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公开(公告)号:DE4108871A1
公开(公告)日:1992-09-24
申请号:DE4108871
申请日:1991-03-19
Applicant: HOECHST AG , SCHERING AGROCHEMICALS LTD
Inventor: DAMO ZOLTAN DR , FAERS MALCOLM
Abstract: The invention provides liquid formulation, which comprises 0.1 to 75% by weight of prochloraz, at least 3% by weight of a nonionic surfactant or surfactant mixture, at least 8.5% by weight of a phenol derivative to prevent crystallisation of the prochloraz on storage of the emulsion, said phenol being a compound of formula R -O-X in which R is phenyl, substituted by one to three C1-C8-alkyl, alpha -methylbenzyl or alpha -methyl-4-methylbenzyl groups, by 4-hydroxyphenylene in the para-position, a C6-C22-alkyl group in the para-position or by two C3-C12-alkyl groups in the ortho and para-positions, and X is hydrogen, an alkali metal, an alkaline earth metal or NR3 in which each R is the same or different and is hydrogen or C1-C8-alkyl, optionally substituted by hydroxy, and at least 1% by weight of an organic solvent which is only slightly soluble in water and which comprises at least one aromatic hydrocarbon.
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公开(公告)号:DE3707711A1
公开(公告)日:1988-09-22
申请号:DE3707711
申请日:1987-03-11
Applicant: HOECHST AG , BAYER AG
Inventor: DAMO ZOLTAN DR , FRISCH GERHARD DR , ROECHLING HANS DR , NIESSEN HEINZ-JOSEF DR , WIRTH WOLFGANG DR
IPC: A01N25/04 , A61K9/107 , B01J13/00 , C09K23/00 , C09K23/12 , C09K23/22 , C09K23/26 , C09K23/42 , B01F17/42 , B01F17/12 , B01F17/02 , B01F17/26 , B01F17/22 , C05G3/00 , A61K9/10
Abstract: Oil-in-water emulsions (microemulsions) which contain 0.01 - 80% by weight of at least one agrochemical active substance which is sparingly soluble in water, an active substance for combating pests in the domestic and hygiene sector, and/or a pharmacologically active ingredient, 1 to 30% by weight of an emulsifier mixture of non-ionic and anionic compounds and at least one salt of an alkylarylsulphonic acid as defined in the description, and water, and, if appropriate, 1 to 30% by weight of at least one organic solvent which is sparingly miscible with water and/or of a solubiliser, and, if appropriate, 0.05 to 15% by weight of additives, where the total of the components is in each case 100% by weight, a process for the preparation of these aqueous microemulsions, and their use.
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公开(公告)号:CH614462A5
公开(公告)日:1979-11-30
申请号:CH988275
申请日:1975-07-29
Applicant: HOECHST AG
Inventor: HOHLFELD GUENTHER , DAMO ZOLTAN DR , VOETZ FRANZ , KOLLER OTTO
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公开(公告)号:ES2064484T3
公开(公告)日:1995-02-01
申请号:ES89810631
申请日:1989-08-24
Applicant: HOECHST AG
Inventor: DAMO ZOLTAN DR , NEUENSCHWANDER ERNST DR
Abstract: The invention relates to novel aqueous formulations containing 1 to 70 % by weight of an agrochemical active compound which is poorly soluble in water in addition to an amount of a compound inhibiting the crystallisation of the active substance or a breaking of the emulsion, of the formula I R-O-M (I> in which R denotes C12-C20-alkyl; C12-C20-alkenyl; phenyl; 4-biphenylyl; phenyl which is disubstituted to trisubstituted by alpha -methylbenzyl or alpha -methyl-4-methylbenzyl; or phenyl which is monosubstituted to trisubstituted by alkyl, where the sum of the carbon atoms present in the alkyl groups is 1 to 18; and M is hydrogen; a cation equivalent of an alkali metal or alkaline earth metal ion, or if R is phenyl, 4-biphenylyl or phenyl which is substituted by alpha -methylbenzyl, alpha -methyl-4-methylbenzyl or alkyl can also stand for ammonium, mono- or di-ethanolammonium; and, if desired, other formulation auxiliaries and/or other agrochemical active compounds, and their use as seed dressings.
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公开(公告)号:DE2504136A1
公开(公告)日:1976-08-05
申请号:DE2504136
申请日:1975-01-31
Applicant: HOECHST AG
Inventor: DAMO ZOLTAN DR , SCHMIDT MANFRED DR , STENGER WILHELM DR
Abstract: 1532506 Emulsion concentrates of waterinsoluble biocides HOECHST AG 29 Jan 1976 [31 Jan 1975] 03511/76 Heading A5E An emulsion concentrate of a water-insoluble organic biocide which is sensitive to hydrolysis in an organic non-polar solvent which is free from hydroxyl groups, contains an anionic emulsifier and optionally an ionic emulsifier, and has as viscosity reducing agent a compound of formula: in which each of R 1 and R 2 is an alkyl group having from 1 to 4 carbon atoms, an alkylcarbonyl group having from 2 to 4 carbon atoms or a carbamoyl group having from 1 to 4 carbon atoms, X is an alkylene group having from 2 to 4 carbon atoms and n is in the range of from 1 to 20. The biocide may be a phosphoric or thiophosphoric acid ester and the solvent may be benzene, toluene, xylene or kerosine. Viscosity reducing agents used are ethylene glycol dimethyl and diethyl ethers; di-, tri- and tetra-ethylene glycol dimethyl ethers; diethylene glycol dibutyl ether; methyl-tetraglycol t-butyl ether; methyl glycolbutyl glycol-, and methyldiglycol-acetates; glycol diacetate; ethyl glycol- and methyldiglycolmethylurethanes; propanediol- and butanedioldiacetates; and butanediol dimethylurethane.
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公开(公告)号:DE4343857A1
公开(公告)日:1995-06-29
申请号:DE4343857
申请日:1993-12-22
Applicant: HOECHST AG
Inventor: FRISCH GERHARD DR , DAMO ZOLTAN DR
IPC: A01N25/04 , A01N25/30 , A01N47/10 , A01N57/10 , C05G5/00 , B01J13/00 , B01F17/00 , A61K31/66 , A61K9/113
Abstract: PCT No. PCT/EP94/04142 Sec. 371 Date Sep. 5, 1996 Sec. 102(e) Date Sep. 5, 1996 PCT Filed Dec. 14, 1994 PCT Pub. No. WO95/17088 PCT Pub. Date Jun. 29, 1995The present invention relates to oil-in-water emulsions containing 0.001 to 70% by weight of at least one active substance from the group consisting of phosphates, thiophosphates and/or carbamates, 0.001 to 30% by weight of one or more surfactant compounds from the group consisting of ethoxylated fatty amines or of phosphorylated fatty amine ethoxylates, and also, if desired, adjuvants and water to make up 100% by weight.
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公开(公告)号:DE4343856A1
公开(公告)日:1995-06-29
申请号:DE4343856
申请日:1993-12-22
Applicant: HOECHST AG
Inventor: FRISCH GERHARD DR , DAMO ZOLTAN DR
IPC: A01N25/04 , A01N25/30 , A01N47/10 , A01N57/10 , C05G5/00 , B01J13/00 , B01F17/00 , A61K31/66 , A61K9/113
Abstract: PCT No. PCT/EP94/04141 Sec. 371 Date Aug. 29, 1996 Sec. 102(e) Date Aug. 29, 1996 PCT Filed Dec. 14, 1994 PCT Pub. No. WO95/17087 PCT Pub. Date Jun. 29, 1995The present invention relates to oil-in-water emulsions containing 0.001-70% by weight of at least one active substance from the group consisting of phosphates, thiophosphates and/or carbamates, 0.001-30% by weight of one or more surfactant compounds from the group consisting of nonionic surfactant compounds or phosphorylated surfactant compounds or sulfated surfactant compounds or sulfonated surfactant compounds, and also, if desired, adjuvants, and, water to make up 100% by weight.
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公开(公告)号:AT112933T
公开(公告)日:1994-11-15
申请号:AT89810631
申请日:1989-08-24
Applicant: HOECHST AG
Inventor: DAMO ZOLTAN DR , NEUENSCHWANDER ERNST DR
Abstract: The invention relates to novel aqueous formulations containing 1 to 70 % by weight of an agrochemical active compound which is poorly soluble in water in addition to an amount of a compound inhibiting the crystallisation of the active substance or a breaking of the emulsion, of the formula I R-O-M (I> in which R denotes C12-C20-alkyl; C12-C20-alkenyl; phenyl; 4-biphenylyl; phenyl which is disubstituted to trisubstituted by alpha -methylbenzyl or alpha -methyl-4-methylbenzyl; or phenyl which is monosubstituted to trisubstituted by alkyl, where the sum of the carbon atoms present in the alkyl groups is 1 to 18; and M is hydrogen; a cation equivalent of an alkali metal or alkaline earth metal ion, or if R is phenyl, 4-biphenylyl or phenyl which is substituted by alpha -methylbenzyl, alpha -methyl-4-methylbenzyl or alkyl can also stand for ammonium, mono- or di-ethanolammonium; and, if desired, other formulation auxiliaries and/or other agrochemical active compounds, and their use as seed dressings.
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公开(公告)号:DE58908525D1
公开(公告)日:1994-11-24
申请号:DE58908525
申请日:1989-08-24
Applicant: HOECHST AG
Inventor: DAMO ZOLTAN DR , NEUENSCHWANDER ERNST DR
Abstract: The invention relates to novel aqueous formulations containing 1 to 70 % by weight of an agrochemical active compound which is poorly soluble in water in addition to an amount of a compound inhibiting the crystallisation of the active substance or a breaking of the emulsion, of the formula I R-O-M (I> in which R denotes C12-C20-alkyl; C12-C20-alkenyl; phenyl; 4-biphenylyl; phenyl which is disubstituted to trisubstituted by alpha -methylbenzyl or alpha -methyl-4-methylbenzyl; or phenyl which is monosubstituted to trisubstituted by alkyl, where the sum of the carbon atoms present in the alkyl groups is 1 to 18; and M is hydrogen; a cation equivalent of an alkali metal or alkaline earth metal ion, or if R is phenyl, 4-biphenylyl or phenyl which is substituted by alpha -methylbenzyl, alpha -methyl-4-methylbenzyl or alkyl can also stand for ammonium, mono- or di-ethanolammonium; and, if desired, other formulation auxiliaries and/or other agrochemical active compounds, and their use as seed dressings.
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公开(公告)号:DE3542441A1
公开(公告)日:1987-06-04
申请号:DE3542441
申请日:1985-11-30
Applicant: HOECHST AG
Inventor: MENGLER HELMUT DR , GRABLEY FRITZ-FEO DR , CUNTZE ULRICH DR , DAMO ZOLTAN DR
Abstract: Bisphosphoric acid monoesters of alkylene oxide block polymers of the formula in which x and z are identical and are numbers from 2 to 200, and y is a number from 2 to 200, and salts thereof are prepared by phosphating the parent block polymer. They are suitable as auxiliaries for the preparation of crop-protection agent formulations.
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