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公开(公告)号:JPH05190918A
公开(公告)日:1993-07-30
申请号:JP15700992
申请日:1992-06-16
Applicant: HOECHST AG
Inventor: PREISLER EBERHARD , BOCK JOACHIM
Abstract: PURPOSE: To provide a resistive current limiter suitable for the frequent appearance of short-circuit currents by forming the limiter by a high temperature superconductive material as a hollow cylinder. CONSTITUTION: A uniform melt is formed from a stoichiometric oxide mixture and a melt having temperature >900 deg.C is allowed to flow into a rotating casting band. A compact solidified as a cylindrical body is extracted and cut off from a gap 5 formed so as to be extended in parallel with the axis of the cylindrical body and plural slits 1 is cut off in parallel with the gap 5. Finally the cylindrical body is heated at 700 to 900 deg.C in oxygen containing atmosphere for 150 hours to manufacture a hollow cylinder. The hollow cylinder is conductively connected to a current leading-in conductor 3 within a range between the gap 5 and the slit 1 existing just on the right side of the gap 5 and connected to a current leading-out conductor 4 within a range between the gap 5 and the slit 1 existing just on the left side of the conductor 5.
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公开(公告)号:JPH05194018A
公开(公告)日:1993-08-03
申请号:JP19877392
申请日:1992-07-24
Applicant: HOECHST AG
Inventor: BOCK JOACHIM , PREISLER EBERHARD
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公开(公告)号:CA2096899C
公开(公告)日:1998-09-22
申请号:CA2096899
申请日:1993-05-25
Applicant: HOECHST AG
Inventor: BOCK JOACHIM , PREISLER EBERHARD
IPC: C01G1/00 , C01G3/00 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , H01B12/00 , H01B13/00 , H01L39/24
Abstract: In a process for producing a high-temperature superconductor and moldings formed therefrom, comprising oxides of bismuth, strontium, calcium, copper and optionally of lead as well as sulfates of strontium and/or barium, the oxides of bismuth, strontium, calcium, copper and optionally of lead in the desired molar ratio, as well as additionally from 2 to 30% by weight of strontium sulfate and/or from 1 to 20% by weight of barium sulfate, each calculated according to the mixture of the oxides, are mixed intimately, the mixture is melted in a crucible of a platinum metal at temperatures from 870 to 1600.degree.C, the melt is poured into permanent molds of desired form and size and is allowed to solidify slowly therein, and the moldings produced are freed from the permanent mold material and are annealed for from 6 to 200 hours at temperatures from 700 to 900.degree.C in an oxygen-containing atmosphere.
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公开(公告)号:GR3019162T3
公开(公告)日:1996-05-31
申请号:GR960400494
申请日:1996-02-29
Applicant: HOECHST AG
Inventor: PREISLER EBERHARD , BOCK JOACHIM
Abstract: A resistive current limiter takes the form of a hollow cylinder and is composed of high-temperature superconducting material. In this connection, the high-temperature superconducting material may be a polynary oxide. To produce said resistive current limiter, a homogeneous melt is prepared from an oxide mixture, suitable for forming high-temperature superconductors, in a specified stoichiometry and said melt is allowed to run, at temperatures above 900 DEG C., into a casting zone which rotates about its horizontal axis. The molding, solidified as a cylinder, is removed from the casting zone. The cylinder is sawn so as to produce a gap extending parallel to its axis. Furthermore, a multiplicity of slits are sawn into the cylinder parallel to the gap. Finally, the cylinder is heat-treated for up to 150 hours at 700 DEG to 900 DEG C. in an oxygen-containing atmosphere.
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公开(公告)号:ES2080991T3
公开(公告)日:1996-02-16
申请号:ES92110538
申请日:1992-06-23
Applicant: HOECHST AG
Inventor: BOCK JOACHIM , PREISLER EBERHARD
Abstract: The invention relates to a high-temperature superconductor composed of the oxides of bismuth, strontium, calcium and copper and, optionally, of lead, and having the composition Bi2-a+b+c Pba (Sr, Ca)3-b-c Cu2+d Ox, where a=0 to 0.7; b+c=0 to 0.5; d=-0.1 to 0.1 and x=7 to 10 and a Sr:Ca ratio of 2.8:1 to 1:2.8 as well as of strontium and/or barium sulfates. Said superconductor can be prepared by intimately mixing the oxides of bismuth, strontium, calcium and copper and optionally of lead with strontium and/or barium sulfates, melting the mixture by heating to temperatures of 870 to 1300 degrees C., higher temperatures being required for higher strontium and/or barium sulfate contents, pouring the melt into molds and allowing it to solidify slowly therein and subjecting the moldings removed from the molds to a heat treatment at temperatures of 700 to 900 degrees C. in an oxygen-containing atmosphere.
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公开(公告)号:CA2131944A1
公开(公告)日:1995-04-05
申请号:CA2131944
申请日:1994-09-13
Applicant: HOECHST AG
Inventor: BOCK JOACHIM , ELSCHNER STEFFEN
Abstract: Solid parts made of high-temperature superconductor material Solid parts made of high-temperature superconductor material are composed of the oxides of bismuth, strontium, calcium and copper and of the sulfates of strontium and/or barium. These solid parts have an enhanced current-carrying capacity which is caused by a preferential orientation of the crystallites, the crystallographic c axis being perpendicular to the temperature gradient during their solidification from the melt. In order to produce said solid parts, a homogeneous melt of the oxides of bismuth, strontium, calcium and copper and of the sulfates of strontium and/or barium is cast, at temperatures of from 900 to 1300.degree.C, in permanent mods, the melt is allowed to solidify therein slowly, and the solid parts taken from the permanent molds are then annealed in an oxygen-containing atmosphere at from 700 to 900.degree.C. In the process, the homogeneous melt is cast in permanent molds having at least two parallel walls, as a result of which there is produced in the solid parts, both after their solidification and after they have been annealed, a crystallographic preferential orientation of the crystallites.
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公开(公告)号:CA2073522A1
公开(公告)日:1993-01-27
申请号:CA2073522
申请日:1992-07-09
Applicant: HOECHST AG
Inventor: BOCK JOACHIM , PREISLER EBERHARD
IPC: C01G1/00 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , H01B12/00 , H01B13/00 , H01L39/24 , H01L39/12
Abstract: The invention relates to a high-temperature superconductor composed of the oxides of bismuth, strontium, calcium and copper and, optionally, of lead, and having the composition Bi2-a+b+c Pba (Sr, Ca)3-b-c Cu2+d Ox, where a=0 to 0.7; b+c=0 to 0.5; d=-0.1 to 0.1 and x=7 to 10 and a Sr:Ca ratio of 2.8:1 to 1:2.8 as well as of strontium and/or barium sulfates. Said superconductor can be prepared by intimately mixing the oxides of bismuth, strontium, calcium and copper and optionally of lead with strontium and/or barium sulfates, melting the mixture by heating to temperatures of 870 to 1300 degrees C., higher temperatures being required for higher strontium and/or barium sulfate contents, pouring the melt into molds and allowing it to solidify slowly therein and subjecting the moldings removed from the molds to a heat treatment at temperatures of 700 to 900 degrees C. in an oxygen-containing atmosphere.
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8.
公开(公告)号:CA2048323A1
公开(公告)日:1992-02-18
申请号:CA2048323
申请日:1991-08-01
Applicant: HOECHST AG
Inventor: PREISLER EBERHARD , BOCK JOACHIM
IPC: C01G1/00 , B22D29/00 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , C04B41/91 , C23F1/18 , H01L39/24 , C04B41/53
Abstract: HOE 90/H 023 Process for producing molded bodies from precursors of oxidic high-temperature superconductors of the disclosure: In the process for producing molded bodies from precursors of oxidic high-temperature superconductors of the BSCCO type, a copper mold of the desired shape which encloses a solidified bismuth strontium calcium cuprate melt is treated with a solution of a soluble compound containing sulfate anions, an aqueous mineral acid and an oxidizing agent until the copper mold is dissolved.
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9.
公开(公告)号:CA2048144A1
公开(公告)日:1992-02-18
申请号:CA2048144
申请日:1991-07-30
Applicant: HOECHST AG
Inventor: PREISLER EBERHARD , BOCK JOACHIM
IPC: C01G1/00 , B28B7/34 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , H01B12/00 , H01B13/00 , H01L39/24 , H01L39/00
Abstract: HOE 90/H 025 Process for producing molded bodies from precursors of high-temperature superconductors of the disclosure: To produce more complex molded bodies from precursors of high-temperature superconductors based on the oxides of bismuth, strontium, calcium and copper, the homogeneous melt of these oxides is cast in molds at temperatures of 870 to 1000.degree.C. In this process, the geometrically appropriately shaped molds are composed of a material having a melting point of at least 1000.degree.C. Finally, the molds containing solidified melt of the oxides of bismuth, strontium, calcium and copper are treated with dilute hydrofluoric acid at temperatures of 20 to 90.degree.C until the molds are dissolved.
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10.
公开(公告)号:CA2048011A1
公开(公告)日:1992-02-18
申请号:CA2048011
申请日:1991-07-26
Applicant: HOECHST AG
Inventor: PREISLER EBERHARD , BOCK JOACHIM
IPC: C01G1/00 , B22D29/00 , C01G29/00 , C04B35/00 , C04B35/45 , C04B35/653 , C25F3/02 , C25F5/00 , H01B12/00 , H01B13/00 , H01L39/24
Abstract: HOE 90/H 024 Process for producing molded bodies from precursors of oxidic high-temperature superconductors of the disclosure: In the process for producing molded bodies from precursors of oxidic high-temperature superconductors of the BSCCO type, a copper mold of the desired shape which encloses a solidified bismuth strontium calcium cuprate melt is wired as anode in a direct current circuit composed of anode, cathode and an electrolyte, a dilute sulfuric acid is used as electrolyte and the electrolyte is subjected to a direct current of 1 to 50 mA?cm-2 until the copper mold wired as anode is dissolved and the BSCCO molded body is laid bare.
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