DISPERSION COMPOSITION, CURABLE COMPOSITION USING THE SAME, TRANSPARENT FILM, MICROLENS, AND SOLID-STATE IMAGING DEVICE

    公开(公告)号:SG11201501472WA

    公开(公告)日:2015-05-28

    申请号:SG11201501472W

    申请日:2013-08-29

    Applicant: FUJIFILM CORP

    Abstract: Provided is a dispersion composition which has a high refractive index. The surface of a film coated from the dispersion has an excellent surface condition. Also provided is a curable composition comprising the dispersion, a transparent film, a microlens and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70; a polymer compound (B) having an acid value of less than 120 mgKOH/g and being represented by Formula (1); and a solvent (C): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(A 1 -R 2 )5 n -R 1 (5P 1 ) m €ƒ€ƒ€ƒ€ƒ€ƒFormula (1) wherein: R 1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L 3 represents a trivalent group; T 3 represents a single bond or a divalent linking group; and the three T 3 's may be the same or different; L 4 represents a tetravalent group; T 4 represents a single bond or a divalent linking group, and the four T 4 's may be the same or different; L 5 represents a pentavalent group; T 5 represents a single bond or a divalent linking group, and the five T 5 's may be the same or different; L 6 represents a hexavalent group; T 6 represents a single bond or a divalent linking group, and the six T 6 's may be the same or different; R 2 represents a single bond or a divalent linking group, A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A 1 's and n R 2 's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P 1 represents a polymer chain, and m P 1 's may be the same or different.

    DISPERSION COMPOSITION, CURABLE COMPOSITION USING THE SAME, TRANSPARENT FILM, MICROLENS, AND SOLID-STATE IMAGING DEVICE

    公开(公告)号:SG11201501493RA

    公开(公告)日:2015-05-28

    申请号:SG11201501493R

    申请日:2013-08-29

    Applicant: FUJIFILM CORP

    Abstract: Provided is a dispersion composition which has a high refractive index and has a high dispersion stability, a curable composition using the same, a transparent film, a microlens, and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70, a polymer compound (B) having an acid value of 120 mgKOH/g or more, which is represented by the following Formula (1), and a solvent (C): wherein: R 1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L 3 represents a trivalent group; T 3 represents a single bond or a divalent linking group; and the three T 3 's may be same or different; L 4 represents a tetravalent group; T 4 represents a single bond or a divalent linking group, and the four T 4 's may be the same or different; L 5 represents a pentavalent group; T 5 represents a single bond or a divalent linking group, and the five T 5 's may be the same or different; L 6 represents a hexavalent group; T 6 represents a single bond or a divalent linking group, and the six T 6 's may be the same or different, R 2 represents a single bond or a divalent linking group, A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A 1 's and n R 2 's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P 1 represents a polymer chain, and m P 1 ,s may be the same or different.

    DISPERSION COMPOSITION, AND CURABLE COMPOSITION, TRANSPARENT FILM, MICROLENS AND SOLID-STATE IMAGING ELEMENT USING SAME, AND POLYMER COMPOUND
    7.
    发明公开
    DISPERSION COMPOSITION, AND CURABLE COMPOSITION, TRANSPARENT FILM, MICROLENS AND SOLID-STATE IMAGING ELEMENT USING SAME, AND POLYMER COMPOUND 有权
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    公开(公告)号:EP2891687A4

    公开(公告)日:2016-04-27

    申请号:EP13834016

    申请日:2013-08-29

    Applicant: FUJIFILM CORP

    Abstract: To provide a dispersion composition having a high refractive index and giving an excellent surface state to a film after coating, and a curable composition, a transparent film, a microlens and a solid-state imaging device each using the dispersion composition; and provide a compound able to afford a dispersion composition having a high refractive index and giving an excellent surface state to a film after coating and drying and maintain the dispersion stability of particles. A dispersion composition containing (A) a metal oxide particle having a primary particle diameter of 1 to 100 nm, (B) a polymer compound represented by the following formula (1) having a weight average molecular weight of 10,000 or less, and (C) a solvent: in formula (1), R 1 represents an (m+n)-valent linking group, R 2 represents a single bond or a divalent linking group, A 1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a coordinating oxygen atom-containing group, a basic nitrogen atom-containing group, a phenol group, an alkyl group, an aryl group, an alkyleneoxy chain-containing group, an imide group, an alkyloxycarbonyl group, an alkylaminocarbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group and a hydroxyl group, n number of A 1 or R 2 may be the same or different from each other, m represents a positive number of 8 or less, n represents from 1 to 9, m+n satisfies the range of 3 to 10, P 1 represents a polymer chain, and m number of P 1 may be the same or different from each other.

    Abstract translation: 提供具有高折射率并且对涂布后的膜赋予优异表面状态的分散组合物,以及使用该分散组合物的可固化组合物,透明膜,微透镜和固态成像装置; 并提供能够提供高折射率的分散组合物并且在涂布和干燥后对膜赋予优异的表面状态并保持颗粒的分散稳定性的化合物。 一种分散体组合物,其含有(A)一级粒径为1〜100nm的金属氧化物粒子,(B)由下式(1)表示的高分子化合物,其重均分子量为10,000以下,(C )溶剂:在式(1)中,R 1表示(m + n)价连接基团,R 2表示单键或二价连接基团,A 1表示具有至少一个选自 含有酸基,脲基,氨基甲酸酯基,配位氧原子基团,碱性氮原子基团,苯酚基,烷基,芳基,含亚烷基氧基的基团, 酰亚胺基,烷氧基羰基,烷基氨基羰基,羧酸酯基,磺酰胺基,杂环基,烷氧基甲硅烷基,环氧基,异氰酸酯基和羟基,n 1的A 1或R 2可以是 相同或不同,m表示ap 8个以下,n表示1〜9,m + n满足3〜10的范围,P 1表示聚合物链,P 1的m个数可以相同也可以不同。

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