公开(公告)号：CA2104318A1

公开(公告)日：1994-02-20

申请号：CA2104318

申请日：1993-08-18

Applicant: HOECHST AG

Inventor： FALK UWE ,  HICKEL WERNER ,  LUPO DONALD ,  SCHEUNEMANN UDE

IPC: B32B7/02 ,  B05D1/20 ,  B32B23/04 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  C03C17/34 ,  G02B6/12 ,  G02F1/39

Abstract: Layer element and use thereof A layer element comprises a plurality of monomolecular layers in a regular and alternating arrangement ABABAB... on a substrate, wherein A is a layer of a dye whose chromophore has a donor-acceptor structure and B is a layer of cellulose whose hydroxyl groups are at least partly substituted by the radical where R1 and R2 are each independently of the other an alkyl radical of from 1 to 4 carbon atoms and R3 is an alkyl radical of from 1 to 18 carbon atoms or phenyl, tolyl or benzyl. It is useful for nonlinear optics.

公开(公告)号：FI934715A

公开(公告)日：1994-04-28

申请号：FI934715

申请日：1993-10-25

Applicant: HOECHST AG

Inventor： CABRERA IVAN ,  FALK UWE ,  HICKEL WERNER ,  LUPO DONALD ,  MAYER ANDREAS ,  PAWLOWSKI GEORG ,  SCHEUNEMANN UDE

IPC: B32B7/02 ,  C08J5/18 ,  C08L101/00 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  C08F20/02 ,  C08F8/14 ,  B05D1/20 ,  C07C315/04 ,  C07B37/00

Abstract: An optical component (100) contains a polymeric medium, which is transparent to electromagnetic radiation and has a second-order susceptibility of at least 10 electrostatic units. This polymeric medium contains compounds having polar-aligned, non-centrosymmetric molecular dipoles which have as a structural element an electron acceptor which is bound to an electron donor via a conjugate pi electron system. As a result, the molar dipole can oscillate between a basic state having a first dipole moment and an electronically excited state having a second dipole moment, differing from the first. The optical component is characterised in that the polymeric medium consists alternately of at least in each case one Langmuir-Blodgett film of at least two polymers having different, non-ionic, nonlinear optical properties (103). In addition to a high mechanical and chemical stability, the optical component according to the invention exhibits excellent nonlinear optical properties, e.g. frequency doubling.

公开(公告)号：CA2109243A1

公开(公告)日：1994-04-28

申请号：CA2109243

申请日：1993-10-26

Applicant: HOECHST AG

Inventor： CABRERA IVAN ,  FALK UWE ,  HICKEL WERNER ,  LUPO DONALD ,  MAYER ANDREAS ,  PAWLOWSKI GEORG ,  SCHEUNEMANN UDE

IPC: B32B7/02 ,  C08J5/18 ,  C08L101/00 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  C07C317/32 ,  C07D309/12 ,  C07D409/12 ,  C07C317/22 ,  C07D333/36 ,  G02F1/37 ,  C07D317/56 ,  C07C323/65 ,  C07D209/86

Abstract: Optical component based on Langmuir-Blodgett layers An optical component comprises an electromagnetic radiation-transparent polymeric medium having a secondorder susceptibility of at least 10-9 electrostatic units where this polymeric medium comprises compounds having polar-aligned noncentrosymmetric molecular dipoles which have as structural element an electron acceptor which is bound to an electron donor via a conjugated .pi.-electron system, which makes possible an oscillation of the molecular dipole between a ground state having a first dipole moment and an electronically excited state having a second dipole moment different from the first, and the nonionic polymeric medium comprises an alternating arrangement of at least one Langmuir-Blodgett film each of at least two different nonionic polymers having nonlinear optical properties Besides high mechanical and chemical stability the optical component of the invention has excellent nonlinear optical properties, for example frequencydoubling

公开(公告)号：AU2697397A

公开(公告)日：1997-11-12

申请号：AU2697397

申请日：1997-04-15

Applicant: HOECHST AG

Inventor： KLUG PETER ,  WEINELT FRANK ,  FALK UWE

IPC: C07C59/125 ,  C07C59/305 ,  C07C59/315 ,  C07C67/31 ,  C07C69/708 ,  C07C69/734 ,  C07C235/08 ,  C07D295/185 ,  C10M105/38 ,  C10M105/40 ,  C10M105/56 ,  C10M105/68 ,  C10M107/34

公开(公告)号：DE59203848D1

公开(公告)日：1995-11-02

申请号：DE59203848

申请日：1992-01-17

Applicant: HOECHST AG

Inventor： FALK UWE ,  HERRMANN-SCHOENHERR OTTO ,  KREUDER WILLI

IPC: C08L65/00 ,  C08L71/00 ,  C08L71/10 ,  C08L79/08

公开(公告)号：FI934715A0

公开(公告)日：1993-10-25

申请号：FI934715

申请日：1993-10-25

Applicant: HOECHST AG

Inventor： CABRERA IVAN ,  FALK UWE ,  HICKEL WERNER ,  LUPO DONALD ,  MAYER ANDREAS ,  PAWLOWSKI GEORG ,  SCHEUNEMANN UDE

IPC: B32B7/02 ,  C08J5/18 ,  C08L101/00 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361

Abstract: An optical component (100) contains a polymeric medium, which is transparent to electromagnetic radiation and has a second-order susceptibility of at least 10 electrostatic units. This polymeric medium contains compounds having polar-aligned, non-centrosymmetric molecular dipoles which have as a structural element an electron acceptor which is bound to an electron donor via a conjugate pi electron system. As a result, the molar dipole can oscillate between a basic state having a first dipole moment and an electronically excited state having a second dipole moment, differing from the first. The optical component is characterised in that the polymeric medium consists alternately of at least in each case one Langmuir-Blodgett film of at least two polymers having different, non-ionic, nonlinear optical properties (103). In addition to a high mechanical and chemical stability, the optical component according to the invention exhibits excellent nonlinear optical properties, e.g. frequency doubling.