3 's may be the same or different; L 4 represents a tetravalent group; T 4 represents a single bond or a divalent linking group, and the four T 4 's may be the same or different; L 5 represents a pentavalent group; T 5 represents a single bond or a divalent linking group, and the five T 5 's may be the same or different; L 6 represents a hexavalent group; T 6 represents a single bond or a divalent linking group, and the six T 6 's may be the same or different; R 2 represents a single bond or a divalent linking group, A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A 1 's and n R 2 's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P 1 represents a polymer chain, and m P 1 's may be the same or different.
Abstract:
Provided is a dispersion composition which has a high refractive index and has a high dispersion stability, a curable composition using the same, a transparent film, a microlens, and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70, a polymer compound (B) having an acid value of 120 mgKOH/g or more, which is represented by the following Formula (1), and a solvent (C): wherein: R 1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L 3 represents a trivalent group; T 3 represents a single bond or a divalent linking group; and the three T 3 's may be same or different; L 4 represents a tetravalent group; T 4 represents a single bond or a divalent linking group, and the four T 4 's may be the same or different; L 5 represents a pentavalent group; T 5 represents a single bond or a divalent linking group, and the five T 5 's may be the same or different; L 6 represents a hexavalent group; T 6 represents a single bond or a divalent linking group, and the six T 6 's may be the same or different, R 2 represents a single bond or a divalent linking group, A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A 1 's and n R 2 's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P 1 represents a polymer chain, and m P 1 ,s may be the same or different.
Title translation:NAHINFRAROT-ABSORBIERENDE ZUSAMMENSETZUNG,HÄRTBAREZUSAMMENSETZUNG,GEHÄRTETERFILM,NAHINFRAROT-SPERRFILTER,FESTKÖRPERBILDGEBUNGSELEMENT,INFRAROTSENSOR,KAMERAMODUL,VERARBEITETER FARBSTOFF UND VERFAHREN ZUR HERSTELLUNG EINES VERARBEITETEN FARBSTOFFES
Abstract:
The invention provides a near-infrared absorption composition having high dispersibility of a near-infrared absorption coloring agent and small thixotropy, a curable composition, a cured film, a near-infrared cut filter, a solid-state imaging device, an infrared sensor, a camera module, a processed coloring agent, and a method of manufacturing a processed coloring agent. The near-infrared absorption composition according to the invention includes a processed coloring agent obtained by coating a near-infrared absorption coloring agent with a resin having one or more selected from a coloring agent structure, a heterocyclic structure, and an acyclic hetero atom-containing group. The near-infrared absorption coloring agent is preferably one or more selected from a phthalocyanine coloring agent, a perylene coloring agent, a pyrrolopyrrole coloring agent, a cyanine coloring agent, a dithiol metal complex coloring agent, a naphthoquinone coloring agent, a diimmonium coloring agent, an azo coloring agent, and a squarylium coloring agent and more preferably a pyrrolopyrrole coloring agent.
Abstract:
Provided are a dispersion composition which has a high refractive index and has a high dispersion stability, a curable composition using the same, a transparent film, a microlens, and a solid-state imaging device. A dispersion composition containing metal oxide particles having a primary particle diameter of 1 nm to 100 nm (A), a polymer compound having an acid value of 120 mgKOH/g or more, which is represented by the following Formula (1) (B), and a solvent (C). In Formula (1), R 1 represents a (m+n)-valent linking group, and R 2 represents a single bond or a divalent linking group. A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group. n A 1 's and n R 2 's may be same or different. m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10. P 1 represents a polymer chain. m P 1 's may be same or different.
Abstract:
To provide a dispersion composition having a high refractive index and giving an excellent surface state to a film after coating, and a curable composition, a transparent film, a microlens and a solid-state imaging device each using the dispersion composition; and provide a compound able to afford a dispersion composition having a high refractive index and giving an excellent surface state to a film after coating and drying and maintain the dispersion stability of particles. A dispersion composition containing (A) a metal oxide particle having a primary particle diameter of 1 to 100 nm, (B) a polymer compound represented by the following formula (1) having a weight average molecular weight of 10,000 or less, and (C) a solvent: in formula (1), R 1 represents an (m+n)-valent linking group, R 2 represents a single bond or a divalent linking group, A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a coordinating oxygen atom-containing group, a basic nitrogen atom-containing group, a phenol group, an alkyl group, an aryl group, an alkyleneoxy chain-containing group, an imide group, an alkyloxycarbonyl group, an alkylaminocarbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group and a hydroxyl group, n number of A 1 or R 2 may be the same or different from each other, m represents a positive number of 8 or less, n represents from 1 to 9, m+n satisfies the range of 3 to 10, P 1 represents a polymer chain, and m number of P 1 may be the same or different from each other.
Abstract:
Provided are a dispersion composition which has a high refractive index and is has excellent surface conditions of a film surface after coating, a curable composition using the same, a transparent film, a microlens, and a solid-state imaging device. A dispersion composition containing metal oxide particles having a primary particle diameter of 1 nm to 100 nm (A), a polymer compound having an acid value of less than 120 mgKOH/g, which is represented by the following Formula (1) (B), and a solvent (C). In Formula (1), R 1 represents a (m+n)-valent linking group, and R 2 represents a single bond or a divalent linking group. A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group. n A 1 's and n R 2 's may be the same or different. m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10. P 1 represents a polymer chain. m P 1 's may be the same or different.