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    5.
    发明专利
    未知

    公开(公告)号：DE3230528A1

    公开(公告)日：1983-09-15

    申请号：DE3230528

    申请日：1982-08-17

    Applicant: HOECHST AG

    Inventor： BLICKLE PETER DR ,  BRANDRUP JOHANNES DR ,  MILLAUER HANS DR ,  SCHWERTFEGER WERNER DR ,  SIEGEMUND GUENTER DR

    IPC: C08F8/12 ,  C08F14/18 ,  C08F20/04 ,  C08F214/26 ,  C08F8/38 ,  C08J5/22 ,  C25B13/08 ,  C25B1/46

    Abstract: Substantially non-crosslinked fluorocarbon polymers containing carboxyl groups are prepared starting from non-crosslinked and in some cases new, fluorocarbon polymers in which the linear macromolecules carry side chains containing the end group -CHFX (X is F or CF3). The starting polymers are first reacted with peroxodisulfuryl difluoride FSO2O-OSO2F to give the corresponding fluorosulfato derivatives containing the side chain end groups. (X is F or CF3). In the event that X is F, these derivaties are then converted into the corresponding carboalkoxy derivatives by means of an alcohol, the fluorosulfato group being split off, and these carboalkoxy derivatives are then converted by saponification into the products containing the free carboxyl groups; the fluorosulfato derivatives can also be hydrolyzed with water, if appropriate in the presence of an inert solvent and/or bases, to give, without further treatment, the products containing the free carboxyl groups. The fluorosulfato derivatives in which X is CF3 in the side chain end groups are first decomposed in the presence of catalytic amounts of alkali metal fluorides and/or aprotic nitrogen bases to give the products containing the side chain end groups and the latter are then hydrolyzed to give the products containing the free carboxyl group. Virtually non-crosslinked fluorocarbon polymers containing carboxyl groups are of industrial importance in the form of cation exchanger membranes in electrolytic cells, particularly in chlor-alkali electrolysis.

    6.
    发明专利
    未知

    公开(公告)号：DE1720630A1

    公开(公告)日：1971-07-01

    申请号：DE1720630

    申请日：1967-03-10

    Applicant: HOECHST AG

    Inventor： BRANDRUP JOHANNES DR ,  SOMMER SIEGFRIED DR

    IPC: C08F2/08 ,  C08F210/00 ,  C08F15/04

    Abstract: 1,161,731. Copolymerizing olefins. FARBWERKE HOECHST A.G. 11 March, 1968 [10 March, 1967], No. 11760/68. Heading C3P. Copolymers of ethylene, an alpha-olefin of the formula R-CH=CH 2 , where R is an aliphatic branch or straight-chain hydrocarbon radical containing less than seven carbon atoms, and optionally a hydrocarbon with two non- conjugated double bonds in an amount such that the polymer obtained has an iodine number of at most 50, are made by copolymerizing the monomers in the presence of (1) as dispersion medium an aliphatic halohydrocarbon which does not dissolve the copolymer under the reaction conditions, (2) a catalyst comprising a vanadium compound and an organoaluminium compound both soluble in the dispersion medium and (3) 0.0001% to 10% by weight, calculated on the dispersion medium, of a finely divided inert solid organic polymer of particle size 0-005 to 300 microns which does not inhibit the catalyst activity, and is insoluble in the dispersion medium and in the precipitating polymer. The copolymerization is carried out at a pressure of 1 to 30 atmospheres, a temperature in the range of - 30‹ C. and +50‹ C., with stirring or mechanical agitation. Specified organic polymers are polyethylene, polypropylene, polybutene-1, poly-3-methylbutene-1, polypentene-1, poly - 4 - methylpentene - 1, polymers of C10 to C24 olefins, copolymers of the above olefins, polyacrylonitrile, polyvinyl chloride, polyethylene glycol terephthalate, polycaprolactam, polyvinyl fluoride, polytetrafluoroethylene, polyvinylidene fluoride, condensation products of formaldehyde with phenols or amines, and pulverized coconut shells. Suitable dispersing media are 1,2-dichloropropane, 1,2,2 - trichloro - 1,1,2 - trifluoroethane, ethylene chloride, 1,2 - dichloroethane and methylene chloride. The optional third component may be 1,4-cis-hexadiene, 1,4-transhexadiene, alkenyl-norbornenes, alkylidene-norbornenes, and dicyclopentadiene. In the examples are copolymerized ethylene and propylene, ethylene, propylene and methylbutenyl norbornene, and ethylene, propylene and 1,4- cis-hexadiene.

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