公开(公告)号：JP2000197851A

公开(公告)日：2000-07-18

申请号：JP29799399

申请日：1999-10-20

Applicant: GEN ELECTRIC

Inventor： HARBLIN OWEN MAYNARD ,  CARROLL KENNETH MICHAEL

IPC: B05D5/00 ,  B05D5/08 ,  B05D7/14 ,  B05D7/16 ,  B05D7/24

Abstract: PROBLEM TO BE SOLVED: To restore the foul release effectiveness of a damaged foul release coating area on a metallic substrate by applying an adhesion promoter composition in the form of a specified two-part condensation curing silicone on the damaged foul release coating area on the metallic substrate of the shell of a ship and others. SOLUTION: Organisms such as barnacles, shellfishes, and algae are inclined to adhere to a metal structure immersed in seawater such as a ship bottom, and an antifouling coating is applied on a metallic substrate such as the ship bottom to prevent the adhesion. In restoring the foul release effectiveness of a damaged foul release coating area on the metallic substrate, the coating area is treated with an adhesion promoter composition in the form of a two-part condensation curing silicone RTV (room temperature curing) comprising a silanol-terminated polydiorganosiloxane and 0.5-5.5 wt.% of an aminoalkyltrialkoxysilane. After that, the composition is applied as a top coat.

公开(公告)号：DE69925233D1

公开(公告)日：2005-06-16

申请号：DE69925233

申请日：1999-10-12

Applicant: GEN ELECTRIC

Inventor： HARBLIN OWEN MAYNARD ,  CARROLL KENNETH MICHAEL

IPC: B05D5/00 ,  B05D5/08 ,  B05D7/14 ,  B05D7/16 ,  B05D7/24 ,  C09D5/16 ,  C09D183/04

Abstract: A method is provided for applying a two-part RTV silicone tie coat directly onto damaged foul release coating area on a metallic substrate to enable restoration procedures. The direct application onto aged epoxy or silicone surface of an effective amount of an aminoalkyltrialkoxysilane, such as gamma -aminopropyltrimethoxy-silane, in a two-part RTV silicone tie coat, has been found to provide cohesive failure results with directly applied two-part RTV silicone top coat. A treated metallic substrate is obtained thereby.

公开(公告)号：FR2549838B1

公开(公告)日：1987-05-29

申请号：FR8411883

申请日：1984-07-26

Applicant: GEN ELECTRIC

Inventor： WARD WILLIAM JESSUP III ,  RITZER ALAN ,  CARROLL KENNETH MICHAEL ,  FLOCK JOHN WILLIAM

IPC: B01J23/835 ,  B01J23/00 ,  B01J23/825 ,  B01J37/08 ,  C01B33/107 ,  C07B61/00 ,  C07F7/12 ,  C07F7/16

Abstract: A method is provided for making alkylhalosilanes by effecting reaction between an alkyl halide, such as methyl chloride and powdered silicon in the presence of a copper-zinc-tin catalyst. Significant improvements in reaction rate and product selectivity are achieved when copper is employed at a critical weight percent relative to silicon and critical weight ratios of tin and zinc are employed relative to copper.

公开(公告)号：FR2733761B1

公开(公告)日：2002-06-14

申请号：FR9602320

申请日：1996-02-26

Applicant: GEN ELECTRIC

Inventor： CARROLL KENNETH MICHAEL ,  HARBLIN OWEN MAYNARD ,  RUBINSZTAJN SLAWOMIR

IPC: B05D1/38 ,  B05D5/00 ,  B05D5/08 ,  B05D7/00 ,  B05D7/24 ,  B32B7/06 ,  C09D5/16 ,  C09D183/04

Abstract: A coated article for foul release for use in aquatic applications does not require a discrete tie-layer to ensure adhesion of a coating to a substrate. An adhesion promoting layer comprising an anticorrosive material and a bonding agent is applied directly to the substrate. A release layer comprising organopolysiloxane is deposited onto the adhesion promoting layer. A method for applying the foul release coating comprises the following steps: applying an adhesion promoting layer, curing the adhesion promoting layer, applying the release layer and curing the release layer.

公开(公告)号：AU3083784A

公开(公告)日：1985-01-31

申请号：AU3083784

申请日：1984-07-19

Applicant: GEN ELECTRIC

Inventor： WARD WILLIAM JESSUP ,  RITZER ALAN ,  CARROLL KENNETH MICHAEL ,  FLOCK JOHN WILLIAM

IPC: B01J23/835 ,  B01J23/00 ,  B01J23/825 ,  B01J37/08 ,  C01B33/107 ,  C07B61/00 ,  C07F7/12 ,  C07F7/16

Abstract: A method is provided for making alkylhalosilanes by effecting reaction between an alkyl halide, such as methyl chloride and powdered silicon in the presence of a copper-zinc-tin catalyst. Significant improvements in reaction rate and product selectivity are achieved when copper is employed at a critical weight percent relative to silicon and critical weight ratios of tin and zinc are employed relative to copper.

公开(公告)号：FR2733761A1

公开(公告)日：1996-11-08

申请号：FR9602320

申请日：1996-02-26

Applicant: GEN ELECTRIC

Inventor： CARROLL KENNETH MICHAEL ,  HARBLIN OWEN MAYNARD ,  RUBINSZTAJN SLAWOMIR

IPC: B05D1/38 ,  B05D5/00 ,  B05D5/08 ,  B05D7/00 ,  B05D7/24 ,  B32B7/06 ,  C09D5/16 ,  C09D183/04

Abstract: A coated article for foul release for use in aquatic applications does not require a discrete tie-layer to ensure adhesion of a coating to a substrate. An adhesion promoting layer comprising an anticorrosive material and a bonding agent is applied directly to the substrate. A release layer comprising organopolysiloxane is deposited onto the adhesion promoting layer. A method for applying the foul release coating comprises the following steps: applying an adhesion promoting layer, curing the adhesion promoting layer, applying the release layer and curing the release layer.

公开(公告)号：DE3425424C3

公开(公告)日：1995-05-18

申请号：DE3425424

申请日：1984-07-11

Applicant: GEN ELECTRIC

Inventor： WARD III WILLIAM JESSUP ,  RITZER ALAN ,  CARROLL KENNETH MICHAEL ,  FLOCK JOHN WILLIAM

IPC: B01J23/835 ,  C07F7/16

公开(公告)号：FR2549838A1

公开(公告)日：1985-02-01

申请号：FR8411883

申请日：1984-07-26

Applicant: GEN ELECTRIC

Inventor： WARD WILLIAM JESSUP III ,  RITZER ALAN ,  CARROLL KENNETH MICHAEL ,  FLOCK JOHN WILLIAM

IPC: B01J23/835 ,  B01J23/00 ,  B01J23/825 ,  B01J37/08 ,  C01B33/107 ,  C07B61/00 ,  C07F7/12 ,  C07F7/16

Abstract: A method is provided for making alkylhalosilanes by effecting reaction between an alkyl halide, such as methyl chloride and powdered silicon in the presence of a copper-zinc-tin catalyst. Significant improvements in reaction rate and product selectivity are achieved when copper is employed at a critical weight percent relative to silicon and critical weight ratios of tin and zinc are employed relative to copper.

公开(公告)号：DE19606966B4

公开(公告)日：2012-01-12

申请号：DE19606966

申请日：1996-02-24

Applicant: GEN ELECTRIC

Inventor： CARROLL KENNETH MICHAEL ,  HARBLIN OWEN MAYNARD ,  RUBINSZTAJN SLAWOMIR

IPC: B05D1/38 ,  C09D5/16 ,  B05D5/00 ,  B05D5/08 ,  B05D7/00 ,  B05D7/24 ,  B32B7/06 ,  C09D5/08 ,  C09D151/08 ,  C09D163/00 ,  C09D183/08

Abstract: Gegenstand zur Bewuchsverhinderung zum Einsatz in wässrigen Anwendungen, umfassend: a. ein Substrat, b. eine die Haftung fördernden Schicht, die auf das Substrat aufgebracht ist und c. eine Antihaftschicht, die in direktem Kontakt mit der die Haftung fördernden Schicht aufgebracht ist, worin die die Haftung fördernde Schicht ein antikorrosives Material und ein Bindemittel umfasst, dadurch gekennzeichnet, dass das antikorrosive Material ein epoxy-funktionelles Grundmaterial und einen Härtungs-Katalysator umfasst, das Bindemittel ein mittels Feuchtigkeit härtbares, gepfropftes Copolymer, das ein oder mehrere auf ein Polydialkylsiloxan gepfropfte ethylenisch ungesättigte Monomere umfasst, eine aminofunktionelle Polysiloxan-Flüssigkeit, oder eine α,ω-diaminofunktionelle Polysiloxan-Flüssigkeit ist, und die Antihaftschicht aus bis zu 20 Gew.-% eines mittels Feuchtigkeit härtbaren, gepfropften Copolymers und Organopolysiloxanzusammensetzung besteht.

公开(公告)号：DE3448237C2

公开(公告)日：1995-02-02

申请号：DE3448237

申请日：1984-07-11

Applicant: GEN ELECTRIC

Inventor： WARD III WILLIAM JESSUP ,  RITZER ALAN ,  CARROLL KENNETH MICHAEL ,  FLOCK JOHN WILLIAM

IPC: B01J23/835 ,  C07F7/12 ,  C07F7/16

Abstract: A copper/zinc/tin catalyst is made available. Significant improvements in the reaction rate during the preparation of alkyl- halosilanes by reaction between an alkyl halide and powdered silicon and in the product selectivity are achieved if copper is employed in the catalyst in a critical weight percentage relative to silicon and critical weight ratios of tin and zinc are used relative to copper.