POLYURETHANE PREPOLYMERS BASED ON OLEOCHEMICAL POLYOLS

    公开(公告)号:AU7635587A

    公开(公告)日:1988-02-04

    申请号:AU7635587

    申请日:1987-07-31

    Applicant: HENKEL KGAA

    Abstract: The invention relates to isocyanate-terminated polyurethane prepolymers containing a stoichiometric excess of an isocyanate component comprised of one or more aromatic isocyanates containing on average from 2 to 4 isocyanate groups per molecule and a polyol component comprised of an oleochemical polyol prepared by epoxidation of a triglyceride containing olefinic unsaturation and subsequent ring opening with an alcohol. In use, accelerators, flameproofing agents, blowing agents and, optionally, liquefying agents, dyes and/or stabilizers, are included. The oleochemical polyol does not contain any free epoxide groups and is obtained by complete ring opening of epoxidized triglycerides of a fatty acid mixture containing at least partly olefinically unsaturated fatty acids with one or more C1-C12 alcohols and partial conversion by alcoholysis or transesterification of the triglyceride derivatives to alkyl ester polyols containing from 1 to 12 carbon atoms in the alkyl radical. A process for the production of these polyurethane prepolymers and to their use as starting materials for the production of polyurethane foams is included.

    7.
    发明专利
    未知

    公开(公告)号:ES2120186T5

    公开(公告)日:2004-11-16

    申请号:ES95910491

    申请日:1995-02-16

    Applicant: HENKEL KGAA

    Abstract: A composition useful for the production of foam plastics from disposable pressurized containers is provided. The composition comprises at least one polyisocyanate or isocyanate prepolymer, at least one catalyst for the reaction of the isocyanate group with the OH group, at least one blowing agent and at least one foam stabilizer. One day at the latest after application from said disposable pressurized container, the residue of said composition left in the pressurized container has a diisocyanate monomer content of less than 5.0% by weight, based on the residual contents of the emptied container.

    10.
    发明专利
    未知

    公开(公告)号:ES2147390T3

    公开(公告)日:2000-09-01

    申请号:ES96927647

    申请日:1996-08-01

    Applicant: HENKEL KGAA

    Abstract: Described is an NCO-group-containing polyurethane prepolymer madefrom polyisocanyates and polyols derived from natural oils. The invention is characterized in that the polyol is obtained by transesterification in the presence of basic lithium compounds. Together with a tertiary amine used to accelerate the moisture curing, the storage stability is thus increased considerably. Up to 4.0 mmol of the lithium compound is used per kilogram of polyol, and 0.1 to 2.0% by wt. of the amine, relative to the total weight of the composition, is used as the accelerator. The polyurethane prepolymer is suitable not only for the production of adhesives but also for the production of foamed materials, in particular those dispensed from throw-away pressure vessels.

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