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公开(公告)号:US3884866A
公开(公告)日:1975-05-20
申请号:US35110773
申请日:1973-04-13
Applicant: GEN ELECTRIC
Inventor: JERAM EDWARD M , STRIKER RICHARD A
CPC classification number: A61L27/44 , C08G77/02 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/70 , C08K5/0025 , C08K5/54 , C08L83/04 , C08L83/00 , C08L2666/28
Abstract: There is provided an organopolysiloxane composition combining high strength with exceptionally good elongation, which composition comprises a first component, a mixture of two vinylcontaining polysiloxanes or blends of vinyl-containing polysiloxanes, one of which is a high viscosity polysiloxane or a blend of high viscosity polysiloxanes, the other is a low viscosity polysiloxane or a blend of low viscosity vinylcontaining polysiloxanes, a filler and an effective amount of a platinum catalyst. The second component comprises a hydrogen-containing silane or polysiloxane. When it is desired to cure the composition into an elastomer the first component is mixed with the second component, that is, the hydrogen containing silane or polysiloxane and the mixture is allowed to cure either at room temperature or at elevated temperatures. Part of the total high viscosity vinylcontaining polymer can be mixed with the second component.
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公开(公告)号:JPH11323134A
公开(公告)日:1999-11-26
申请号:JP4245399
申请日:1999-02-22
Applicant: GEN ELECTRIC
Inventor: BURKUS II FRANK STEVEN , JERAM EDWARD M , RUBINSZTAJN SLAWOMIR
Abstract: PROBLEM TO BE SOLVED: To obtain a liq. injection moldable silicone elastomer compsn. which exhibits a low compression set, adhesiveness without using a primer, and easiness in peeling by compounding a silicone elastomer, a cationic org. nitrogen compd. salt, bis(trimethoxysilylpropyl) fumarate, and a specific silanol-terminated polymer so that the resulting elastomer compsn. has specified physical properties. SOLUTION: A silanol-terminated polymer represented by the formula (wherein RA , RA , RA , and RA are each a 1-40C org. group; RA is a 2-40C olefinic org. group; y is 0-50; and x is 0-100) is used. This polymer is soluble in the objective curable elastomer compsn., exhibits a lower solubility in the elastomer compsn. after cured than the solubility in the elastomer compsn. before cured, and hence contains a silicone oozing out of the elastomer compsn. after cured. Examples of the cation of the cationic org. nitrogen compd. are H, a monovalent cation bonded to an org. group, and a cation of a mono- or polycyclic heterocyclic compd.
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公开(公告)号:CA2061971A1
公开(公告)日:1992-09-28
申请号:CA2061971
申请日:1992-02-27
Applicant: GEN ELECTRIC
Inventor: EVANS EDWIN R , JERAM EDWARD M
Abstract: Docket No.: 60SI-1422 of the Invention Novel fluorosilicone hydrides are provided which are useful as intermediates in the preparation of epoxy-functional fluorosilicones having improved cure efficiency at low temperatures and improved resistance to solvents and fuels than analogous non fluoro-functional epoxy-functional silicones prepared from non fluoro-functional silicone hydrides.
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公开(公告)号:JP2002254427A
公开(公告)日:2002-09-11
申请号:JP2001386866
申请日:2001-12-20
Applicant: GEN ELECTRIC
Inventor: BOUDREAU BRUCE E , GROCELA-ROCHA TERESA , JERAM EDWARD M , LIERMANN AUGUST O , ROCHA-GALICIA GERARDO , DAVID A WILLIAMS
IPC: B29B7/44 , B29B7/48 , B29B7/74 , B29B7/84 , B29B7/88 , B29B11/14 , B29C47/40 , B29K19/00 , B29K105/16 , C08J3/20 , C08J3/22 , C08K3/36 , C08K5/54 , C08K9/06 , C08L83/07 , C08K5/541
Abstract: PROBLEM TO BE SOLVED: To provide a method for continuous manufacturing of a devolatilized liquid silicone rubber(LSR) composition from a polymer, a filler and an additive. SOLUTION: In the method for continuous manufacturing of the devolatilized LSR composition, the filler, a treating agent (16) and a silicone polymer are introduced into an extruder (22) having a length to diameter ratio of greater than 50 and the filler, the treating agent and the silicone elastomer are continuously compounded in the extruder (22) into a devolatilized LSR silicone composition. A system (40) for manufacturing the liquid silicone rubber composition comprises a mixer (18) to manufacture a concentrate of the filler and the silicone polymer, a continuous length extruder (22) having an L/D ratio of greater than 50, connected to the mixer to receive the concentrate from the mixer and to compound and devolatilize the concentrate, the treating agent and the silicone polymer into the devolatilized liquid silicone rubber composition and a cooler to receive the liquid silicone rubber composition and to cool, homogenize and further devolatilize the composition.
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公开(公告)号:JPH11246766A
公开(公告)日:1999-09-14
申请号:JP36364598
申请日:1998-12-22
Applicant: GEN ELECTRIC
Inventor: BURKUS II FRANK STEVEN , JERAM EDWARD M , RUBINSZTAJN SLAWOMIR
Abstract: PROBLEM TO BE SOLVED: To obtain a curable silicone elastomer composition which can give a cured product reduced in compression set by adding a salt of a cationic organonitrogen compound to a silicone composition suited for the production of a rollable rubber or pumpable liquid injection-moldable composition. SOLUTION: Desirably this composition contains (1) an alkenylorganopolysiloxane and (2) a hydrogen-containing silicon compound selected from the group consisting of hydrogen-containing silanes and hydrogen- containing organopolysiloxanes. The salt of the cationic organonitrogen compound is desirably, for example, a cation of a cycloaliphatic nitrogen-containing heterocyclic ring having the formula: (CH2-e Qe )f NRN g H2-g [wherein e is 0, 1, or 2; Q is a 1-40 monovalent organic group; f is an integer of 4 or greater; RN is a 1-40C monovalent organic group; and g is 0, 1, or 2].
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公开(公告)号:FR2707993A1
公开(公告)日:1995-01-27
申请号:FR9408271
申请日:1994-07-05
Applicant: GEN ELECTRIC
Inventor: MCDERMOTT PHILIP J , O'BRIEN MICHAEL J , JERAM EDWARD M
Abstract: Acetylenic maleates, fumarates and related derivative compounds are new compositions of matter having the formula: R1O2C-CH=CH-CO2R2 wherein R1 may be an organic moiety containing at least two carbon atoms triply bonded one to the other as: -C 3BOND C- and R2 may be hydrogen, an organic moiety, or R1; suitable for use as liquid injection molding inhibitors either singly or in combination with themselves or other liquid injection molding inhibitors when used for the process of liquid injection molding curable compositions enabling an increase in the size of articles manufactured therefrom, which new compositions of matter cure into the polymerizable or curable resins thereby creating new compositions of matter as cured resins from which said articles of manufacture are produced.
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公开(公告)号:CA2048776A1
公开(公告)日:1992-03-26
申请号:CA2048776
申请日:1991-08-08
Applicant: GEN ELECTRIC
Inventor: JERAM EDWARD M , WARD BRIAN J
Abstract: PATENTS 60SI-1336/MAM/0267m The present invention provides an improved heat curable silicone composition, having increased tear strength, oil resistance, and reduced compression set, comprising (A) a blend containing (1) a vinyl-containing organopolysiloxane or vinyl-containing organopolysiloxane blend having a viscosity of about 5,000 to about 500,000 centipoise at 25.degree.C, and (2) a vinyl-containing organopolysiloxane or vinyl-containing organopolysiloxane blend having a viscosity of about 8,000,000 to about 100,000,000 centipoise at 25.degree.C; (B) an organopolysiloxane resin copolymer; (C) an organic peroxide catalyst; (D) a filler; and (E) an organohydrogenpolysiloxane.
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公开(公告)号:JPH11246765A
公开(公告)日:1999-09-14
申请号:JP36364498
申请日:1998-12-22
Applicant: GEN ELECTRIC
Inventor: BURKUS II FRANK STEVEN , JERAM EDWARD M , RUBINSZTAJN SLAWOMIR
IPC: C08K5/19 , C08K5/3432 , C08K5/5419 , C08K5/5425 , C08L83/04 , C08L83/05 , C08L83/07 , C08K5/54
Abstract: PROBLEM TO BE SOLVED: To obtain a silicone elastomer which can give a cured product reduced in compression set by adding a salt of a cationic organonitrogen compound to a silicone composition suited for the production of a liquid injection-moldable composition. SOLUTION: This composition contains the following four components: (1) a silicone elastomer, (2) a salt of a cationic organonitrogen compound, (3) bis(trimethoxysilylpropyl) fumarate, and (4) a silanol-terminated polymer represented by the formula (wherein RA , RA , RA , and RA are each independently a 1-40C monovalent organic group; RA is a 2-40C monovalent olefinic organic group; y' is 0 to about 50; x' is 0 or 1 to about 100; and the alkenyl content ranges from 0 in the case of y'=0 to about 25 wt.%, in the case of y'>0). When this composition is bonded to a substrate comprising a thermosetting polymer or a thermoplastic polymer, components (3) and (4) function as an adhesion promoter system.
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公开(公告)号:JPH11246764A
公开(公告)日:1999-09-14
申请号:JP36364398
申请日:1998-12-22
Applicant: GEN ELECTRIC
Inventor: BURKUS II FRANK STEVEN , JERAM EDWARD M , RUBINSZTAJN SLAWOMIR
IPC: C08K5/17 , C08K5/19 , C08K5/3432 , C08K5/5419 , C08L83/04 , C08L83/05 , C08L83/07 , C08K5/54
Abstract: PROBLEM TO BE SOLVED: To obtain a silicone elastomer composition which can give a cured product reduced in compression set by adding a salt of a cationic organonitrogen compound to a silicone composition suited for the production of a rollable rubber or pumpable liquid injection-moldable composition. SOLUTION: Desirably, the curable silicone elastomer used in the curable silicone elastomer composition contains a hydrogen-containing silicon compound selected from the group consisting of (1) alkenylorganopolysiloxanes and (2) hydrogen-containing silanes and hydrogen-containing organopolysiloxanes. The salt of the cationic organonitrogen compound is desirably, for example, a nitrogen compound containing a monovalent cation having the following formula: RN a RN b RN c RN d N (wherein RN is selected from the group consisting of hydrogen and 1-40C monovalent organic groups; RN to RN are each independently selected from the group consisting of 1-40C monovalent organic groups; a is 0-3; b, c, and d are each independently 0-4; and the sum of a to d is always 4).
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公开(公告)号:JPH07178757A
公开(公告)日:1995-07-18
申请号:JP16851794
申请日:1994-07-21
Applicant: GEN ELECTRIC
Inventor: MCDERMOTT PHILIP J , O'BRIEN MICHAEL J , JERAM EDWARD M
Abstract: PURPOSE: To enhance hardness and tear strength and to prevent the adverse effect on other physical properties by using a compd. represented by a predetermined formula as a precure inhibitor of an injection molding compsn. CONSTITUTION: As a precure inhibitor of an injection molding compsn., a compd. represented by formula I (wherein R1 can become an org. group containing at least two carbon atoms mutually bonded by a triple bond and R2 is hydrogen or an org. group or can be R1 ) is used. These acetylenic maleate and fumarate and a related deriv. compd. are used alone or combined mutually or combined with other liquid injection molding inhibitor to be used in the liquid injection molding of a curable compsn.
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